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tert-Butyl chloroacetate

tert-Butyl chloroacetate
tert-Butyl chloroacetate structure
CAS No.
107-59-5
Chemical Name:
tert-Butyl chloroacetate
Synonyms
153N-6;NSC 87891;Digitoxin 3'ClCH2C(O)OC(CH3)3;(10E)-3-O-De(αtert-Butyl chloroace;T-BUTYL CHLOROACETATE;TERT-BUTYL CHLORACETATE;3-Formyl Tyrosol αreft-Butyl chloroacetate
CBNumber:
CB7749461
Molecular Formula:
C6H11ClO2
Formula Weight:
150.6
MOL File:
107-59-5.mol

tert-Butyl chloroacetate Properties

Boiling point:
48-49 °C/11 mmHg (lit.)
Density 
1.053 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.423(lit.)
Flash point:
116 °F
storage temp. 
Flammables area
form 
Liquid
Specific Gravity
1.053
color 
Clear colorless to yellow
Water Solubility 
<0.1 g/L (20 ºC)
Merck 
14,1563
BRN 
1753006
CAS DataBase Reference
107-59-5(CAS DataBase Reference)
FDA UNII
05TMW98298
NIST Chemistry Reference
Acetic acid, chloro-, 1,1-dimethylethyl ester(107-59-5)
EPA Substance Registry System
Acetic acid, chloro-, 1,1-dimethylethyl ester (107-59-5)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS02,GHS05,GHS06,GHS09
Signal word  Danger
Hazard statements  H302+H312+H332-H315-H319-H302-H312-H335-H400-H410-H226-H302+H312-H314-H331
Precautionary statements  P273-P280h-P309-P501a-P261-P280-P305+P351+P338-P310-P210-P233-P240-P241+P242+P243-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501
Hazard Codes  C,N,Xn,Xi,F
Risk Statements  20/21/22-34-50/53-36/37/38-10
Safety Statements  26-36/37/39-45-61-60-16-7/9
RIDADR  UN 2920 8/PG 2
WGK Germany  3
RTECS  AF8985500
19-21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29154000

tert-Butyl chloroacetate price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 186791 tert-Butyl chloroacetate 97% 107-59-5 25g $28.9 2021-12-16 Buy
Sigma-Aldrich 186791 tert-Butyl chloroacetate 97% 107-59-5 100g $69.6 2021-12-16 Buy
TCI Chemical C1267 tert-Butyl Chloroacetate >97.0%(GC) 107-59-5 25mL $27 2021-12-16 Buy
TCI Chemical C1267 tert-Butyl Chloroacetate >97.0%(GC) 107-59-5 500mL $77 2021-12-16 Buy
Alfa Aesar A15833 tert-Butyl chloroacetate, 98% 107-59-5 25g $26.2 2021-12-16 Buy

tert-Butyl chloroacetate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid

Uses

In the glycidic ester condensation.

Uses

tert-Butyl chloroacetate is used in the synthesis of imidazol-1-yl-acetic acid hydrochloride, cis-disubstituted aziridine ester via aza-Darzens reaction and 1,10-diaza-18-crown-6 based sensors bearing a coumarin fluorophore.

Hazard

A poison by ingestion. Moderately toxic by inhalation skin contact. Severe skin and moderate eye irritant.

Safety Profile

A poison by ingestion. Moderately toxic by inhalation skin contact. S severe sluin and moderate eye irritant. When heated to decomposition it emits toxic vapors of Cl-.

Purification Methods

Check the NMR spectrum; if satisfactory then distil in a vacuum; if not then dissolve in Et2O, wash with H2O, 10% H2SO4 until the acid extract does not become cloudy when made alkaline with NaOH. Wash the organic layer again with H2O, then saturated aqueous NaHCO3, dry over Na2SO4, evaporate and fractionate it through a carborundum-packed column or a 6-inch Widmer column (p 11, see tert-butyl ethyl malonate for precautions to avoid decomposition during disillation). [Johnson et al. J Am Chem Soc 75 4995 1953, Baker Org Synth Coll Vol III 144 1944, Beilstein 2 III 444.]

tert-Butyl chloroacetate Preparation Products And Raw materials

Raw materials

Preparation Products


tert-Butyl chloroacetate Suppliers

Global( 251)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 15419 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 26782 60
career henan chemical co
+86-0371-55982848
sales@coreychem.com China 29953 58
Kingfirst chemical (nanjing) co.,ltd
86-25-84522992
86-25-84774616 or 1617 marketing@kingfirstchem.com CHINA 95 58
Chongqing Chemdad Co.,Ltd
+86-19923101450
sales@chemdad.com CHINA 4000 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63726 58

View Lastest Price from tert-Butyl chloroacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-12-29 Tert-Butyl Chloroacetate
107-59-5
US $19.00 / KG 1KG 99.% 10 ton Hebei Crovell Biotech Co Ltd
2021-07-13 tert-Butyl chloroacetate
107-59-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10 tert-Butyl chloroacetate
107-59-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

tert-Butyl chloroacetate Spectrum


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