1,2,4,5-Tetrachlorobenzene
- CAS No.
- 95-94-3
- Chemical Name:
- 1,2,4,5-Tetrachlorobenzene
- Synonyms
- 1,2,4,5-tcb;1.2.4.5-Tetrac;TETRACHLOROBENZOL;rcrawastenumberu207;ethenyl trichloride;s-Tetrachlorobenzene;benzenetetrachloride;1,2,4,5-Tetrachlorob;Purity(GC) min. 99.0 %;Rcra waste number U207
- CBNumber:
- CB7854716
- Molecular Formula:
- C6H2Cl4
- Molecular Weight:
- 215.89
- MDL Number:
- MFCD00000549
- MOL File:
- 95-94-3.mol
- MSDS File:
- SDS
| Melting point | 139 °C |
|---|---|
| Boiling point | 240-246 °C(lit.) |
| Density | 1.858 |
| vapor pressure | 5 at 25 °C (extrapolated, Mackay et al., 1982) |
| refractive index | 1.5348 (estimate) |
| Flash point | >230 °F |
| storage temp. | 0-6°C |
| solubility | 0.0003g/l |
| form | Crystalline Solid |
| color | Light pink to gray |
| Water Solubility | insoluble. <0.1 g/100 mL at 21 ºC |
| BRN | 1618315 |
| Henry's Law Constant | 0.10 at 20 °C (gas stripping-GC, Oliver, 1985) |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. Reacts explosively with alkaline methanol solutions. |
| CAS DataBase Reference | 95-94-3(CAS DataBase Reference) |
| FDA UNII | 5N27529KGH |
| NIST Chemistry Reference | Benzene, 1,2,4,5-tetrachloro-(95-94-3) |
| EPA Substance Registry System | 1,2,4,5-Tetrachlorobenzene (95-94-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H410 | |||||||||
| Precautionary statements | P273-P301+P312+P330 | |||||||||
| Hazard Codes | Xn,T,F,N | |||||||||
| Risk Statements | 22-36/37/38-23/24/25-11-36-20/21/22-51/53 | |||||||||
| Safety Statements | 26-36-45-27-16-36/37-61 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | DB9450000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| HS Code | 29036990 | |||||||||
| Toxicity | Acute oral LD50 for rats 1,500 mg/kg, mice 1,035 mg/kg (quoted, RTECS, 1985). | |||||||||
| NFPA 704 |
|
1,2,4,5-Tetrachlorobenzene price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 131857 | 1,2,4,5-Tetrachlorobenzene 98% | 95-94-3 | 5g | $24.6 | 2024-03-01 | Buy |
| TCI Chemical | T0060 | 1,2,4,5-Tetrachlorobenzene | 95-94-3 | 25G | $39 | 2024-03-01 | Buy |
| TCI Chemical | T0060 | 1,2,4,5-Tetrachlorobenzene | 95-94-3 | 500G | $157 | 2024-03-01 | Buy |
| Alfa Aesar | A14318 | 1,2,4,5-Tetrachlorobenzene, 98% | 95-94-3 | 10g | $29.4 | 2024-03-01 | Buy |
| Alfa Aesar | A14318 | 1,2,4,5-Tetrachlorobenzene, 98% | 95-94-3 | 50g | $100 | 2024-03-01 | Buy |
1,2,4,5-Tetrachlorobenzene Chemical Properties,Uses,Production
Chemical Properties
white solid
Uses
1,2,4,5-Tetrachlorobenzene was used to study the environmental behavior of hexachlorobutadiene (HCBD).
Uses
Intermediate for herbicides and defoliants, insecticide, impregnant for moisture resistance, electrical insulation.
Definition
ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 4 and 5.
Environmental Fate
Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,4,5-
tetrachlorobenzene to 2,3,5,6-tetrachlorophenol (Ballschiter and Scholz, 1980). After incubation in
sewage sludge for 32 d under anaerobic conditions, 1,2,4,5-tetrachlorobenzene did not biodegrade
(Kirk et al., 1989).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,4,5-
tetrachlorobenzene underwent reductive dechlorination to 1,2,4-trichlorobenzene. The maximum
dechlorination rate, based on the recommended Michaelis-Menten model, was 5.5 nM/d
(Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,4,5-tetrachlorobenzene (1.1–1.2 mM/L) in an
acetonitrile-water mixture containing acetone (0.553 mM) as a sensitizer gave the following
products (% yield): 1,2,4-trichlorobenzene (25.3), 1,3-dichlorobenzene (8.1), 1,4-dichlorobenzene
(3.6), 2,2′,3,4′,5,5′,6-heptachlorobiphenyl (4.19), four hexachlorobiphenyls (6.78), four pentachlorobiphenyls
(2.33), one tetrachlorobiphenyl (0.32), 2,4,5-trichloroacetophenone, and (2,4,5-
trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified
photolysis products (% yield) included 1,2,4-trichlorobenzene (27.7), 1,3-dichlorobenzene (0.3),
1,4-dichlorobenzene (8.5), pentachlorobenzene (trace), 1,2,3,4-tetrachlorobenzene (0.45), 1,2,3,5-
tetrachlorobenzene (1.11), 2,2′,3,4′,5,5′,6-heptahlorobiphenyl (1.24), three hexachlorobiphenyls
(1.19), and four pentachlorobiphenyls (0.56) (Choudhry and Hutzinger, 1984). The sunlight
irradiation of 1,2,4,5-tetrachlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 28 d yielded 26 ppm heptachlorobiphenyl (Uyeta et al., 1976).
Chemical/Physical. Based on an assumed base-mediated 1% disappearance after 16 d at 85 °C
and pH 9.70 (pH 11.26 at °C), the hydrolysis half-life was estimated to be >900 yr (Ellington et
al., 1988).
Purification Methods
Crystallise it from EtOH, ether, *benzene, *benzene/EtOH or carbon disulfide. [Beilstein 5 IV 668.]
1,2,4,5-Tetrachlorobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 | sophieliu@speranzachem.com | China | 723 | 55 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81148696 +8615536356810 | 1047@dideu.com | China | 3408 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5601 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-519-519-85557386 | marketing1@neostarunited.com | China | 8349 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
View Lastest Price from 1,2,4,5-Tetrachlorobenzene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-26 | 1,2,4,5-Tetrachlorobenzene
95-94-3
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2020-01-13 | 1,2,4,5-Tetrachlorobenzene
95-94-3
|
US $0.10 / KG | 1KG | 99.0% | 1000 tons | Shaanxi Dideu Medichem Co. Ltd | |
 |
2020-01-10 | 1,2,4,5-Tetrachlorobenzene
95-94-3
|
US $1.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- 1,2,4,5-Tetrachlorobenzene
95-94-3
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1,2,4,5-Tetrachlorobenzene
95-94-3
- US $0.10 / KG
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
-
- 1,2,4,5-Tetrachlorobenzene
95-94-3
- US $1.00 / KG
- 99%
- Career Henan Chemical Co