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Allyl bromide

CAS No.
106-95-6
Chemical Name:
Allyl bromide
Synonyms
3-BROMOPROPENE;3-BROMO-1-PROPENE;3-bromopropane;3-BROMOPROPYLENE;Allylbromid;BROMALLYLENE;3-Brompropen;3-bromo-prop-1-ene;CH2=CHCH2Br;ALLYL BROMIDE
CBNumber:
CB7852691
Molecular Formula:
C3H5Br
Lewis structure
c3h5br lewis structure
Molecular Weight:
120.98
MDL Number:
MFCD00000244
MOL File:
106-95-6.mol
MSDS File:
SDS
Last updated:2023-12-25 13:23:17

Allyl bromide Properties

Melting point -119 °C
Boiling point 70-71 °C(lit.)
Density 1.398 g/mL at 25 °C(lit.)
vapor density 4.2 (vs air)
vapor pressure 18.66kPa at 25℃
refractive index n20/D 1.469(lit.)
Flash point 28 °F
storage temp. 2-8°C
solubility Chloroform (Soluble)
form Liquid
Specific Gravity 1.398
color Clear colorless to slightly colored
Odor unpleasant
explosive limit 4.3-7.3%(V)
Water Solubility insoluble
Sensitive Light Sensitive
Merck 14,288
BRN 605308
Exposure limits ACGIH: TWA 0.1 ppm; STEL 0.2 ppm (Skin)
Dielectric constant 7.0
Stability Stable. Flammable. Incompatible with strong oxidizing agents.
InChIKey BHELZAPQIKSEDF-UHFFFAOYSA-N
LogP 1.79
CAS DataBase Reference 106-95-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII FXQ8X2F74Z
NIST Chemistry Reference 1-Propene, 3-bromo-(106-95-6)
EPA Substance Registry System 3-Bromopropene (106-95-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H301+H331-H314-H340-H350-H400
Precautionary statements  P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,T,N
Risk Statements  11-23/25-34-50-25-46-45
Safety Statements  16-26-36/37/39-45-60-61-53
RIDADR  UN 1099 3/PG 1
WGK Germany  2
RTECS  UC7090000
8-19
Autoignition Temperature 554 °F
TSCA  Yes
HazardClass  3
PackingGroup  I
HS Code  29033036
Toxicity LD50 orally in Rabbit: 120 mg/kg
NFPA 704
3
3 1

Allyl bromide price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 337528 Allyl bromide reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer 106-95-6 250ml $58.2 2024-03-01 Buy
Sigma-Aldrich 8.01021 3-Bromo-1-propene (stabilised) for synthesis 106-95-6 1L $185 2024-03-01 Buy
Sigma-Aldrich 337528 Allyl bromide reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer 106-95-6 1l $179 2024-03-01 Buy
TCI Chemical B0643 Allyl Bromide >98.0%(GC) 106-95-6 25g $23 2024-03-01 Buy
TCI Chemical B0643 Allyl Bromide >98.0%(GC) 106-95-6 500g $92 2024-03-01 Buy
Product number Packaging Price Buy
337528 250ml $58.2 Buy
8.01021 1L $185 Buy
337528 1l $179 Buy
B0643 25g $23 Buy
B0643 500g $92 Buy

Allyl bromide Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Chemical Properties

Allyl bromide is a highly flammable, colorless to light yellow liquid with an unpleasant, pungent odor.

Chemical Properties

Allyl bromide is a clear to light yellow liquid. As an alkylating agent, allyl bromide is used extensively in the synthesis of polymers, pharmaceuticals, allyls, and other organic compounds. Allyl bromide is a clear liquid with an intense, acrid, persistent smell and is flammable. It is insoluble in water, but soluble in alcohol, aether, acetone, carbon tetrachloride, and chloroform. In fact, allyl bromide is used in the synthesis of other allyl compounds, to synthesize dyestuff, spice, and as a curative in the medicine industry. Allyl bromide has a very high mobility in soil. It is also used as a soil fumigant and as a contact poison. Allyl bromide induces unscheduled DNA synthesis in HeLa cells.

Uses

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Uses

Allyl Bromide is used as a reagent in the synthesis of Resveratrol derivatives. Resveratrol (R150000) is a minor constituent of wine, correlated with serum lipid reduction and inhibition of platelet a ggregation. Resveratrol is a specific inhibitor of COX-1, and it also inhibits the hydroperoxidase activity of COX-1. It has been shown to inhibit events associated with tumor initiation, promotion a nd progression.

Uses

manufacture of synthetic perfumes, other allyl compounds.

General Description

A clear colorless to light yellow liquid with an irritating unpleasant odor. Flash point 30°F. Irritates eyes, skin, and respiratory system. Toxic by skin absorption. Denser than water and slightly soluble in water.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

Allyl bromide decomposes upon heating and exposure to light, forming HBr (a strong reducing agent). Reacts violently with oxidizing agents. Can react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

Hazard

Strong irritant to skin and eyes, flammable, high fire risk. Upper respiratory tract irritant. Ques- tionable carcinogen.

Health Hazard

Inhalation of vapor irritates mucous membranes and causes dizziness, headache, and lung irritation. Contact with liquid irritates eyes and skin. Ingestion causes irritation of mouth and stomach.

