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Thioacetamide

Organic reagents Chemical properties Uses Production method
Thioacetamide
Thioacetamide
CAS No.
62-55-5
Chemical Name:
Thioacetamide
Synonyms
TAA;CH3CSNH2;usafcb-21;USAF cb-21;usafek-1719;Thiacetamide;Thioactamide;USAF ek-1719;hioacetamide;thio-acetamid
CBNumber:
CB7755552
Molecular Formula:
C2H5NS
Formula Weight:
75.13
MOL File:
62-55-5.mol

Thioacetamide Properties

Melting point:
108-112 °C(lit.)
Density 
1.37
refractive index 
1.5300 (estimate)
storage temp. 
Store at RT.
solubility 
passes test2%
form 
Liquid
color 
Off-white to slightly beige
PH
5.2 (100g/l, H2O, 20℃)
Water Solubility 
16.3 g/100 mL (25 ºC)
Merck 
14,9319
BRN 
506006
Stability:
Stability Incompatible with water, mineral acids.
CAS DataBase Reference
62-55-5(CAS DataBase Reference)
NIST Chemistry Reference
Ethanethioamide(62-55-5)
EPA Substance Registry System
Ethanethioamide(62-55-5)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T
Risk Statements  45-22-36/38-52/53
Safety Statements  53-45-61-99
RIDADR  2811
WGK Germany  3
RTECS  AC8925000
10
TSCA  Yes
HS Code  29309070
Hazardous Substances Data 62-55-5(Hazardous Substances Data)
Toxicity MLD orally in rats: 200 mg/kg (Ambrose)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

Thioacetamide price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 1.08170 Thioacetamide 62-55-5 1EA $239 2017-11-08 Buy
Sigma-Aldrich 1.08170 Thioacetamide 62-55-5 2EA $992 2017-11-08 Buy
TCI Chemical T0187 Thioacetamide >98.0%(GC)(T) 62-55-5 25g $20 2017-11-08 Buy
TCI Chemical T0187 Thioacetamide >98.0%(GC)(T) 62-55-5 100g $58 2017-11-08 Buy
Alfa Aesar 030638 Thioacetamide, ACS, 99% 62-55-5 50g $69.6 2018-11-16 Buy

Thioacetamide Chemical Properties,Uses,Production

Organic reagents

Thioacetamide is organic reagent, it is colorless or white crystalline flake. It is dissolved in water, ethanol, very slightly soluble in benzene, ether, the aqueous solution at room temperature or 50~60℃ is fairly stable, when placed 2 to 3 weeks, it is not change, but when hydrogen ions is in the presence, it quickly decomposes into hydrogen sulfide , but hydrolysis increases with alkalinity or acidity of the solution and the temperature rises quickly. Hydrolysis equations solution of thioacetamide in acidic and basic is:
Acidic solution: CH3CSNH2 + 2H2O----(NH4 +) + CH3COO-+ H2S
Alkaline solution: CH3CSNH2 + 2OH-----NH3 + CH3COO-+ HS-
Since H2S or HS-can generate for hydrolysis in acidic or alkaline solution, so in analytical chemistry, it is often used in place of toxic and odor H2S, as the metal cation group reagents or precipitation reagents. The property of resulting precipitate is good, easy to separate. In addition, it can also be used for bismuth measurement reagent. Preparation method: It can be prepared by heating the acetamide with aluminum sulfide, hydrogen sulfide reacting with acetonitrile, or acetamide reacting with K3PS4.

Chemical properties

It is colorless or white crystals. Mp is 113-114℃, the solubility in water is 16.3g/100ml at 25℃, ethanol 26.4g/100ml. It is slightly soluble in benzene, ether. Their solution is quite stable at room temperature or 50-60℃, but when hydrogen ions exists, it can generate thiosulfate hydrogen and decompose quickly. New product sometimes has mercaptan odor, slight moisture absorption.
The above information is edited by the chemicalbook of Wang Xiaodong.

Uses

1. It can be used for the production of catalysts, stabilizers, polymerization inhibitors, electroplating additives, photographic chemicals, pesticides, dyeing auxiliary and processing agents. It can be also used as polymer curing agents, crosslinking agents, rubber additives and pharmaceutical raw materials.
2. It can be also used as vulcanizing agent and crosslinking agent of polymer, rubber additives, pharmaceutical raw materials, etc.
3. It can be also used as analytical reagents.

Production method

Thioacetamide can be obtained by the reaction of acetonitrile with hydrogen sulfide, or acetamide with phosphorus pentasulfide.

Chemical Properties

White solid

Uses

Sulfide generation

Uses

Substitute for H2S in laboratory qualitative analyses.

Definition

ChEBI: A thiocarboxamide consiting of acetamide having the oxygen replaced by sulfur.

General Description

White crystals with a mercaptan odor.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Thioacetamide reacts with aqueous acid to generate hydrogen sulfide. Forms addition compounds and sulfides with salts of heavy metals. Hydrolyzed by acids or bases .

Hazard

Toxic by ingestion and inhalation, a possible carcinogen.

Fire Hazard

Flash point data on Thioacetamide are not available; Thioacetamide is probably combustible.

Purification Methods

Crystallise the amide from absolute diethyl ether or *benzene. Dry it at 70o in a vacuum and store it over P2O5 at 0o under nitrogen. (It develops an obnoxious odour on storage, and absorption at 269nm decreases, hence it should be freshly recrystallised before use). [Beilstein 2 IV 565.]

Thioacetamide Preparation Products And Raw materials

Raw materials

Preparation Products


Thioacetamide Suppliers

Global( 294)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Jinan Chenghui-Shuangda Chemical Co.,Ltd
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+86-531-58897093 jack@jnchsd.com CHINA 79 58
Henan DaKen Chemical CO.,LTD.
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Shanghai Time Chemicals CO., Ltd.
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career henan chemical co
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Sichuan Hainuowei Technology Co. Ltd. 028-83585582 ,13708085536
028-83585580 hanovichem@163.com China 5786 56
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727 shenlinxing@macklin.cn China 15834 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
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View Lastest Price from Thioacetamide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-20 Thioacetamide
62-55-5
US $1.00 / KG 1KG 99% Customized

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