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Allyl bromide

Allyl bromide
Allyl bromide structure
CAS No.
106-95-6
Chemical Name:
Allyl bromide
Synonyms
CH2=CHCH2Br;Allylbromid;BROMALLYLENE;3-Brompropen;ALLYL BROMIDE;Bromoallylene;ALLYLBROMID-R;3-BROMOPROPENE;3-bromopropane;3-bromo-propen
CBNumber:
CB7852691
Molecular Formula:
C3H5Br
Formula Weight:
120.98
MOL File:
106-95-6.mol

Allyl bromide Properties

Melting point:
-119 °C
Boiling point:
70-71 °C(lit.)
Density 
1.398 g/mL at 25 °C(lit.)
vapor density 
4.2 (vs air)
refractive index 
n20/D 1.469(lit.)
Flash point:
28 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless to slightly colored
Specific Gravity
1.398
Odor
unpleasant
explosive limit
4.3-7.3%(V)
Water Solubility 
insoluble
Sensitive 
Light Sensitive
Merck 
14,288
BRN 
605308
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents.
InChIKey
BHELZAPQIKSEDF-UHFFFAOYSA-N
CAS DataBase Reference
106-95-6(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
FXQ8X2F74Z
NIST Chemistry Reference
1-Propene, 3-bromo-(106-95-6)
EPA Substance Registry System
3-Bromopropene (106-95-6)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS02,GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H301-H314-H340-H350-H400-H301+H331-H335-H318-H331
Precautionary statements  P301+P310a-P501a-P201-P210-P273-P280-P301+P310-P305+P351+P338-P370+P378-P403+P235-P301+P310+P330-P303+P361+P353-P304+P340+P310-P308+P313-P233-P240-P241+P242+P243-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P305+P351+P338+P310-P391-P403+P233-P405-P501
Hazard Codes  F,T,N
Risk Statements  11-23/25-34-50-25-46-45
Safety Statements  16-26-36/37/39-45-60-61-53
RIDADR  UN 1099 3/PG 1
WGK Germany  2
RTECS  UC7090000
8-19
Autoignition Temperature 554 °F
TSCA  Yes
HazardClass  3
PackingGroup  I
HS Code  29033036
Toxicity LD50 orally in Rabbit: 120 mg/kg
NFPA 704
3
3 1

Allyl bromide price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 337528 Allyl bromide reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer 106-95-6 250ml $36.6 2019-12-02 Buy
Sigma-Aldrich 337528 Allyl bromide reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer 106-95-6 1l $123 2019-12-02 Buy
TCI Chemical B0643 Allyl Bromide >98.0%(GC) 106-95-6 25g $20 2020-06-24 Buy
TCI Chemical B0643 Allyl Bromide >98.0%(GC) 106-95-6 500g $76 2020-06-24 Buy
Alfa Aesar A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide 106-95-6 250g $38.9 2020-06-24 Buy

Allyl bromide Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Chemical Properties

Allyl bromide is a clear to light yellow liquid. As an alkylating agent, allyl bromide is used extensively in the synthesis of polymers, pharmaceuticals, allyls, and other organic compounds. Allyl bromide is a clear liquid with an intense, acrid, persistent smell and is flammable. It is insoluble in water, but soluble in alcohol, aether, acetone, carbon tetrachloride, and chloroform. In fact, allyl bromide is used in the synthesis of other allyl compounds, to synthesize dyestuff, spice, and as a curative in the medicine industry. Allyl bromide has a very high mobility in soil. It is also used as a soil fumigant and as a contact poison. Allyl bromide induces unscheduled DNA synthesis in HeLa cells.

Chemical Properties

Allyl bromide is a highly flammable, colorless to light yellow liquid with an unpleasant, pungent odor.

Uses

Allyl Bromide is used as a reagent in the synthesis of Resveratrol derivatives. Resveratrol (R150000) is a minor constituent of wine, correlated with serum lipid reduction and inhibition of platelet a ggregation. Resveratrol is a specific inhibitor of COX-1, and it also inhibits the hydroperoxidase activity of COX-1. It has been shown to inhibit events associated with tumor initiation, promotion a nd progression.

Uses

manufacture of synthetic perfumes, other allyl compounds.

General Description

A clear colorless to light yellow liquid with an irritating unpleasant odor. Flash point 30°F. Irritates eyes, skin, and respiratory system. Toxic by skin absorption. Denser than water and slightly soluble in water.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

Allyl bromide decomposes upon heating and exposure to light, forming HBr (a strong reducing agent). Reacts violently with oxidizing agents. Can react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

Hazard

Strong irritant to skin and eyes, flammable, high fire risk. Upper respiratory tract irritant. Ques- tionable carcinogen.

Health Hazard

Inhalation of vapor irritates mucous membranes and causes dizziness, headache, and lung irritation. Contact with liquid irritates eyes and skin. Ingestion causes irritation of mouth and stomach.

Health Hazard

Exposures to allyl bromide cause severe eye and skin burns, irritation to the eyes, skin, and respiratory system. It is harmful when absorbed through the skin or inhaled in the workplace. Laboratory rats exposed for a prolonged period of time developed symptoms of poisoning, such as excessive salivation in a small number of animals, and severe gastric irritation. Vapors of allyl bromide may cause dizziness or suffocation, headache, coughing, and distressed breathing.

Safety Profile

Poison by ingestion and intraperitoneal routes. Mdly toxic by inhalation. Human mutation data reported. See also ALLYL CHLORIDE and ALLYL COMPOUNDS. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Br-. To fight fire, use alcohol foam, water spray or mist, CO2, dry chemical

Potential Exposure

Used as an insecticide; in the manufacture of resins, fragrances, and other chemicals

storage

Allyl bromide should be stored separate from oxidizing materials and alkalis in a cool, dry, well-ventilated location in tightly closed containers.

Shipping

UN1099 Allyl bromide, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials

Purification Methods

Wash the bromide with NaHCO3 solution then distilled water, dry (CaCl2 or MgSO4), and fractionally distil. Protect it from strong light. [Beilstein 1 IV 754.] LACHRYMATORY, HIGHLY TOXIC and FLAMMABLE.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Heat or light exposure may cause decomposition and corrosive vapors.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Precautions

Workers should wear positive pressure self-contained breathing apparatus (SCBA), goggles and a face shield, protective clothing for high concentrations of vapor, chemical protective clothing that is specifi cally recommended by the manufacturer to avoid poisoning. Workers should be careful as allyl bromide reacts with oxidizing materials and alkalis.

Allyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products


Allyl bromide Suppliers

Global( 305)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Yancheng Longshen Chemical Co.,Ltd.
86-0515-88706880 86-18352073353
86-0515-88706880 sales@longshenchem.com CHINA 78 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21837 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22625 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30043 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28231 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930501651
whatsapp: +8619930501651 breeduan@crovellbio.com CHINA 2581 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6371 58
Henan Xiangtong Chemical Co., Ltd.
86-371-61312303
86-371-86017988 xtchem2019@gmail.com CHINA 288 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23045 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35434 58

Related articles


View Lastest Price from Allyl bromide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-11-01 Allyl bromide
106-95-6
US $1.00 / KG 1KG 99% 100MT Henan Xiangtong Chemical Co., Ltd.
2020-04-30 Allyl bromide
106-95-6
US $1.00 / KG 1KG 99% 20 ton Hebei Guanlang Biotechnology Co., Ltd.
2020-01-11 Allyl bromide
7230-25-2
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co

Allyl bromide Spectrum


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