ChemicalBook >> CAS DataBase List >>METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

CAS No.
369-26-6
Chemical Name:
METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
Synonyms
Methyl 3-amino-4-fluorobenzoate;Methyl 3-amino-4-fluorobenzoate 99%;2-Fluoro-5-(methoxycarbonyl)aniline;METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE;Benzoic acid, 3-amino-4-fluoro-, methyl ester;methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O);3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI);Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)
CBNumber:
CB7830853
Molecular Formula:
C8H8FNO2
Molecular Weight:
169.15
MDL Number:
MFCD08689743
MOL File:
369-26-6.mol
Last updated:2025-07-24 18:13:45
Product description Number Pack Size Price
Methyl3-amino-4-fluorobenzoate M328678 100mg $45
Methyl 3-amino-4-fluorobenzoate 4658-3-W0 5G $50
Methyl3-Amino-4-fluorobenzoate W5803 1g $67
Methyl 3-amino-4-fluorobenzenecarboxylate >95% 047241 5g $71
Methyl3-amino-4-fluorobenzoate 99% PC7646 25g $103
More product size

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Properties

Melting point 66-69
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form crystalline solid
color Beige

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
HazardClass  IRRITANT
HS Code  2922498590

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M328678 Methyl3-amino-4-fluorobenzoate 369-26-6 100mg $45 2021-12-16 Buy
SynQuest Laboratories 4658-3-W0 Methyl 3-amino-4-fluorobenzoate 369-26-6 5G $50 2021-12-16 Buy
AK Scientific W5803 Methyl3-Amino-4-fluorobenzoate 369-26-6 1g $67 2021-12-16 Buy
Matrix Scientific 047241 Methyl 3-amino-4-fluorobenzenecarboxylate >95% 369-26-6 5g $71 2021-12-16 Buy
Apolloscientific PC7646 Methyl3-amino-4-fluorobenzoate 99% 369-26-6 25g $103 2021-12-16 Buy
Product number Packaging Price Buy
M328678 100mg $45 Buy
4658-3-W0 5G $50 Buy
W5803 1g $67 Buy
047241 5g $71 Buy
PC7646 25g $103 Buy

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Chemical Properties,Uses,Production

Synthesis

Methyl 4-fluoro-3-nitrobenzoate

329-59-9

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

369-26-6

Step B: Synthesis of methyl 3-amino-4-fluorobenzoate; Methyl 4-fluoro-3-nitrobenzoate (6.57 g, 33 mmol) was dissolved in EtOAc (75 mL) and 10% palladium carbon catalyst (0.66 g) was added. The reaction mixture was transferred to a Fisher-Porter flask and mounted on a hydrogenation unit. The flask was charged with hydrogen (25 psi) and the reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad, followed by concentration of the filtrate to give a yellow oily product which deepened in color on standing and in quantitative yield (5.51 g, 33 mmol). Mass spectrometry (ESI) showed m/z = 170 [M + H]+.

References

[1] Patent: WO2009/76140, 2009, A1. Location in patent: Page/Page column 186
[2] Journal of Organic Chemistry, 1990, vol. 55, # 7, p. 2034 - 2044
[3] Synlett, 2010, # 20, p. 3019 - 3022
[4] Patent: WO2010/126922, 2010, A1. Location in patent: Page/Page column 62
[5] Zhurnal Organicheskoi Khimii, 1972, vol. 8, p. 803,804; engl. Ausg. S. 813, 814

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Preparation Products And Raw materials

Global( 102)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16515 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718; +8613336195806 sales@capot.com China 29735 60
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49975 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29799 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569262 +86-15003564040 1087@dideu.com China 3979 58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
+8613580539051 joe@yuhengpharm.com CHINA 21142 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Win-Win chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14360 58

View Lastest Price from METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 3-amino-4-fluorobenzoate pictures 2025-10-13 Methyl 3-amino-4-fluorobenzoate
369-26-6
US $3.00-9.00 / KG 0.1KG 99% g-kg-tons, free sample is available ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Methyl3-amino-4-fluorobenzenecarboxylate pictures 2025-01-03 Methyl3-amino-4-fluorobenzenecarboxylate
369-26-6
US $0.00-0.00 / KG 5mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid pictures 2025-01-03 4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid
56447-54-2
US $0.00-0.00 / KG 5mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Methyl 3-amino-4-fluorobenzoate Methyl 3-amino-4-fluorobenzoate 99% methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O) 2-Fluoro-5-(methoxycarbonyl)aniline Benzoic acid, 3-amino-4-fluoro-, methyl ester Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI) 3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI) 369-26-6