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4-Chloroaniline

4-Chloroaniline
4-Chloroaniline structure
CAS No.
106-47-8
Chemical Name:
4-Chloroaniline
Synonyms
NSC 36941;NCI-C02039;4-Chloranilin;4-Choraniline;p-Chloraniline;4-CHLORANILINE;chloro-4aniline;chloroanilinep-;p-chloro-anilin;Pp chloraniline
CBNumber:
CB8147309
Molecular Formula:
C6H6ClN
Formula Weight:
127.57
MOL File:
106-47-8.mol

4-Chloroaniline Properties

Melting point:
67-70 °C(lit.)
Boiling point:
232 °C(lit.)
Density 
1,43 g/cm3
vapor density 
4.4 (vs air)
vapor pressure 
0.15 mm Hg ( 25 °C)
refractive index 
1.5546
Flash point:
120°C
storage temp. 
2-8°C
solubility 
2.2g/l
pka
4.15(at 25℃)
form 
Crystalline Solid
color 
Beige to brown-purple
Specific Gravity
1.2417
PH
6.9 (1g/l, H2O, 20℃)
Water Solubility 
0.3 g/100 mL (20 ºC)
Merck 
14,2118
BRN 
471359
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates, nitrous acid. May be light sensitive.
CAS DataBase Reference
106-47-8(CAS DataBase Reference)
NIST Chemistry Reference
p-Chloroaniline(106-47-8)
EPA Substance Registry System
Benzenamine, 4-chloro-(106-47-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N,F
Risk Statements  45-23/24/25-43-50/53-52/53-39/23/24/25-11-51/53
Safety Statements  53-45-60-61-36/37-16-7
RIDADR  UN 2018 6.1/PG 2
WGK Germany  3
RTECS  BX0700000
8-10-23
Autoignition Temperature 685 °C
Hazard Note  Toxic/Possible Carcinogen
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214210
Hazardous Substances Data 106-47-8(Hazardous Substances Data)
Toxicity LD50 orally in rats: 0.31 g/kg (Smyth)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

4-Chloroaniline price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 35823 4-Chloroaniline PESTANAL , analytical standard 106-47-8 1g $18.4 2018-11-13 Buy
Sigma-Aldrich 1111908 4-Chloroaniline United States Pharmacopeia (USP) Reference Standard 106-47-8 200mg $356 2018-11-13 Buy
TCI Chemical C0112 4-Chloroaniline >99.0%(GC) 106-47-8 25g $15 2018-11-22 Buy
TCI Chemical C0112 4-Chloroaniline >99.0%(GC) 106-47-8 500g $60 2018-11-22 Buy
Alfa Aesar A12879 4-Chloroaniline, 98% 106-47-8 1000g $94.2 2018-11-15 Buy

4-Chloroaniline Chemical Properties,Uses,Production

Chemical Properties

White or pale-yellow solid.Soluble in hot water and organic solvents.

Uses

Dye intermediate, pharmaceuticals, agricultural chemicals.

Definition

ChEBI: A chloroaniline in which the chloro atom is para to the aniline amino group.

General Description

A white or pale yellow solid. Melting point 69.5°C.

Air & Water Reactions

Insoluble in cold water. Soluble in hot water [Hawley].

Reactivity Profile

4-Chloroaniline is incompatible with oxidizing agents. Also incompatible with acids, acid chlorides, acid anhydrides and chloroformates. Subject to exothermic decomposition during high-temperature distillation. Incompatible with nitrous acid.

Hazard

Toxic by inhalation and ingestion. Possible carcinogen.

Health Hazard

Inhalation or ingestion causes bluish tint to fingernails, lips, and ears indicative of cyanosis; headache, drowsiness, and nausea, followed by unconsciousness. Liquid can be absorbed through skin and cause similar symptoms. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Irritating and toxic hydrogen chloride and oxides of nitrogen may form in fires.

Safety Profile

Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by ingestion, inhalation, sh contact, subcutaneous, and intravenous routes. A skin and severe eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland NOx. See also ANILINE DYES

Purification Methods

Crystallise the aniline from MeOH, pet ether (b 30-60o), or 50% aqueous EtOH, then *benzene/pet ether (b 60-70o), and then dry it in a vacuum desiccator. It can be distilled under vacuum (b 75-77o/3mm). It sublimes in a very high vacuum. The acetate crystallises from aqueous MeOH (m 178o, 180o) or EtOH or AcOH (m 173-174o) and has b 331.3o/760mm. [Beilstein 12 III 1325, 12 IV 1116.]

4-Chloroaniline Preparation Products And Raw materials

Raw materials

Preparation Products


4-Chloroaniline Suppliers

Global( 314)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19919 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21924 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 24196 60
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20516 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23983 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20094 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 4660 58
Shanghai Boyle Chemical Co., Ltd. Mr Qiu:021-50182298(Demestic market) Miss Xu:021-50180596(Abroad market)
+86-21-57758967 sales@boylechem.com China 2214 55

View Lastest Price from 4-Chloroaniline manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-18 4-Chloroaniline
106-47-8
US $1.00 / kg 1kg 98% 1000kg career henan chemical co

4-Chloroaniline Spectrum


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