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(S)-(+)-Benzyl glycidyl ether

(S)-(+)-Benzyl glycidyl ether Structure
(S)-(+)-Benzyl glycidyl ether structure
CAS No.
16495-13-9
Chemical Name:
(S)-(+)-Benzyl glycidyl ether
Synonyms
(S)-BENZYL GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;BENZYL (S)-(+)-GLYCIDYL ETHER;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
CBNumber:
CB8164324
Molecular Formula:
C10H12O2
Molecular Weight:
164.2
MDL Number:
MFCD00054428
MOL File:
16495-13-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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(S)-(+)-Benzyl glycidyl ether Properties

alpha 5.1 º (c=5 in toluene)
Boiling point 130 °C (0.1 mmHg)
Density 1.072 g/mL at 20 °C(lit.)
refractive index n20/D 1.517
Flash point >110°C
storage temp. 2-8°C
solubility Chloroform, Ethanol
form Oil
color Colourless
Specific Gravity 1.077
optical activity [α]20/D +5.1°, c = 5 in toluene
BRN 5246495
CAS DataBase Reference 16495-13-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  TX2860030
HS Code  29109000
Toxicity mic-sat 660 nmol/plate MUREAV 298,197,1993
NFPA 704
0
2 0

(S)-(+)-Benzyl glycidyl ether price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 363537 (S)-(+)-Glycidyl benzyl ether 99% 16495-13-9 1g $9.64 2024-03-01 Buy
TCI Chemical B2239 Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) 16495-13-9 1g $16 2024-03-01 Buy
TCI Chemical B2239 Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) 16495-13-9 5g $25 2024-03-01 Buy
Alfa Aesar L14033 Benzyl (S)-(+)-glycidyl ether, 98+% 16495-13-9 1g $72.65 2024-03-01 Buy
Alfa Aesar L14033 Benzyl (S)-(+)-glycidyl ether, 98+% 16495-13-9 5g $236.65 2024-03-01 Buy
Product number Packaging Price Buy
363537 1g $9.64 Buy
B2239 1g $16 Buy
B2239 5g $25 Buy
L14033 1g $72.65 Buy
L14033 5g $236.65 Buy

(S)-(+)-Benzyl glycidyl ether Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.

Uses

(S)-(+)-Glycidyl benzyl ether may be employed for the total asymmetric synthesis of (+)-gigantecin.

General Description

(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-Benzyl glycidyl ether Suppliers

Global( 259)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 906 58
Jinan Carbotang Biotech Co.,Ltd. 		+8615866703830 figo.gao@foxmail.com China 6992 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Changzhou Ditong Chemical Co.,Ltd 		+86-0519-88299272 info@edengenechem.com China 2169 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49390 58
career henan chemical co 		+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Jinan Liheng Biotechnology Co., Ltd. 		15865262812 info@lihengpharm.com CHINA 938 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
Shanghai Arbor Chemical Co., Ltd. 		58
Jinan Carbotang Biotech Co.,Ltd. 		58
Accela ChemBio Inc. 		58
Changzhou Ditong Chemical Co.,Ltd 		58
Alchem Pharmtech,Inc. 		58
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Jinan Liheng Biotechnology Co., Ltd. 		58

View Lastest Price from (S)-(+)-Benzyl glycidyl ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-(+)-Benzyl glycidyl ether pictures 2023-03-14 (S)-(+)-Benzyl glycidyl ether
16495-13-9
 US $65.00 / kg 1kg 99% 5000 tons Hebei Duling International Trade Co. LTD
(S)-(+)-Benzyl glycidyl ether pictures 2023-03-06 (S)-(+)-Benzyl glycidyl ether
16495-13-9
 US $10.70 / Kg/Drum 10g 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE pictures 2020-01-08 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE
16495-13-9
 US $2.00 / KG 1KG 98% 100g , 1kg, 5kg , 50kg Career Henan Chemical Co

(S)-(+)-Benzyl glycidyl ether Spectrum

(S)-(+)-Benzyl glycidyl ether(16495-13-9)1HNMR(S)-(+)-Benzyl glycidyl ether(16495-13-9)IR(S)-(+)-Benzyl glycidyl ether(16495-13-9)Raman(S)-(+)-Benzyl glycidyl ether(16495-13-9)FT-IR

16495-13-9((S)-(+)-Benzyl glycidyl ether)Related Search:

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(S)-(-)-Trityl glycidyl ether (R)-(-)-BENZYL GLYCIDYL ETHER,(R)-BENZYL GLYCIDYL ETHER,(R)-(-)-BENZYL GLYCIDYL ETHER, 98+% BENZYL GLYCIDYL ETHER

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(S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE (S)-(+)-1-BENZYLOXY-2,3-EPOXYPROPANE (S)-1-BENZYLOXY-2,3-EPOXYPROPANE (S)-(+)-BENZYL GLYCIDYL ETHER (S)-BENZYLOXYMETHYL-OXIRANE (s)-o-benzylglycidol (S)-(+)-Glycidyl benzyl ether puriss., >=99.0% (sum of enantiomers, GC) (S)-Benzyl Glycidyl Ether,99%e.e. (+)-BENZYL (S)-GLYCIDYL ETHER BENZYL (S)-(+)-GLYCIDYL ETHER BENZYL (S)-(+)-GLYCIDYL ETHER, 99+% (2S)-2β-(Benzyloxymethyl)oxirane (S)-Glycidylbenzyl ether (S)-(+)-GLYCIDYL BENZYL ETHER ((S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE) Benzyl (S)-(+)-glycidyl ether, 98+% (S)-(+)-Benzyl glycidyl ether,98% Benzyl (S)-(+)-2,3-Epoxypropyl Ether (S)-(+)-1-Benzyloxy-2,3-epoxypropane (S)-(+)-2-(Benzyloxymethyl)oxirane Benzyl (S)-(+)-glycidyl ether, ee: 99% Benzyl (S)-(+)-glycidyl ether, 98%, ee: 99% (S)-Benzyl glycidyl ether 97% (2S)-2-(phenylmethoxymethyl)oxirane 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE Benzyl (S)-(+)-Glycidyl Ether > Oxirane, 2-[(phenylmethoxy)methyl]-, (2S)- (S)-BENZYL GLYCIDYL ETHER (2S)-2-[(Benzyloxy)methyl]oxirane (+)-Benzyl glycidyl ether (S)-Benzylglycidyether 16495-13-9 Cd0H12O2 Asymmetric Synthesis Epoxides Organic Building Blocks Oxiranes Glycidyl Compounds, etc. (Chiral) Simple 3-Membered Ring Compounds Chiral Building Blocks CHIRAL COMPOUNDS Glycidyl Compounds, etc. (Chiral) Oxiranes Simple 3-Membered Ring Compounds Synthetic Organic Chemistry Chiral Compound chiral Chiral Building Blocks