ChemicalBook >> CAS DataBase List >>COPPER(II) TRIFLUOROMETHANESULFONATE
COPPER(II) TRIFLUOROMETHANESULFONATE
- CAS No.
- 34946-82-2
- Chemical Name:
- COPPER(II) TRIFLUOROMETHANESULFONATE
- Synonyms
- Cu(OTf)2;COPPER(II) TRIFLATE;copper(II) bis(trifluoromethanesulfonate);COPPER TRIFLATE;CUPRIC TRIFLUOROMETHANESULFONATE;COPPER(II) TRIFLUOROMETHANESULPHONATE;Bis(((trifluoromethyl)sulfonyl)oxy)copper;Copper(II) trifL;CUPRIC-2-TRIFLATE;Copper (Ii) Trifluorome
- CBNumber:
- CB8184128
- Molecular Formula:
- C2CuF6O6S2
- Molecular Weight:
- 361.68
- MDL Number:
- MFCD00077492
- MOL File:
- 34946-82-2.mol
- MSDS File:
- SDS
Last updated:2023-08-18 18:37:42
| Melting point | ≥300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Water (Slightly) |
| form | Powder |
| color | White to slightly blue or light gray |
| Water Solubility | Soluble in water. |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 6: forms irreversible hydrate |
| BRN | 4028198 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
| Stability | hygroscopic |
| InChIKey | SBTSVTLGWRLWOD-UHFFFAOYSA-L |
| CAS DataBase Reference | 34946-82-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H318-H314 | |||||||||
| Precautionary statements | P280-P305+P351+P338-P310-P260-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501-P260h-P301+P330+P331-P303+P361+P353-P501a | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45-27 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Irritant/Hygroscopic | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29049085 | |||||||||
| NFPA 704 |
|
COPPER(II) TRIFLUOROMETHANESULFONATE price More Price(61)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 283673 | Copper(II) trifluoromethanesulfonate 98% | 34946-82-2 | 5g | $152 | 2024-03-01 | Buy |
| Sigma-Aldrich | 283673 | Copper(II) trifluoromethanesulfonate 98% | 34946-82-2 | 25g | $427 | 2024-03-01 | Buy |
| TCI Chemical | T1292 | Copper(II) Trifluoromethanesulfonate >98.0%(T) | 34946-82-2 | 5g | $24 | 2024-03-01 | Buy |
| TCI Chemical | T1292 | Copper(II) Trifluoromethanesulfonate >98.0%(T) | 34946-82-2 | 25g | $72 | 2024-03-01 | Buy |
| Alfa Aesar | 040133 | Copper(II) trifluoromethanesulfonate, 99% min | 34946-82-2 | 10g | $116 | 2024-03-01 | Buy |
COPPER(II) TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production
Reaction
- Ring-Opening of epoxides and aziridines.
- Asymmetric conjugate addition of organozinc reagents to α,β-unsaturated ketones.
- Electrophilic addition of olefins.
- Asymmetric aziridination of olefins.
- Asymmetric cycloadditions and aldol condensations.
- Asymmetric Kharasch oxidation.
- Asymmetric Michael addition of enamides.
- Asymmetric O-H or O-R insertion reactions.
- Enantioselective intramolecular aminooxygenation of alkenes.
- Enantioselective addition of dialkylzinc reagents to N-acylpyridinium salts.
- Pd-catalyzed C-H functionalizations of oximes with arylboronic acids.
- Used as a Lewis acid in the Nazarov cyclization.
- Catalyst in the diacetoxylation olefins.
- Catalyst in the meta-selective direct arylation of α-aryl carbonyl compounds.
- Catalyst in the three-component coupling of amines, aldehydes, and alkynes.
Chemical Properties
white to slightly blue or light grey cryst. powder
Uses
Copper(II) trifluoromethanesulfonate is a mild lewis acid. It is used as catalyst which promotes dehydration of alcohols and diols to alkenes at ambient temperatures. It is widely used to generate carbenoid species from ?-diazo esters and ketones, via in situ reduction to the Cu(I) species. It is also promotes the reaction between diazo esters and imines to give aziridines. It catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes, Friedel-Crafts alkylation, acylation reactions of aromatics and addition of trimethylsilyl cyanide to carbonyl compounds.
Purification Methods
Dissolve it in MeCN, add dry Et2O until cloudy and cool at -20o in a freezer. The light blue precipitate is collected and dried in a vacuum oven at 130o/20mm for 8hours. It has 737nm ( 22.4 max M1cm -1) in AcOH. [Salomon & Kochi J Am Chem Soc 95 330 1973]. It has also been dried in a vessel at 0.1Torr by heating with a Fischer burner [Andrist et al. J Org Chem 43 3422 1978]. It has been dried at 110-120o/5mm for 1hour before use and forms a *benzene complex which should be handled in a dry box because it is air sensitive [Kobayashi et al. Chem Pharm Bull Jpn 28 262 1980, Salomon & Kochi J Am Chem Soc 95 330 1973]. [Beilstein 3 IV 34.]
