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(Bromomethyl)cyclopropane

CAS No.
7051-34-5
Chemical Name:
(Bromomethyl)cyclopropane
Synonyms
CYCLOPROPYLMETHYL BROMIDE;Cyclopropane, (bromomethyl)-;CPMBr;(Bromomethyl)cyclopr;(Xiu Jiaji)cyclopropane;BroMoMethyl)cyclopropan;Cyclopropylmethylbromid;Roflumilast impurity 18;CYCLOPROPYLMETYL BROMIDE;Bromo(cyclopropyl)methane
CBNumber:
CB8119915
Molecular Formula:
C4H7Br
Molecular Weight:
135
MDL Number:
MFCD00001306
MOL File:
7051-34-5.mol
MSDS File:
SDS
Last updated:2023-12-26 11:30:52

(Bromomethyl)cyclopropane Properties

Melting point 87-90 °C
Boiling point 105-107 °C(lit.)
Density 1.392 g/mL at 25 °C(lit.)
refractive index n20/D 1.457(lit.)
Flash point 107 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
Specific Gravity 1.392
color Clear colorless to slightly colored
Water Solubility Not miscible in water.
BRN 605296
Stability Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKey AEILLAXRDHDKDY-UHFFFAOYSA-N
CAS DataBase Reference 7051-34-5(CAS DataBase Reference)
FDA UNII D8ZPP7X54B
NIST Chemistry Reference Cyclopropane, (bromomethyl)-(7051-34-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H302
Precautionary statements  P210-P233-P240-P241-P242-P301+P312
Hazard Codes  Xi,F,Xn
Risk Statements  10-36/37/38-22
Safety Statements  23-24/25-37/39-26-16-36/37/39
RIDADR  UN 1993 3/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29035990
NFPA 704
2
2 0

(Bromomethyl)cyclopropane price More Price(49)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 242403 (Bromomethyl)cyclopropane 97% 7051-34-5 1g $54 2024-03-01 Buy
Sigma-Aldrich 242403 (Bromomethyl)cyclopropane 97% 7051-34-5 5g $162 2024-03-01 Buy
Alfa Aesar L01122 (Bromomethyl)cyclopropane, 97% 7051-34-5 1g $46.4 2024-03-01 Buy
Alfa Aesar L01122 (Bromomethyl)cyclopropane, 97% 7051-34-5 5g $132 2024-03-01 Buy
Alfa Aesar L01122 (Bromomethyl)cyclopropane, 97% 7051-34-5 25g $522 2024-03-01 Buy
Product number Packaging Price Buy
242403 1g $54 Buy
242403 5g $162 Buy
L01122 1g $46.4 Buy
L01122 5g $132 Buy
L01122 25g $522 Buy

(Bromomethyl)cyclopropane Chemical Properties,Uses,Production

Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description

(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Chemical Properties

Colorless to yellow liquid

Uses

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

2516-33-8
7051-34-5
Synthesis of (Bromomethyl)cyclopropane from Cyclopropyl carbinol
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View Lastest Price from (Bromomethyl)cyclopropane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Bromomethyl)cyclopropane pictures 2024-04-24 (Bromomethyl)cyclopropane
7051-34-5
US $20.00 / KG 1KG 99% 200 tons/ year Speranza Chemical Co., Ltd.
(Bromomethyl)cyclopropane pictures 2024-04-24 (Bromomethyl)cyclopropane
7051-34-5
US $5.00 / kg 1kg ≥98% 500mt/year Jinan Finer Chemical Co., Ltd
(Bromomethyl)cyclopropane pictures 2023-12-26 (Bromomethyl)cyclopropane
7051-34-5
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
CPMBr Cyclopropylcarbinyl bromide Bromo(cyclopropyl)methane 1-(Bromomethyl)cyclopropane, 95+% (Bromomethyl)cyclopropane,Cyclopropylmethyl bromide (Bromomethyl)cyclopr (Bromomethyl)cyclopropane,96% Cyclopropane Methyl Chloride BroMoMethyl)cyclopropan (Xiu Jiaji)cyclopropane Cyclopropanemethyl bromide 1-(BROMOMETHYL)CYCLOPROPANE (BROMOMETHYL)CYCLOPROPANE CYCLOPROPYLMETYL BROMIDE CyclopropylmethylBromide96% Cyclopropyl bromo methane Cyclopropylmethylbromid Roflumilast impurity 18 (Bromomethyl)cyclopropane, 96%, for synthesis (BROMOMETHYL)CYCLOPROPANE 7051-34-5 (Bromomethyl)cyclopropane ISO 9001:2015 REACH CYCLOPROPYLMETHYL BROMIDE Cyclopropane, (bromomethyl)- 7051-34-5 051-34-5 C3H5CH2Br C4H7Br HALOGEN Alkyl Building Blocks Organic Building Blocks Halogenated Hydrocarbons Methyl Halides Halides Methyl Halides Ring Systems Cycloalkanes Miscellaneous Reagents bc0001