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Tris(2-phenylpyridine)iridium (Ir(ppy)3)

CAS No.
94928-86-6
Chemical Name:
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Synonyms
Ir(ppy)3;TRIS(2-PHENYLPYRIDINE)IRIDIUM;fac-Tris(2-phenylpyridine)iridium;sublimed grade;tris[2-(2-pyridyl)phenyl]iridium;TRIS(2-PHENYLPYRIDINE)IRIDIUM (III);Tris[2-phenylpyridinato-C2,N]iridium(III);(ppy)3Ir;Tris(2-phenyL;pyridine)iridium
CBNumber:
CB8112370
Molecular Formula:
C33H24IrN3
Molecular Weight:
654.79
MDL Number:
MFCD04039766
MOL File:
94928-86-6.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Properties

Melting point 328°C
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color yellow
Sensitive air sensitive
CAS DataBase Reference 94928-86-6(CAS DataBase Reference)
Absorption λmax?282, 377 nm?in THF

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
0
2 0

Tris(2-phenylpyridine)iridium (Ir(ppy)3) price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 694924 Tris[2-phenylpyridinato-C2,N]iridium(III) sublimed grade 94928-86-6 250mg $715 2024-03-01 Buy
Sigma-Aldrich 688096 Tris[2-phenylpyridinato-C2,N]iridium(III) 99% 94928-86-6 250mg $402 2024-03-01 Buy
TCI Chemical T3716 Tris(2-phenylpyridinato)iridium(III) >98.0%(HPLC) 94928-86-6 200mg $250 2024-03-01 Buy
TCI Chemical T1946 Tris(2-phenylpyridinato)iridium(III) (purified by sublimation) >95.0%(HPLC) 94928-86-6 200mg $533 2024-03-01 Buy
Strem Chemicals 77-7015 Tris(2-phenylpyridinato-C2,N)iridium(III), 95% 94928-86-6 50mg $64 2024-03-01 Buy
Product number Packaging Price Buy
694924 250mg $715 Buy
688096 250mg $402 Buy
T3716 200mg $250 Buy
T1946 200mg $533 Buy
77-7015 50mg $64 Buy

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties,Uses,Production

Applications

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.

Reactions

  1. Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
  2. Photocatalyst for trifluoromethylation of alkenes and alkynes
  3. Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
  4. Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
  5. Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
  6. Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides
Reactions of 94928-86-6_1
Reactions of 94928-86-6_2

Description

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.

Chemical Properties

Light yellow to red solid

Uses

suzuki reaction

Uses

Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.

General Description

Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 233)Suppliers
Supplier Tel Email Country ProdList Advantage
Springchem New Material Technology Co.,Limited
+86-021-62885108 +8613917661608 info@spring-chem.com China 2068 57
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
QINGDAO HONG JIN CHEMCIAL CO.,LTD.
532-83657313 hjt@hong-jin.com China 228 58
HaBo Hong Kong Co., Limited.
+86-25-18512596065 info@habotech.com CHINA 933 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

View Lastest Price from Tris(2-phenylpyridine)iridium (Ir(ppy)3) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Fac-Ir (ppy)3 pictures 2024-04-19 Fac-Ir (ppy)3
94928-86-6
US $0.00 / g 1g 99.90% 100kgs Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Tris(2-phenylpyridine)iridium (Ir(ppy)3) pictures 2023-03-16 Tris(2-phenylpyridine)iridium (Ir(ppy)3)
94928-86-6
US $0.00 / kg 1kg 98.0%min 100kg LY Global chemicals co.,ltd .
Tris(2-phenylpyridine)iridium (Ir(ppy)3) pictures 2022-10-01 Tris(2-phenylpyridine)iridium (Ir(ppy)3)
94928-86-6
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
  • Fac-Ir (ppy)3 pictures
  • Fac-Ir (ppy)3
    94928-86-6
  • US $0.00 / g
  • 99.90%
  • Zhejiang Free Trade Zone Violet Trade Co., Ltd.

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Spectrum

Tris(2-phenylpyridinato) iridium(III),98+% Tris[2-phenylpyridinato-C2,N]iridium(III) sublimed grade Tris(2-phenylpyridine)iridium (Ir(ppy)3) iridium(3+),2-phenylpyridine Tris(2-phenylpyridine) TRIS(2-PHENYLPYRIDINE)IRIDIUM(III) OLED GREEN LIGHT EMITTER ΛPL 512 NM (FILM) Tris(2-phenylpyridinato)iridium(III) (purified by sublimation) REF DUPL: fac-tris(2-(2-pyridinyl)phenyl)iridium tris(2-(pyridin-2-yl)phenyl)iridium tris[2-(2-pyridinyl-κN)phenyl-κC] Tris[2-phenylpyridinato-C2,N]iridium(III),Ir(ppy)3, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC] Tris(2-phenylpyridin Ir(ppy)3, Iridium, tris[2-(2-pyridinyl-KN)phenyl-KC] Tris(2-phenylpyridinato)iridium(III) Ir(ppy)3 , Tris(2-phenylpyridine)iridiuM 1Tris(2-phenylpyridine)iridiuM(III)/ Ir(ppy)3 Tris[2-phenylpyridinato-C2 (ppy)3Ir Tris(2-phenylpyridine-C2,N') IridiuM (III) Iridium, tris(2-phenylpyidine) Tris(2-phenylpyridinato)iridium(III), 98%, purified by sublimation Tris(2-phenylpyridinato)iridium(III) (purified Tris(2-phenylpyridinato)iridium(III)(purifiedbysublimation)Ir(PPY) fac-Tris(2-phenylpyridyl)iridium Ter(2-Phenyl-pyridine) iridium Tris(2-phenylpyridine)iridium(Ⅲ), purified by sublimation pyridine)iridium Tris(2-phenyL Iridium, tris[2-(2-pyridinyl-kN)phenyl-kC]-, (OC-6-22)- Tris(2-phenylpyridine)iridium (Ir(ppy)3) ISO 9001:2015 REACH TRIS(2-PHENYLPYRIDINE)IRIDIUM TRIS(2-PHENYLPYRIDINE)IRIDIUM (III) Ir(ppy)3 Tris[2-phenylpyridinato-C2,N]iridium(III) fac-Tris(2-phenylpyridine)iridium tris[2-(2-pyridyl)phenyl]iridium sublimed grade Tris[2-phenylpyridinato-C2,N]iridium 94928-86-6 C30H24IrN3 C33H27IrN3 C33H24IrN3 Electronic Chemicals electronic Classes of Metal Compounds Highly Purified Reagents Ir (Iridium) Compounds Other Categories Refined Products by Sublimation Transition Metal Compounds olde Materials oled materials fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials OLED 94928-86-6