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Tetradecane

CAS No.
629-59-4
Chemical Name:
Tetradecane
Synonyms
N-TETRADECANE;Tetradecan;ALKANE C14;etradecane;n-Teradecane;1-TETRADECANE;Tetradecane C14;C10-C14;Linpar 14;TETRADECANE
CBNumber:
CB7854039
Molecular Formula:
C14H30
Molecular Weight:
198.39
MDL Number:
MFCD00008986
MOL File:
629-59-4.mol
MSDS File:
SDS
Last updated:2023-12-25 13:23:17

Tetradecane Properties

Melting point 5.5 °C (lit.)
Boiling point 252-254 °C (lit.)
Density 0.762 g/mL at 20 °C (lit.)
vapor density 6.83 (vs air)
vapor pressure 1 mm Hg ( 76.4 °C)
refractive index n20/D 1.429(lit.)
Flash point 211 °F
storage temp. Store below +30°C.
solubility <0.0001g/l
form Liquid
color Clear colorless
Odor at 100.00?%. mild waxy
Viscosity 2.81mm2/s
explosive limit 0.5-6.5%(V)
Water Solubility INSOLUBLE
BRN 1733859
InChIKey BGHCVCJVXZWKCC-UHFFFAOYSA-N
LogP 8.11 at 25℃
CAS DataBase Reference 629-59-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 03LY784Y58
NIST Chemistry Reference Tetradecane(629-59-4)
EPA Substance Registry System Tetradecane (629-59-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Danger
Hazard statements  H304
Precautionary statements  P301+P310-P331-P405-P501
Hazard Codes  Xn
Risk Statements  65-67
Safety Statements  23-24-62-24/25
WGK Germany  3
RTECS  XB8000000
Autoignition Temperature 455 °F
TSCA  Yes
HS Code  29011090
Toxicity LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
NFPA 704
1
1 0

Tetradecane price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.14767 n-Tetradecane for synthesis 629-59-4 50mL $39.3 2024-03-01 Buy
Sigma-Aldrich 172456 Tetradecane ≥99% 629-59-4 2g $48.4 2024-03-01 Buy
Sigma-Aldrich 8.14767 n-Tetradecane for synthesis 629-59-4 250ML $187 2024-03-01 Buy
Sigma-Aldrich 1.09608 n-Tetradecane reference substance for gas chromatography 629-59-4 5ml $258 2022-05-15 Buy
Sigma-Aldrich 04003 Tetradecane certified reference material, TraceCERT 629-59-4 100mg $144 2022-05-15 Buy
Product number Packaging Price Buy
8.14767 50mL $39.3 Buy
172456 2g $48.4 Buy
8.14767 250ML $187 Buy
1.09608 5ml $258 Buy
04003 100mg $144 Buy

Tetradecane Chemical Properties,Uses,Production

Description

Tetradecane is an alkane hydrocarbon containing 14 carbon atoms. It is majorly used for the organic synthesis, and used as a kind of organic solvent. Its binary mixtures with hexadecane can be used as phase change materials (PCMs) for cool storage in district cooling systems for refrigeration and air-conditioning. It can also be used as a standard analysis agent in chromatography analysis. In the determination of silicate ion, tetradecane can be used as an internal standard for calibration.

References

He, B. "00/01073 Tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for cool storage in district cooling systems."Fuel & Energy Abstracts 41.2(2000):117–118.
Bassler, Peter, et al. "Olefin is first absorbed from offgas stream formed in oxidation in a solvent comprising hydrocarbons, preferably tetradecane, subsequently desorbed therefrom, possibly freed of aliphatics, and recirculated to oxidation process; recirculation of propene use." US, US 7544818 B2. 2009.
Zhao, M., et al. "Modulated self-assembly of 4,4'- diphenyltetrathiafulvalene molecules on highly oriented pyrolytic graphite by n-tetradecane solvent." Nanotechnology 20.42 (2009):425301.
Chamblee, Theresa S., et al. "Quantitative analysis of the volatile constituents of lemon peel oil. Effects of silica gel chromatography on the composition of its hydrocarbon and oxygenated fractions." Journal of agricultural and food chemistry 39.1 (1991): 162-169.

Chemical Properties

colourless liquid

Chemical Properties

Tetradecane, C14H30, is a colorless liquid with moderate explosive potential and specific gravity 0.763. It occurs naturally in crude oil and in chickpea seeds, nectarines, and kiwi-fruit flowers. It may be released to the environment during its production and use, in the exhaust of motor vehicles, and in the effluent of landfills and industrial processes.

Uses

Tetradecane, often as a mixture with other straight-chain alkanes, is used as building block for detergents and animal feeds, and as a solvent and distillation chaser.

Uses

Tetradecane is a biomarker in dog hair for visceral leishmaniasis.

Uses

Organic synthesis, solvent standardized hydrocarbon, distillation chaser.

Definition

ChEBI: Tetradecane is a straight chain alkane consisting of 14 carbon atoms. It has a role as a plant metabolite and a volatile oil component.

Production Methods

Tetradecane is isolated from kerosene and gas oil fractions of crude oil by selective adsorption followed by fractional distillation.

General Description

Colorless liquid. Must be preheated before ignition can occur.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Saturated aliphatic hydrocarbons, such as Tetradecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.

Hazard

A fire hazard. Lower flammable limit in air 0.5%.

Health Hazard

ACUTE/CHRONIC HAZARDS: Explosion hazard: Moderate, in the form of vapor when exposed.

Carcinogenicity

Tetradecane is a cocarcinogen and tumor promoter in two-stage experiments of benzo[a]pyrene carcinogenicity in mice.

Purification Methods

Wash it successively with 4M H2SO4 and water. Dry it over MgSO4 and distil it several times under reduced pressure [Po. et al. J Am Chem Soc 108 5459 1986]. It is used as a standard in gas chromatography. [Beilstein 1 H 171, 1 IV 520.]

112-72-1
629-50-5
629-59-4
Synthesis of Tetradecane from 1-Tetradecanol
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View Lastest Price from Tetradecane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetradecane pictures 2023-12-26 Tetradecane
629-59-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Tetradecane pictures 2023-10-21 Tetradecane
629-59-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Tetradecane pictures 2023-10-11 Tetradecane
629-59-4
US $50.00-16.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
  • Tetradecane pictures
  • Tetradecane
    629-59-4
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • Tetradecane pictures
  • Tetradecane
    629-59-4
  • US $0.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
  • Tetradecane pictures
  • Tetradecane
    629-59-4
  • US $50.00-16.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
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