ChemicalBook >> CAS DataBase List >>(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) structure

CAS No.: 361346-80-7

Chemical Name:: (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

Synonyms: (R)-AMAC;(R,R)-AMAC;(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II);(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II);(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate

CBNumber:: CB7717721

Molecular Formula:: C32H38CoN2O4

Molecular Weight:: 573.59

MDL Number:: MFCD06797061

MOL File:: 361346-80-7.mol

Last updated:2023-06-08 17:06:35

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(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Properties

Melting point	246-250°C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
optical activity	[α]/D 291°, c = 0.1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07,GHS08
Signal word	Warning
Hazard statements	H302+H312+H332-H351-H302-H312-H315-H319-H332-H335
Precautionary statements	P261-P280-P305+P351+P338-P201-P202-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P308+P313-P405-P501
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	22-24/25-36/37/39
WGK Germany	2
HS Code	2942.00.3500

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) price More Price(15)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	B2314	(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	361346-80-7	100mg	$205	2024-03-01	Buy
TRC	B592090	(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)	361346-80-7	50mg	$265	2021-12-16	Buy
AK Scientific	3990AL	(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)	361346-80-7	100mg	$266	2021-12-16	Buy
Biosynth Carbosynth	FB59944	(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	361346-80-7	25mg	$53	2021-12-16	Buy
Biosynth Carbosynth	FB59944	(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	361346-80-7	50mg	$92	2021-12-16	Buy

Product number	Packaging	Price	Buy
B2314	100mg	$205	Buy
B592090	50mg	$265	Buy
3990AL	100mg	$266	Buy
FB59944	25mg	$53	Buy
FB59944	50mg	$92	Buy

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties,Uses,Production

Uses

Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds

Catalyst for:

Enantioselective borohydride reduction
Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
Stereoselective borohydride reduction of diketones to diols
Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Suppliers

Global( 37)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	52927	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006608290; 18621169109	market03@meryer.com	China	40241	62
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24539	81
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44751	61
Shanghai Longsheng chemical Co.,Ltd.	021-58099652-8005 13585536065	bin.wu@shlschem.com	China	9816	59
Maya High Purity Chemicals	+86 (573) 82222445 (0)18006601000 452520369	sales@maya-r.com	China	11714	57
TOKYO CHEMICAL INDUSTRY CO., LTD.	03-36680489	Sales-JP@TCIchemicals.com	Japan	28398	80
TCI Europe	320-37350700	sales@tcieurope.eu	Europe	23680	75
TCI AMERICA	800-4238616	sales@tciamerica.com	Americas	23662	75

Supplier	Advantage
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Shanghai Longsheng chemical Co.,Ltd.	59
Maya High Purity Chemicals	57
TOKYO CHEMICAL INDUSTRY CO., LTD.	80
TCI Europe	75
TCI AMERICA	75

361346-80-7((1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II))Related Search:

Cobalt (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) (S)-1-PHENYL-2-(P-TOLYL)ETHYLAMINE 1,2-Diphenylethylenediamine Benzenemethanamine,a,2,4-trimethyl-, (aS)-

Benzenemethanamine, α,2,4,6-tetramethyl-, (αS)- (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) MESO-1,2-BIS(P-TOLYL)ETHYLENEDIAMINE (1R,2R)-1,2-BIS(2,4,6-TRIMETHYLPHENYL)ETHYLENEDIAMINE

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(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) (R)-AMAC (R,R)-AMAC (E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 361346-80-7 Homogeneous Catalysts Transition Metal Compounds Classes of Metal Compounds Metal Complexes Catalysts for Organic Synthesis Co (Cobalt) Compounds Asymmetric Synthesis Asymmetric Synthesis Catalysts for Organic Synthesis Classes of Metal Compounds Co (Cobalt) Compounds Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Transition Metal Compounds