Health Hazard

Exposures to allyl bromide cause severe eye and skin burns, irritation to the eyes, skin, and respiratory system. It is harmful when absorbed through the skin or inhaled in the workplace. Laboratory rats exposed for a prolonged period of time developed symptoms of poisoning, such as excessive salivation in a small number of animals, and severe gastric irritation. Vapors of allyl bromide may cause dizziness or suffocation, headache, coughing, and distressed breathing.

Flammability and Explosibility

Highly flammable

Safety Profile

Poison by ingestion and intraperitoneal routes. Mdly toxic by inhalation. Human mutation data reported. See also ALLYL CHLORIDE and ALLYL COMPOUNDS. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Br-. To fight fire, use alcohol foam, water spray or mist, CO2, dry chemical

Synthesis

Allyl alcohol was synthesized from glycerol and formic acid under inert atmosphere, hydrolysed with NaOH and fractionally distilled to yield the 73% allyl alcohol water azeotrope. This was then reacted with 48% hydrobromic acid and sulfuric acid and the allyl bromide distilled as per the conventional method. It was then redistilled with 3A molecular sieves drying agent to yield the final product which is stored over additional 3A molecular sieves.

Potential Exposure

Used as an insecticide; in the manufacture of resins, fragrances, and other chemicals

storage

Allyl bromide should be stored separate from oxidizing materials and alkalis in a cool, dry, well-ventilated location in tightly closed containers.

Shipping

UN1099 Allyl bromide, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials

Purification Methods

Wash the bromide with NaHCO3 solution then distilled water, dry (CaCl2 or MgSO4), and fractionally distil. Protect it from strong light. [Beilstein 1 IV 754.] LACHRYMATORY, HIGHLY TOXIC and FLAMMABLE.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Heat or light exposure may cause decomposition and corrosive vapors.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Precautions

Workers should wear positive pressure self-contained breathing apparatus (SCBA), goggles and a face shield, protective clothing for high concentrations of vapor, chemical protective clothing that is specifi cally recommended by the manufacturer to avoid poisoning. Workers should be careful as allyl bromide reacts with oxidizing materials and alkalis.

107-11-9
106-95-6
Synthesis of Allyl bromide from Allylamine
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View Lastest Price from Allyl bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allyl bromide pictures 2024-03-29 Allyl bromide
106-95-6
US $5.00 / KG 1KG 99% 500mt/year Jinan Finer Chemical Co., Ltd
Allyl bromide pictures 2023-12-26 Allyl bromide
106-95-6
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Allyl bromide pictures 2023-11-14 Allyl bromide
106-95-6
US $0.00-0.00 / kg 1kg 99% 50000kg Hebei Yibangte Import and Export Co. , Ltd.
  • Allyl bromide pictures
  • Allyl bromide
    106-95-6
  • US $5.00 / KG
  • 99%
  • Jinan Finer Chemical Co., Ltd
  • Allyl bromide pictures
  • Allyl bromide
    106-95-6
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • Allyl bromide pictures
  • Allyl bromide
    106-95-6
  • US $0.00-0.00 / kg
  • 99%
  • Hebei Yibangte Import and Export Co. , Ltd.
2-PROPENYL BROMIDE ALLYL BROMIDE CH2=CHCH2Br Propene, 3-bromo- Propene,3-bromo- ALLYL BROMIDE, REAGENTPLUS, 99% ALLYL BROMIDE STAB. WITH SILVER Allyl bromide, stabilized, 99% 3-BROMOPROPENE,REAGENT 3-Bromo-1-propene (stabilised) for synthesis Allyl bromide, Stabilized with 300 to 1000ppm Propylene oxide 1-Bromo-2-propene 1-Propene,3-bromo- 3-bromo-1-propen 3-bromo-propen allylbromide(3-bromopropene) bromo-3propene Bromoallylene ALLYL BROMIDE pure Allyl broMide, stabilized, 99% 250ML (DG) Allyl bromide 2g [106-95-6] Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide 3-Bromoprop-1-ene 99% ALLYLBROMID-R Allyl bromide, 98+% Allyl bromide, 99%, stabilized 3-Bromo-1-propene 3-Bromopropylene 3-BROMO-1-PROPENE (STABILISED) FOR SYNTH 3-BroMopropene/ Allyl broMide Allyl Bromide (Stabilized with Propylene Oxide) 3-BroMopropene, Stabilized with ca. 300 ppM Propylene Oxide, Reagent Allyl broMide reagent grade, 97%, contains <=1000 ppM propylene oxide as stabilizer Allyl broMide ReagentPlus(R), 99%, contains <=1000 ppM propylene oxide as stabilizer 3 - allyl broMide ALLYL BROMIDE, 98%ALLYL BROMIDE, 98%ALLYL BROMIDE, 98%ALLYL BROMIDE, 98% Аллил бромистый, 2-пропенилбромид, 3-бромпропен, Allyl bromide, 3-Bromo-1-propene Allyl Bromide > Allyl bromide,99% Allyl bromide ISO 9001:2015 REACH Allyl bromideF Allyl bromide, GR 99%+ ALLYL BROMIDE For Synthesis BROMALLYLENE 3-BROMOPROPYLENE 3-BROMOPROPENE 3-BROMO-1-PROPENE 3-bromo-prop-1-ene 3-Brompropen Allylbromid 3-bromopropane Eugenol Impurity 18 Eugenol Impurity 1 3-Bromo-1-Propylene 106-95-6 106-95-9 203-446-6 7230-25-2 106956