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ChemicalBook >> CAS DataBase List >>Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Structure
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride structure
CAS No.
228120-95-4
Chemical Name:
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Synonyms
(S)-RuCl[(p-cymene)(T-BINAP)]Cl;[RuCl(p-cymene)((S)-tolbinap)]Cl;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl
CBNumber:
CB81181041
Molecular Formula:
C58H52Cl2P2Ru
Molecular Weight:
982.97
MDL Number:
MFCD09753014
MOL File:
228120-95-4.mol
Last updated:2023-06-08 17:06:36
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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form solid
color yellow to dark brown
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
HS Code  2843.90.0000

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692964 (S)-RuCl[(p-cymene)(T-BINAP)]Cl 228120-95-4 500mg $51.2 2024-03-01 Buy
Sigma-Aldrich 692964 (S)-RuCl[(p-cymene)(T-BINAP)]Cl 228120-95-4 100mg $32.9 2023-06-20 Buy
TCI Chemical R0149 [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 200mg $50 2024-03-01 Buy
TCI Chemical R0149 [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 1g $162 2024-03-01 Buy
Strem Chemicals 44-0089 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
692964 500mg $51.2 Buy
692964 100mg $32.9 Buy
R0149 200mg $50 Buy
R0149 1g $162 Buy
44-0089 250mg $53 Buy

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chemical Properties,Uses,Production

Reactions

1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.
Reactions of 228120-95-4_1
Reactions of 228120-95-4_2

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Suppliers

Global( 47)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
changzhou huayang technology co., ltd 		+8615250961469 2571773637@qq.com China 9821 58
Alfa Chemistry 		+1-5166625404 Info@alfa-chemistry.com United States 21317 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
Zibo Hangyu Biotechnology Development Co., Ltd 		+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 11013 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Supplier Advantage
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Richest Group Ltd 		58
changzhou huayang technology co., ltd 		58
Alfa Chemistry 		58
Shaoxin Catsyn Co., Ltd. 		58
Zibo Hangyu Biotechnology Development Co., Ltd 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76

View Lastest Price from Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride pictures 2019-08-09 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
228120-95-4
 US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co

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(R)-(+)-TolBINAP 2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (S)-RuCl[(p-cymene)(T-BINAP)]Cl [RuCl(p-cymene)((S)-tolbinap)]Cl Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl -binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride 228120-95-4 C58H54ClP2RuCl8722 Ru