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HEXAFLUOROACETYLACETONE

Description References
HEXAFLUOROACETYLACETONE
HEXAFLUOROACETYLACETONE structure
CAS No.
1522-22-1
Chemical Name:
HEXAFLUOROACETYLACETONE
Synonyms
HFAC;HFACAC;uoroacetyL;HEXAFLUOROACETYLACETONE;Hexafluoroacetylacetone99%;Hexafluoroacetylacetone>Hexafluoro-2,4-pentanedione;Hexafluoroacetylacetone 98%;1,1,1,5,5,5-Hexafluoropentane;HEXAFLUOROACETYLACETONE HFAC
CBNumber:
CB8188414
Molecular Formula:
C5H2F6O2
Formula Weight:
208.06
MOL File:
1522-22-1.mol

HEXAFLUOROACETYLACETONE Properties

Boiling point:
70-71 °C (lit.)
Density 
1.47 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.332(lit.)
Flash point:
32 °C
storage temp. 
Inert atmosphere,Room Temperature
pka
4.30±0.10(Predicted)
form 
Liquid
color 
Clear colorless to slightly yellow
Specific Gravity
1.470
Water Solubility 
Not miscible in water.
Sensitive 
Hygroscopic
BRN 
1790138
InChIKey
QAMFBRUWYYMMGJ-UHFFFAOYSA-N
CAS DataBase Reference
1522-22-1(CAS DataBase Reference)
EPA Substance Registry System
2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- (1522-22-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H318-H335-H226-H302+H312+H332-H314
Precautionary statements  P280-P305+P351+P338-P310-P260h-P303+P361+P353-P501a-P210-P233-P240-P241+P242+P243-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405-P501
Hazard Codes  C,F,Xi
Risk Statements  10-20/21/22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 2920 8/PG 2
WGK Germany  3
3
Hazard Note  Flammable/Corrosive
TSCA  T
HazardClass  8
PackingGroup  II
HS Code  29147000

HEXAFLUOROACETYLACETONE price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 238309 Hexafluoroacetylacetone 98% 1522-22-1 5g $41.7 2021-03-22 Buy
Sigma-Aldrich 238309 Hexafluoroacetylacetone 98% 1522-22-1 25g $123 2021-03-22 Buy
TCI Chemical H0476 Hexafluoroacetylacetone >95.0%(GC) 1522-22-1 5g $40 2021-03-22 Buy
TCI Chemical H0476 Hexafluoroacetylacetone >95.0%(GC) 1522-22-1 25g $117 2021-03-22 Buy
Alfa Aesar L01693 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1522-22-1 25g $125 2021-03-22 Buy

HEXAFLUOROACETYLACETONE Chemical Properties,Uses,Production

Description

HEXAFLUOROACETYLACETONE acts as a chelating ligand. For example, it can forms metal-chelate complexes with Ca(II), Zn (II), Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III), making it be useful in extracting related metal ions. It can also be used as liquid crystal intermediate.

References

Chattoraj, S. C., A. G. C. Jr, and R. E. Sievers. "Cadmium and zinc chelates of hexafluoroacetylacetone the gas phase reaction of a novel volatile cadmium complex with hydrogen sulphide." Journal of Inorganic & Nuclear Chemistry 28.9(1966):1937-1943.
Tomazic, Branko B., and J. W. O'Laughlin. "Synergic extraction of iron with hexafluoroacetylacetone and tributyl phosphate." Analytical Chemistry 45.8(2002):1519-1526.
http://www.sigmaaldrich.com/catalog/product/aldrich/238309?lang=en&region=US
https://www.alfa.com/zh-cn/catalog/L01693/

Chemical Properties

clear colorless to slightly yellow liquid

Purification Methods

It forms a dihydrate which has no UV spectrum compared with max (CHCl3) 273nm ( 7,800) for the anhydrous ketone. The dihydrate decomposes at ~90o. The hydrate (10g) plus anhydous CaSO4 (Drierite, 30g) are heated and distilled, the distillate is treated with more CaSO4 and redistilled. When the distillate is treated with aqueous NaOH and heated, the dihydrate crystallises on cooling. The Cu complex has m 135o (after sublimation). [Gilman et al. J Am Chem Soc 78 2790 1956, Belford et al. J Inorg Nucl Chem 2 11 1956, Beilstein 1 IV 3681.]

HEXAFLUOROACETYLACETONE Preparation Products And Raw materials

Raw materials

Preparation Products


HEXAFLUOROACETYLACETONE Suppliers

Global( 204)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Springchem New Material Technology Co.,Limited
+8613917661608 +86-021-62885108
info@spring-chem.com China 2064 57
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20012 60
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20898 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 8909 55
career henan chemical co
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CONIER CHEM AND PHARMA LIMITED
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Shaanxi Dideu Medichem Co. Ltd
15319487004
029-88380327 1015@dideu.com CHINA 4103 58
Antai Fine Chemical Technology Co.,Limited
18503026267
info@antaichem.com CHINA 9664 58

View Lastest Price from HEXAFLUOROACETYLACETONE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-07-06 HEXAFLUOROACETYLACETONE
1522-22-1
US $1.00 / KG 1KG 98-100% 1000kg career henan chemical co
2019-07-06 HEXAFLUOROACETYLACETONE
1522-22-1
US $1.00 / KG 1KG 98-100% 1000kg career henan chemical co

HEXAFLUOROACETYLACETONE Spectrum


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