COPPER(II) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 316)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4242 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10248 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 6992 | 58 |
| HaBo Hong Kong Co., Limited. | +86-25-18512596065 | info@habotech.com | CHINA | 933 | 58 |
Related articles
- Applications of Copper(Ⅱ) Trifluoromethanesulfonate
- Copper(Ⅱ) Trifluoromethanesul is a powerful Lewis acid. It is a mild lewis acid, used as catalyst which promotes dehydration o....
- Nov 1，2019
View Lastest Price from COPPER(II) TRIFLUOROMETHANESULFONATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-09-06 | COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
 |
2023-08-18 | COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2022-10-10 | COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- COPPER(II) TRIFLUOROMETHANESULFONATE
34946-82-2
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
34946-82-2(COPPER(II) TRIFLUOROMETHANESULFONATE)Related Search:
Boron trifluoride diethyl etherate
Trifluoromethanesulfonic acid
SILVER TRIFLUOROMETHANESULFONATE
Trifluoromethanesulfonic anhydride
YTTERBIUM(III) TRIFLATE HYDRATE, 99.90%
CERIUM(III) CHLORIDE HEPTAHYDRATE
TRIFLUOROMETHYL SULFINYL CHLORIDE
Silver(I) trifluoromethanethiolate
CERIUM(III) TRIFLUOROMETHANESULFONATE
CALCIUM TRIFLUOROMETHANESULFONATE
1of4
Copper (Ii) Trifluorome
Copper(II) trifluoromethanesulfonate,Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt
Copper(II) trifluoromethanesulfonate 98%
Trifluoromethanesulfonic acid copper(II)
Copper(Ⅱ) trifluoroMethanesulfonate
Cupric trifluoroMethylsulfonate
Copper(II) trifluoroMethanesulfonate,98% Cu(CF3SO3)2
Copper(II) Triflate
Trifluoromethanesulfonic Acid Copper(II) Salt
Copper(II) trifluoroMethanesulfonate, 98% 5GR
Trifluoromethanesulfonic Acid (copper)
TRIFLUOROMETHANESULFONIC ACID COPPER SALT
TRIFLUOROMETHANESULFONIC ACID COPPER(II) SALT
COPPER(II) TRIFLUOROMETHANESULFONATE
Copper (II) trifluoromethanesulfonate, (Copper triflate)
COPPER(II) TRIFLUOROMETHANESULFONATE, 98 %
Copper(II)trifluoromethanesulphonate,98%
COPPER TRIFLUOROMETHANESULFONATE
coppertrifluoromethanesulfonate
Trifluoromethanesulfonic acid cupric salt
CUPRIC-2-TRIFLATE
Copper(II) trifluoromethanesulfonate, 99% min
Bis(trifluoromethanesulfonic acid)copper(II) salt
Bis(trifluoromethylsulfonyloxy) copper(II)
Copper(II)trifluoromethanesulfonate,98%(Coppertriflate)
Copper(II) trifluoromethanesulphonate 98%
Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt
Copper(II) trifluoromethanesulfonate, 99% (99.9%-Cu) (Copper triflate)
CUPRIC TRIFLUOROMETHANESULFONATE, 98%CUPRIC TRIFLUOROMETHANESULFONATE, 98%CUPRIC TRIFLUOROMETHANESULFONATE, 98%CUPRIC TRIFLUOROMETHANESULFONATE, 98%
Copper(II) trifL
Copper(II) trifluoromethanesulfonate, 98%, for synthesis
COPPER(II) TRIFLUOROMETHANESULFONATE ISO 9001：2015 REACH
Cu(OTf)2
Bis(((trifluoromethyl)sulfonyl)oxy)copper
copper(II) bis(trifluoromethanesulfonate)
COPPER TRIFLATE
COPPER(II) TRIFLATE
COPPER(II) TRIFLUOROMETHANESULPHONATE
CUPRIC TRIFLUOROMETHANESULFONATE
Cupric (Ⅱ) trifluoromethanesulfonate
34946-82-2
CHF3O3S12Cu
C2CuF6O6S2
CuCF3SO32
CF3SO32Cu
2CF3O3SCu
C2F6S2O6Cu
C2CuF6O4S2
Catalysts for Organic Synthesis
Metal Triflates
Catalysis and Inorganic Chemistry
Cu (Copper) Compounds
Classes of Metal Compounds
Reagents for Oligosaccharide Synthesis
Homogeneous Catalysts
Transition Metal Compounds
Biochemistry
Catalysts for Organic Synthesis
Classes of Metal Compounds