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2,3-diaminonaphthalene

CAS No.
771-97-1
Chemical Name:
2,3-diaminonaphthalene
Synonyms
Naphthalene-2,3-diamine;DAN;2,3-DIAMINONAPHTHALENE;2,3-NAPHTHALENEDIAMINE;JACS-771-97-1;NAPHTHALENEDIAMINE;TIMTEC-BB SBB000127;2,3-DiaminonaphthaL;2,3-Diaminonapthalene;2,3-NAPHTHYLENEDIAMINE
CBNumber:
CB8101895
Molecular Formula:
C10H10N2
Molecular Weight:
158.2
MDL Number:
MFCD00004116
MOL File:
771-97-1.mol
Last updated:2023-08-18 13:05:06

2,3-diaminonaphthalene Properties

Melting point 197-203 °C
Boiling point 273.29°C (rough estimate)
Density 1.0968
refractive index 1.6392 (estimate)
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility pyridine: soluble50mg/mL
form Crystalline Powder
pka 5.36±0.10(Predicted)
color Green-brown to brown
Water Solubility Slightly soluble in water. Soluble in pyridine, dimethylsulfoxide, dimethyformamide, dil.hydrochloric acid, ethanol, ether and hot methanol.
BRN 2206394
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 771-97-1(CAS DataBase Reference)
FDA UNII 2BNZ6BRS87
EPA Substance Registry System 2,3-Naphthalenediamine (771-97-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H315-H319-H335-H350
Precautionary statements  P201-P202-P301+P312-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xn,T
Risk Statements  22-36/37/38-45
Safety Statements  26-45-53
RIDADR  2811
WGK Germany  3
8-10-23
TSCA  Yes
HS Code  29215900
NFPA 704
1
2 0

2,3-diaminonaphthalene price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 88461 2,3-Diaminonaphthalene BioReagent, suitable for fluorescence, ≥98.0% (HPLC) 771-97-1 25mg $52.2 2024-03-01 Buy
Sigma-Aldrich 88461 2,3-Diaminonaphthalene BioReagent, suitable for fluorescence, ≥98.0% (HPLC) 771-97-1 100mg $84.3 2024-03-01 Buy
TCI Chemical D1045 2,3-Diaminonaphthalene >98.0%(T) 771-97-1 1g $133 2024-03-01 Buy
TCI Chemical D1045 2,3-Diaminonaphthalene >98.0%(T) 771-97-1 5g $298 2024-03-01 Buy
Alfa Aesar A12993 2,3-Diaminonaphthalene, 97% 771-97-1 1g $126 2024-03-01 Buy
Product number Packaging Price Buy
88461 25mg $52.2 Buy
88461 100mg $84.3 Buy
D1045 1g $133 Buy
D1045 5g $298 Buy
A12993 1g $126 Buy

2,3-diaminonaphthalene Chemical Properties,Uses,Production

Description

2,3-Diaminonaphthalene is a highly selective colorimetric and fluorometric reagent for selenium detection and also used for the fluorometric determination of nitrite. It is also useful for detection of ketones and alpha-keto acids.
2,3-Diaminonaphthalene reacts with nitrosonium, which is formed from nitrite at low pH, to form the fluorescent dye 1 H-naphthotriazole. This method can be used to detect 10 nM to 10 uM of nitrite (NO2-) and is compatible with 96-well format.
Fluorometric probe for nitrite
Quantify 10 nM to 10 uM of nitrite
Yellow orange solid soluble in DMSO

Chemical Properties

colourless to white crystalline powder

Uses

In a reaction similar to that of DAF-FM , 2,3- diaminonaphthalene (D-7918) reacts with the nitrosonium cation that forms spontaneously from NO to form the fluorescent product 1H-naphthotriazole.Using 2,3-diaminonaphthalene, researchers have developed a rapid, quantitative fluorometric assay that can detect from 10 nM to 10 μM nitrite and is compatible with a 96-well microplate format.

Uses

2,3-Diaminonaphtaline (DAN) is used as a derivatisation-reagent for the determination of selenium at low detection limits.

Uses

2,3-Diaminonaphthalene is used in preparation of precursors for multi-layer 3D material comprising chiral organic sandwich compounds.

Reactions

2,3-diaminonaphthalene (DAN) is a fluorometric probe for nitrite. It reacts with nitrosonium, which is formed from nitrite at low pH, to form the fluorescent dye 1 H-naphthotriazole. This method can be used to detect 10 nM to 10 uM of nitrite (NO2-) and is compatible with 96-well format.
Reaction of 2,3-Diaminonaphthalene with NO2
Reaction of 2,3-Diaminonaphthalene with NO2.

Purification Methods

Crystallise the diamine from water, or dissolve it in 0.1M HCl, by heating to 50o. After cooling, the solution is extracted with decalin to remove fluorescent impurities and centrifuged. [Beilstein 13 IV 346.]

2050-75-1
771-97-1
Synthesis of 2,3-diaminonaphthalene from 2,3-DICHLORONAPHTHALENE
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from 2,3-diaminonaphthalene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,3-DIAMINONAPHTHALENE pictures 2023-08-18 2,3-DIAMINONAPHTHALENE
771-97-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
2,3-DIAMINONAPHTHALENE  pictures 2022-08-16 2,3-DIAMINONAPHTHALENE
771-97-1
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
2,3-DIAMINONAPHTHALENE pictures 2021-09-27 2,3-DIAMINONAPHTHALENE
771-97-1
US $10.00 / KG 100KG 99% 100 mt Hebei Guanlang Biotechnology Co., Ltd.
2,3-Diaminonaphthalene(ForNoDetection) NAPHTHALENEDIAMINE TIMTEC-BB SBB000127 2,3-Diaminonaphthalene,97% 2,3-Diaminonapthalene 2,3-DiaMinonaphthalene, 97% 1GR 2,3-DiaMinonaphthalene, 97% 5GR 2,3-DiaMinonaphthalene [for BiocheMical Research] DAN 2,3-Naphthalenediamine 2,3-NAPHTHYLENEDIAMINE Diaminonaphthalene test solution(ChP) 2,3-Diaminonaphthalene *CAS 771-97-1* JACS-771-97-1 2,3-Diaminonaphthalene > 2,3-Diaminonaphthalene[forBiochemicalResearch]> 2,3-DiaminonaphthaL 2,3-DIAMINONAPHTHALENE ISO 9001:2015 REACH Diaminonaphthalene test solution 2,3-DIAMINONAPHTHALENE Extra Pure Naphthalene-2,3-diamine 2,3-NAPHTHALENEDIAMINE 2,3-DIAMINONAPHTHALENE DAN 771-97-1 771-91-1 Nitric Oxide and Oxygen Probes Nitric Oxide Probes Fluorescent Indicators and Probes Fluorescent Probes, Labels, Particles and Stains Biochemicals and Reagents BioChemical Naphthalene derivatives