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(S)-(-)-2-Methyl-1-butanol

(S)-(-)-2-Methyl-1-butanol structure

CAS No.: 1565-80-6

Chemical Name:: (S)-(-)-2-Methyl-1-butanol

Synonyms: AMYL ALCOHOL;N-PENTANOL;FUSEL OIL;N-PENTYL ALCOHOL;AMYL ALCOHOL, N-;FEMA 2056;ALCOHOL C5;L-pentanol;(s)-1-butano;BUTYLCARBINOL

CBNumber:: CB7853148

Molecular Formula:: C5H12O

Molecular Weight:: 88.15

MDL Number:: MFCD00064299

MOL File:: 1565-80-6.mol

MSDS File:: SDS

Last updated:2023-11-28 16:31:43

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(S)-(-)-2-Methyl-1-butanol Properties

Melting point	-70 °C
alpha	-5.8 º (neat 23 ºC)
Boiling point	136-138 °C(lit.)
Density	0.811 g/mL at 25 °C(lit.)
vapor density	3 (vs air)
vapor pressure	1 mm Hg ( 13.6 °C)
refractive index	n20/D 1.409(lit.)
Flash point	120 °F
storage temp.	2-8°C
solubility	soluble in Chloroform, Ethanol
pka	15.24±0.10(Predicted)
form	clear liquid
color	Colorless to Almost colorless
Odor	ethereal fresh
optical activity	[α]23/D 5.8°, neat
Water Solubility	36 g/L (30 ºC)
Merck	14,6030
BRN	1718809
Dielectric constant	15.8（20℃）
LogP	1.223 (est)
CAS DataBase Reference	1565-80-6(CAS DataBase Reference)
FDA UNII	II2QJB35IC
NIST Chemistry Reference	1-Butanol, 2-methyl-, (S)-(1565-80-6)
EPA Substance Registry System	1-Butanol, 2-methyl-, (2S)- (1565-80-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07

Signal word

Warning

Hazard statements

H226-H332-H335

Precautionary statements

P210-P304+P340+P312

Hazard Codes

Risk Statements

10-20-37-66-2017/10/20

Safety Statements

46-24/25

RIDADR

UN 1105 3/PG 3

WGK Germany

RTECS

SB9800000

HazardClass

PackingGroup

III

HS Code

29051990

NFPA 704

	2
1		0

(S)-(-)-2-Methyl-1-butanol price More Price(17)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	65980	(S)-(?)-2-Methylbutanol ≥95.0% (sum of enantiomers, GC)	1565-80-6	100ml	$96.9	2024-03-01	Buy
Sigma-Aldrich	65980	(S)-(?)-2-Methylbutanol ≥95.0% (sum of enantiomers, GC)	1565-80-6	500ml	$164.8	2024-03-01	Buy
TCI Chemical	M0170	(S)-(-)-2-Methyl-1-butanol >98.0%(GC)	1565-80-6	25mL	$98	2024-03-01	Buy
Sigma-Aldrich	A83407	(S)-(?)-2-Methylbutanol 99%	1565-80-6	10g	$119	2024-03-01	Buy
TRC	M295215	(S)-(-)-2-Methylbutanol	1565-80-6	5g	$55	2021-12-16	Buy

Product number	Packaging	Price	Buy
65980	100ml	$96.9	Buy
65980	500ml	$164.8	Buy
M0170	25mL	$98	Buy
A83407	10g	$119	Buy
M295215	5g	$55	Buy

(S)-(-)-2-Methyl-1-butanol Chemical Properties,Uses,Production

Chemical Properties

clear colourless liquid

Uses

(S)-(?)-2-Methylbutanol can be used to prepare:

(S)-(?)-2-Methyl-1-butyloxy carbonyl amino hexyl isocyanate (MBI), which is used to synthesize isocyanate copolymers.
Chiral alkoxynaphathoic acid derivatives having liquid crystalline properties.
3,4-Bis[(S)-2-methylbutoxy]thiophene, a key intermediate for the synthesis of polythiophenes.

Uses

(S)-(-)-2-Methylbutanol can be used as a reactant to prepare:

Methylbutyl-2-(3-thienyl)acetate (MBTA) by esterification reaction with 3-thiophene acetic acid in the presence of an acid catalyst.
(2S)-2-Methyl-1-butanesulfenyl chloride by reacting with thioacetic acid using Mitsunobu reaction conditions.
(+)-Violapyrone C and (-)-myxalamide A.

Definition

ChEBI: The (S)-enantiomer of 2-methylbutan-1-ol.

