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HEXAFLUOROACETYLACETONE

HEXAFLUOROACETYLACETONE structure

CAS No.: 1522-22-1

Chemical Name:: HEXAFLUOROACETYLACETONE

Synonyms: HFACAC;HFAC;1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONE;1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE;1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE;uoroacetyL;HEXAFLUOROACETYLACETONE;Hexafluoroacetylacetone99%;Hexafluoroacetylacetone>

CBNumber:: CB8188414

Molecular Formula:: C5H2F6O2

Molecular Weight:: 208.06

MDL Number:: MFCD00000426

MOL File:: 1522-22-1.mol

MSDS File:: SDS

Last updated:2024-02-19 12:30:55

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HEXAFLUOROACETYLACETONE Properties

Boiling point	70-71 °C (lit.)
Density	1.47 g/mL at 25 °C (lit.)
refractive index	n20/D 1.332(lit.)
Flash point	32 °C
storage temp.	Inert atmosphere,Room Temperature
form	Liquid
pka	4.30±0.10(Predicted)
color	Clear colorless to slightly yellow
Specific Gravity	1.470
Water Solubility	Not miscible in water.
Sensitive	Hygroscopic
BRN	1790138
InChIKey	QAMFBRUWYYMMGJ-UHFFFAOYSA-N
CAS DataBase Reference	1522-22-1(CAS DataBase Reference)
FDA UNII	MG8477QRV4
EPA Substance Registry System	2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- (1522-22-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS07

Signal word

Danger

Hazard statements

H226-H302+H312+H332-H314

Precautionary statements

P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338

Hazard Codes

C,F,Xi

Risk Statements

10-20/21/22-34

Safety Statements

26-36/37/39-45

RIDADR

UN 2920 8/PG 2

WGK Germany

Hazard Note

Flammable/Corrosive

TSCA

HazardClass

PackingGroup

HS Code

29147000

NFPA 704

	3
3		1

HEXAFLUOROACETYLACETONE price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	238309	Hexafluoroacetylacetone 98%	1522-22-1	5g	$48.7	2024-03-01	Buy
Sigma-Aldrich	238309	Hexafluoroacetylacetone 98%	1522-22-1	25g	$143	2024-03-01	Buy
TCI Chemical	H0476	Hexafluoroacetylacetone >95.0%(GC)	1522-22-1	5g	$44	2024-03-01	Buy
TCI Chemical	H0476	Hexafluoroacetylacetone >95.0%(GC)	1522-22-1	25g	$129	2024-03-01	Buy
Alfa Aesar	L01693	1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+%	1522-22-1	5g	$57	2024-03-01	Buy

Product number	Packaging	Price	Buy
238309	5g	$48.7	Buy
238309	25g	$143	Buy
H0476	5g	$44	Buy
H0476	25g	$129	Buy
L01693	5g	$57	Buy

HEXAFLUOROACETYLACETONE Chemical Properties,Uses,Production

Description

HEXAFLUOROACETYLACETONE acts as a chelating ligand. For example, it can forms metal-chelate complexes with Ca(II), Zn (II), Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III), making it be useful in extracting related metal ions. It can also be used as liquid crystal intermediate.

References

Chattoraj, S. C., A. G. C. Jr, and R. E. Sievers. "Cadmium and zinc chelates of hexafluoroacetylacetone the gas phase reaction of a novel volatile cadmium complex with hydrogen sulphide." Journal of Inorganic & Nuclear Chemistry 28.9(1966):1937-1943.
Tomazic, Branko B., and J. W. O'Laughlin. "Synergic extraction of iron with hexafluoroacetylacetone and tributyl phosphate." Analytical Chemistry 45.8(2002):1519-1526.
http://www.sigmaaldrich.com/catalog/product/aldrich/238309?lang=en&region=US
https://www.alfa.com/zh-cn/catalog/L01693/

Chemical Properties

clear colorless to slightly yellow liquid

Uses

1,1,1,5,5,5-Hexafluoro-2,4-pentanedione acts as a chelating ligand. It is used as liquid crystal intermediate.

General Description

Hexafluoroacetylacetone forms metal-chelate complexes with Cu(II), Ni(II), Co(II), Nd(III), Rh(III), Fe(III) and Cr(III). Hexafluoroacetylacetone on hydration yields 1,1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraol.

Purification Methods

It forms a dihydrate which has no UV spectrum compared with max (CHCl3) 273nm ( 7,800) for the anhydrous ketone. The dihydrate decomposes at ~90o. The hydrate (10g) plus anhydous CaSO4 (Drierite, 30g) are heated and distilled, the distillate is treated with more CaSO4 and redistilled. When the distillate is treated with aqueous NaOH and heated, the dihydrate crystallises on cooling. The Cu complex has m 135o (after sublimation). [Gilman et al. J Am Chem Soc 78 2790 1956, Belford et al. J Inorg Nucl Chem 2 11 1956, Beilstein 1 IV 3681.]

