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N-Nitrosodiphenylamine

N-Nitrosodiphenylamine
N-Nitrosodiphenylamine structure
CAS No.
86-30-6
Chemical Name:
N-Nitrosodiphenylamine
Synonyms
TJB;Ndpa;NdphA;Redax;delacj;Ortard;Sconoc;Vultrol;Delac J;ai3-00698
CBNumber:
CB7712443
Molecular Formula:
C12H10N2O
Formula Weight:
198.22
MOL File:
86-30-6.mol

N-Nitrosodiphenylamine Properties

Melting point:
65-66 °C
Boiling point:
268°C
Density 
1.23
vapor pressure 
0.1 at 25 °C (assigned by analogy, Mabey et al., 1982)
refractive index 
1.6330 (estimate)
Flash point:
11 °C
storage temp. 
2-8°C
solubility 
methanol: 0.1 g/mL, clear
color 
Yellow to brown to orange power or flakes
Water Solubility 
Insoluble
BRN 
909531
Henry's Law Constant
2.33 at 25 °C (approximate - calculated from water solubility and vapor pressure)
Stability:
Stability Combustible. Incompatible with oxidising agents.
CAS DataBase Reference
86-30-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, N-nitroso-N-phenyl-(86-30-6)
EPA Substance Registry System
Benzenamine, N-nitroso-N-phenyl-(86-30-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,T,F
Risk Statements  22-39/23/24/25-23/24/25-11
Safety Statements  22-36/37-53-45-16-7
RIDADR  UN 1230 3/PG 2
WGK Germany  3
RTECS  JJ9800000
4.10-9-23
HazardClass  9
PackingGroup  III
Hazardous Substances Data 86-30-6(Hazardous Substances Data)
Toxicity Acute oral LD50 for mice 3,850 mg/kg, rats 1,650 mg/kg (quoted, RTECS, 1985).
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P501 Dispose of contents/container to..…

N-Nitrosodiphenylamine price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 73900 N-Nitrosodiphenylamine technical, ≥97.0% (N) 86-30-6 50g $36.4 2018-11-13 Buy
Sigma-Aldrich 40060 N-Nitrosodiphenylamine solution 86-30-6 1EA $3069.4 2018-11-13 Buy
TCI Chemical D0899 N-Nitrosodiphenylamine >98.0%(HPLC) 86-30-6 25g $20 2018-11-22 Buy
TCI Chemical D0899 N-Nitrosodiphenylamine >98.0%(HPLC) 86-30-6 500g $177 2018-11-22 Buy
Sigma-Aldrich 73900 N-Nitrosodiphenylamine technical, ≥97.0% (N) 86-30-6 250g $103 2018-11-13 Buy

N-Nitrosodiphenylamine Chemical Properties,Uses,Production

Chemical Properties

orange to brown solid

Chemical Properties

N-Nitrosodiphenylamine is a yellow to orangebrown crystalline solid.

Uses

N-Nitrosodiphenylamine is the N-nitroso analogue of diphenylamine that was once used as a rubber additive but is no longer due to undesirable side effects. N-Nitrosodiphenylamine may have potential carcinogenic activity and is currently classified as a probable carcinogen by EPA.

General Description

Yellow to brown or orange powder or flakes or a black solid. Insoluble in water and denser in water. Hence sinks in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

N-Nitrosodiphenylamine may be sensitive to moisture at elevated temperatures in strongly acidic solutions. May react vigorously with oxidizing agents. May undergo trans-nitrosation reactions with secondary amines .

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition N-Nitrosodiphenylamine emits toxic fumes of nitrogen oxides.

Fire Hazard

Flash point data for N-Nitrosodiphenylamine are not available; however, N-Nitrosodiphenylamine is probably combustible.

Safety Profile

Moderately toxic by ingestion. An eye irritant. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Human mutation data reported. Dangerous fire hazard when exposed to heat, flame, or oxidzing materials. Can react vigorously with oxidizing materials. When heated to decomposition it emits highly toxic fumes of NOx,. See also NITROSAMINES.

Potential Exposure

N-Nitrosodiphenylamine is not a naturally occurring substance; it is a man-made chemical that is no longer produced in the United States. It was used in the manufacture of plastics, resins, rubber and synthetic textiles; to help control processes involved in making rubber products, such as tires and mechanical goods; however, in the early 1980s, the United States manufacturers stopped producing N-nitrosodiphenylamine because new and more efficient chemicals were found to replace its uses. In addition, the use of N-nitrosodiphenylamine had several undesirable side effects which do not occur with the replacement chemicals.

Environmental Fate

Chemical/Physical. At temperatures greater than 85 °C, technical grades may decompose to nitrogen oxides (IARC, 1978). N-Nitrosodiphenylamine will not hydrolyze because it does not contain a hydrolyzable functional group (Kollig, 1993).
At influent concentrations of 10, 1.0, 0.1, and 0.01 mg/L, the GAC adsorption capacities were 510, 120, 91, and 38 mg/g, respectively (Dobbs and Cohen, 1980).

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may form hydrazine; hydrogen bromide. Light sensitive; rapidly decomposes.

Waste Disposal

Burn in admixture with flammable solvent in furnace equipped with afterburner and scrubber.

N-Nitrosodiphenylamine Preparation Products And Raw materials

Raw materials

Preparation Products


N-Nitrosodiphenylamine Suppliers

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N-Nitrosodiphenylamine Spectrum


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