General Description

rest mainly 3-methyl-1-butanol

Purification Methods

Reflux the butanol with CaO, distil, reflux with magnesium and again fractionally distil it. A small sample of highly purified material is obtained by fractional crystallisation after conversion into a suitable ester such as the trinitrophthalate or the 3-nitrophthalate. The latter is converted to the cinchonine salt in acetone and recrystallised from CHCl3 by adding pentane. The salt is saponified, extracted with ether, and fractionally distilled. [Terry et al. J Chem Eng Data 5 403 1960, Beilstein 1 IV 1666.]

(S)-(-)-2-Methyl-1-butanol synthesis

Synthesis of (S)-(-)-2-Methyl-1-butanol from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-

(S)-(-)-2-Methyl-1-butanol Preparation Products And Raw materials

Raw materials

(S)-(+)-2-Methylbutyric acid Sodium borohydride Tetrahydrofuran Ethyl acetate Lithium Aluminum Hydride

Preparation Products

S-2-Methylbutanal 2-methylbutyl butyrate (R)-2-Methylbutanol 1H-Pyrazole, 4-(1-methylpropyl)-, (S)- (9CI) 2-methyl butyl lactate

(S)-(-)-2-Methyl-1-butanol Suppliers

Global( 178)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Xi'an Kono chem co., Ltd.,	029-86107037 13289246953	info@konochemical.com	China	2995	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12468	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
CD Chemical Group Limited	+8615986615575	info@codchem.com	China	20356	58
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Hangzhou FandaChem Co.,Ltd.	55
Xi'an Kono chem co., Ltd.,	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
CD Chemical Group Limited	58
Alfa Chemistry	58

View Lastest Price from (S)-(-)-2-Methyl-1-butanol manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(S)-(-)-2-Methylbutanol >=95.0% (sum of enantiomers, GC) 1565-80-6	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
	2019-12-27	(S)-(-)-2-Methyl-1-butanol 1565-80-6	US $6.60 / KG	1KG	97%-99%	1kg-1000kg	Career Henan Chemical Co

(S)-(-)-2-Methylbutanol >=95.0% (sum of enantiomers, GC)
1565-80-6
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(S)-(-)-2-Methyl-1-butanol
1565-80-6
US $6.60 / KG
97%-99%
Career Henan Chemical Co

(S)-(-)-2-Methyl-1-butanol Spectrum

(S)-(-)-2-Methyl-1-butanol(1565-80-6)¹HNMR (S)-(-)-2-Methyl-1-butanol(1565-80-6)¹³CNMR (S)-(-)-2-Methyl-1-butanol(1565-80-6)IR1 (S)-(-)-2-Methyl-1-butanol(1565-80-6)Raman

1565-80-6((S)-(-)-2-Methyl-1-butanol)Related Search:

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Methyl 3-Methyl-1-butanol Methyl bromide

1of4

(S)-2-Methyl-1-butanol,99%e.e. (S)-(-)-2-Methylbutanol >=95.0% (suM of enantioMers, GC) (S)-(-)-2-Methylbutanol 99% (s)-1-butano (S)-2-methyl-butan-1-ol AMYL ALCOHOL, NORMAL ALCOHOL C5 1-PENTANOL ALCOHOL 1-PENTYL ALCOHOL FEMA 2056 BUTYLCARBINOL PRI-N-AMYL ALCOHOL (S)-(-)-2-Methyl-1-butanol (S)-(-)-2-Methylbutanol (S)-(-)-sec-Butylcarbinol 1-Butanol, 2-methyl-, (2S)- (S)-(-)-2-Methyl-1-butanol, 98+% (S)-(-)-2-Methyl-1-butanol, Active amyl alcohol Active amyl alcohol, Prim. active amyl alcohol (2S)-2-Methyl-1-butanol (2S)-2-Methylbutane-1-ol (S)-(-)-2-Methyl-1-butanol,99% D-2-METHYL-1-BUTANOL, ROT.-4.5 degrees 3-(4-((S)-()-2-Methyl-1-butanol active-Amyl Alcohol sec-Butylcarbinol N-BUTYLCARBINOL WATER STANDARD, AMYL ALCOHOL L-pentanol (S)-(-)-2-Methyl-1-butanol> AMYL ALCOHOL, N- AMYL ALCOHOL FUSEL OIL N-PENTYL ALCOHOL N-PENTANOL 1565-80-6 71410 30899195 Monofunctional Alkanes 1-Alkanols Monofunctional & 伪,蠅-Bifunctional Alkanes Building Blocks Analytical Standards Analytical Chromatography Product Catalog Alcohols Alphabetic Asymmetric Synthesis C2 to C6 ALCOHOL Organic Building Blocks Chiral Resolution Reagents Chiral Resolving Reagents PA - PEN Oxygen Compounds Building Blocks for Liquid Crystals Chiral Building Blocks Chiral Compounds (Building Blocks for Liquid Crystals) Functional Materials Glycidyl Compounds, etc. (Chiral)