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tert-Butyl chloroacetate

tert-Butyl chloroacetate
tert-Butyl chloroacetate structure
Chemical Name:
tert-Butyl chloroacetate
NSC 87891;ClCH2C(O)OC(CH3)3;tert-Butyl chloroace;T-BUTYL CHLOROACETATE;TERT-BUTYL CHLORACETATE;reft-Butyl chloroacetate;TERT-BUTYL CHLOROACETATE;tert-Butyl chloroacetate,99%;tert-Butyl chloroacetate,97%;#ntert.-Butyl chloroacetate
Molecular Formula:
Formula Weight:
MOL File:

tert-Butyl chloroacetate Properties

Boiling point:
48-49 °C11 mm Hg(lit.)
1.053 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.423(lit.)
Flash point:
116 °F
storage temp. 
Flammables area
Clear colorless to yellow
Specific Gravity
Water Solubility 
<0.1 g/L (20 ºC)
CAS DataBase Reference
107-59-5(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, chloro-, 1,1-dimethylethyl ester(107-59-5)
EPA Substance Registry System
Acetic acid, chloro-, 1,1-dimethylethyl ester(107-59-5)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C,N,Xn,Xi,F
Risk Statements  20/21/22-34-50/53-36/37/38-10
Safety Statements  26-36/37/39-45-61-60-16-7/9
RIDADR  UN 2920 8/PG 2
WGK Germany  3
RTECS  AF8985500
HazardClass  3
PackingGroup  III
HS Code  29154000
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

tert-Butyl chloroacetate price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 186791 tert-Butyl chloroacetate 97% 107-59-5 25g $27.2 2018-11-20 Buy
Sigma-Aldrich 186791 tert-Butyl chloroacetate 97% 107-59-5 100g $65.8 2018-11-20 Buy
TCI Chemical C1267 tert-Butyl Chloroacetate >97.0%(GC) 107-59-5 25mL $28 2018-11-22 Buy
TCI Chemical C1267 tert-Butyl Chloroacetate >97.0%(GC) 107-59-5 500mL $235 2018-11-22 Buy
Alfa Aesar A15833 tert-Butyl chloroacetate, 98% 107-59-5 100g $65.2 2018-11-13 Buy

tert-Butyl chloroacetate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid


In the glycidic ester condensation.


A poison by ingestion. Moderately toxic by inhalation skin contact. Severe skin and moderate eye irritant.

Safety Profile

A poison by ingestion. Moderately toxic by inhalation skin contact. S severe sluin and moderate eye irritant. When heated to decomposition it emits toxic vapors of Cl-.

Purification Methods

Check the NMR spectrum; if satisfactory then distil in a vacuum; if not then dissolve in Et2O, wash with H2O, 10% H2SO4 until the acid extract does not become cloudy when made alkaline with NaOH. Wash the organic layer again with H2O, then saturated aqueous NaHCO3, dry over Na2SO4, evaporate and fractionate it through a carborundum-packed column or a 6-inch Widmer column (p 11, see tert-butyl ethyl malonate for precautions to avoid decomposition during disillation). [Johnson et al. J Am Chem Soc 75 4995 1953, Baker Org Synth Coll Vol III 144 1944, Beilstein 2 III 444.]

tert-Butyl chloroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

tert-Butyl chloroacetate Suppliers

Global( 200)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817 CHINA 21909 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693 CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733 CHINA 32457 55
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 CHINA 24196 60
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114 CHINA 6374 58
career henan chemical co
+86-371-86658258 CHINA 20653 58
Kingfirst chemical (nanjing) co.,ltd
86-25-84774616 or 1617 CHINA 60 58
Chemwill Asia Co.,Ltd.
86-21-51861608;;; CHINA 23982 58
Nanjing Vital Chemical Co., Ltd. Please Send Email QQ:18652950785
025-87193546 China 4429 65
Hangzhou Alltech Chemical Co., Ltd +86-571-86739500
0571-86731857 China 52 58

View Lastest Price from tert-Butyl chloroacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-22 tert-Butyl chloroacetate
US $1.00 / kg 1kg 99% Customized career henan chemical co

tert-Butyl chloroacetate Spectrum

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