HEXAFLUOROACETYLACETONE synthesis

Synthesis of HEXAFLUOROACETYLACETONE from 3,3,3-TRIFLUOROPROPYNE and Ethyl trifluoroacetate

HEXAFLUOROACETYLACETONE Preparation Products And Raw materials

Raw materials

Ethanol Di-n-butyl ether tert-Butyl methyl ether N,N-Dimethylformamide 1,1,1-Trifluoroacetone

Toluene Sodium Ethyl trifluoroacetate Sodium Methoxide Tetrahydrofuran

Diethyl ether Methanol Magnesium Sulfuric acid 1,1,1,5,5,5-HEXAFLUORO-2,2,4,4-PENTANE-T ETROL, 97

3,3,3-TRIFLUOROPROPYNE

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Preparation Products

1-(1-TERT-BUTYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOL-4-YL)-2,2,2-TRIFLUOROETHANONE 2,2,2-TRIFLUORO-1-(3-(TRIFLUOROMETHYL)-1-METHYL-1H-PYRAZOL-4-YL)ETHANONE 5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE 4-Butoxy-1,1,1-trofluoro-3-buten-2-one 1H-Benzimidazole,5-methyl-2-(trifluoromethyl)-(9CI)

HEXAFLUOROACETYLACETONE Suppliers

Global( 279)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7613	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2967	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Springchem New Material Technology Co.,Limited	57
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Jinan Finer Chemical Co., Ltd	58

View Lastest Price from HEXAFLUOROACETYLACETONE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-03-28	Hexafluoroacetylacetone 1522-22-1	US $0.00 / kg	25kg	GC>99%	Inquiry	PNP Biotech Co. Ltd
2024-02-19	1,1,1,5,5,5-Hexafluoroacetylacetone 1522-22-1	US $1250.00 / Kg	1Kg	99	500 Kg	R&D Scientific Inc.
2024-01-22	1,1,1,5,5,5-Hexafluoroacetylacetone 1522-22-1	US $8.00-0.80 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd

Hexafluoroacetylacetone
1522-22-1
US $0.00 / kg
GC>99%
PNP Biotech Co. Ltd

1,1,1,5,5,5-Hexafluoroacetylacetone
1522-22-1
US $1250.00 / Kg
99
R&D Scientific Inc.

1,1,1,5,5,5-Hexafluoroacetylacetone
1522-22-1
US $8.00-0.80 / KG
99%
Henan Fengda Chemical Co., Ltd

HEXAFLUOROACETYLACETONE Spectrum

HEXAFLUOROACETYLACETONE(1522-22-1)MS HEXAFLUOROACETYLACETONE(1522-22-1)¹HNMR HEXAFLUOROACETYLACETONE(1522-22-1)¹³CNMR HEXAFLUOROACETYLACETONE(1522-22-1)IR1 HEXAFLUOROACETYLACETONE(1522-22-1)ESR

1522-22-1(HEXAFLUOROACETYLACETONE)Related Search:

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COPPER(II) HEXAFLUORO-2,4-PENTANEDIONATE YTTRIUM HEXAFLUOROACETYLACETONATE HEXAFLUOROACETYLACETONATO NICKEL (II) TRIHYDRATE 1,1,1,5,5,5-Hexafluoroacetylacetone iron(III) salt Acetylacetone

COBALT (II) HEXAFLUORO-2,4-PENTANEDIONATE THALLIUM(I) HEXAFLUOROACETYLACETONATE Hexafluoroacetylacetone magnesium(II) salt MANGANESE(II) HEXAFLUOROACETYLACETONATE HEXAFLUOROACETYLACETONE, ZINC SALT

1,1,1,5,5,5-HEXAFLUOROACETYLACETONE DIHYDRATE 1,1,1,5,5,5-HEXAFLUORO-3-(1,2,3,4-TETRAHYDRO-1-ISOQUINOLINYL)-2,4-PENTANEDIONE 3-ISOBUTOXYVINYL-1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE

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1,1,1,5,5,5-hexafluoro-4-pentanedione 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione 1,3-Bis(trifluoromethyl)propane-1,3-dione Hexafluoro-2,4-pentanedione 1,1,1,5,5,5-Hexafluoroacetylacetone, 99% 25GR 1,1,1,5,5,5-Hexafluoroacetylacetone, 99% 5GR 1,1,1,5,5,5-HEXAFLUOROACETYLACETONE FOR 1,1,1,5,5,5-Hexafluoropentane-2,4-dione, 1,1,1-Trifluoro-3-(trifluoroacetyl)acetone, 2,4-Dioxo-1,1,1,5,5,5-hexafluoropentane, HFAA 3H,3H-Hexafluoropentane-2,4-dione Hexafluoroacetylacetone 98% Hexafluoroacetylacetone,98% HFAA 1,1,1,5,5,5-Hexafluoropentane Hexafluoroacetylacetone99% Hexafluoroacetylacetone (HFAcAc) 1,1,1,5,5,5-Hexafluoroacetylacetone for synthesis HEXAFLUOROACETYLACETONE 1,1,1,5,5-HEXAFLUORO-2,4-PENTANDIONE 1,1,1,5,5,5-HEXAFLUORO-2,4-PENTADIONE 1,1,5,5,5-HEXAFLUORO-2,4-PENTADIONE 1,1,1,5,5,5-Hexafluoropentane-2,4-dione [HFAA] Hexafluoroacetylacetone,min.98%HFAA 2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro- HEXAFLUOROACETYLACETONE HFAC HEXAFLUOROACETYLACETONE, ELECTRONIC GRADE 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+% 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 99+% 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 1,1,1,5,5,5-Hexafluoroacetylacetone 1,1,1,5,5,5-Hexafluoroacetylacetone 99% 1,1,1,5,5,5-Hexafluoroacetylacetone99% 1,1,1,5,5,5-Hexafluoroacetylacetone,96% Hexafluoroacetylacetone,1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 1,1,1,5,5,5-Hexafluoroacetylacetone 1,1,1,5,5,5-Hexafluoroacetylacetone, 98+% ##DISCONTINUED USE L01693## 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 97% Hexafluoroacetylacetone> uoroacetyL HFAC HFACAC 1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE 1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONE 1,1,1,5,5,5-HEXAFLUOROACETYLACETONATE 1,1,1,5,5,5-HEXAFLUOROACETYLACETONE 1522-22-1 C5H2F6O2 CF3COCH2COCF3 Organic Building Blocks Ketones Building Blocks C3 to C6 Carbonyl Compounds organofluorine compounds Halogen compounds