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tert-Butyl bromoacetate

tert-Butyl bromoacetate
tert-Butyl bromoacetate structure
CAS No.
5292-43-3
Chemical Name:
tert-Butyl bromoacetate
Synonyms
BrCH2C(O)OC(CH3)3;1-Butylbromoacetate;T-BUTYL BROMOACETATE;tert-Butyl Bromoacet;BUTYLBROMOACETATE-TERT;T-BUTYL 2-BROMOACETATE;TERT-BUTYL BROMOACETATE;TERT-BUTYL 2-BROMOACETATE;tert-Butylbromoacetate,98%;tertiary butyl bromoacetate
CBNumber:
CB7853739
Molecular Formula:
C6H11BrO2
Formula Weight:
195.05
MOL File:
5292-43-3.mol

tert-Butyl bromoacetate Properties

Boiling point:
50 °C10 mm Hg(lit.)
Density 
1.338
refractive index 
n20/D 1.445(lit.)
Flash point:
121 °F
storage temp. 
0-6°C
form 
Liquid
Specific Gravity
1.333 (20/4℃)
color 
Clear colorless to yellow
Water Solubility 
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive 
Lachrymatory
BRN 
1753010
InChIKey
BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference
5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,F
Risk Statements  10-36/37/38
Safety Statements  26-24/25-16
RIDADR  UN 1993 3/PG 3
WGK Germany  3
19
Hazard Note  Irritant/Flammable/Lachrymatory
TSCA  T
HazardClass  3
PackingGroup  III
HS Code  29159080
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

tert-Butyl bromoacetate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 124230 tert-Butyl bromoacetate 98% 5292-43-3 10g $25.9 2018-11-13 Buy
Sigma-Aldrich 124230 tert-Butyl bromoacetate 98% 5292-43-3 50g $104 2018-11-13 Buy
TCI Chemical B1473 tert-Butyl Bromoacetate >98.0%(GC) 5292-43-3 25g $54 2018-11-22 Buy
TCI Chemical B1473 tert-Butyl Bromoacetate >98.0%(GC) 5292-43-3 250g $282 2018-11-22 Buy
Alfa Aesar A14917 tert-Butyl bromoacetate, 98% 5292-43-3 50g $92.1 2018-11-13 Buy

tert-Butyl bromoacetate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid

Uses

tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.

Purification Methods

Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]

tert-Butyl bromoacetate Preparation Products And Raw materials

Raw materials

Preparation Products


tert-Butyl bromoacetate Suppliers

Global( 298)Suppliers
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Kingfirst chemical (nanjing) co.,ltd
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Yancheng Longshen Chemical Co.,Ltd.
86-0515-88706880 86-18352073353
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Henan DaKen Chemical CO.,LTD.
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Henan Tianfu Chemical Co.,Ltd.
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Shanghai Time Chemicals CO., Ltd.
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ATK CHEMICAL COMPANY LIMITED
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View Lastest Price from tert-Butyl bromoacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-06 tert-Butyl bromoacetate
5292-43-3
US $2.00 / KG 1KG 99% 20KG career henan chemical co

tert-Butyl bromoacetate Spectrum


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