ChemicalBook >> CAS DataBase List >>(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) structure

CAS No.: 259259-80-8

Chemical Name:: (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

Synonyms: (S)-AMAC;(S,S)-AMAC;(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II);Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-

CBNumber:: CB8189532

Molecular Formula:: C32H38CoN2O4

Molecular Weight:: 573.59

MDL Number:: MFCD06797062

MOL File:: 259259-80-8.mol

Last updated:2023-06-08 17:06:36

Request For Quotation

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Properties

Melting point	242-246°C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	powder to crystal
color	Orange to Brown
optical activity	[α]/D 309°, c = 0.1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07,GHS08
Signal word	Warning
Hazard statements	H302+H312+H332-H315-H319-H351
Precautionary statements	P201-P202-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P308+P313-P405-P501
WGK Germany	3
HS Code	2942.00.3500

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) price More Price(12)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	708844	(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)	259259-80-8	100mg	$34.12	2024-03-01	Buy
Sigma-Aldrich	708844	(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)	259259-80-8	500mg	$389	2023-06-20	Buy
TCI Chemical	B2315	(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	259259-80-8	100mg	$303	2024-03-01	Buy
TRC	A165435	(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	259259-80-8	10mg	$65	2021-12-16	Buy
Biosynth Carbosynth	FB59945	(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)	259259-80-8	10mg	$66	2021-12-16	Buy

Product number	Packaging	Price	Buy
708844	100mg	$34.12	Buy
708844	500mg	$389	Buy
B2315	100mg	$303	Buy
A165435	10mg	$65	Buy
FB59945	10mg	$66	Buy

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties,Uses,Production

Uses

Catalyst for:

Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
Enantioselective borohydride reduction
Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Suppliers

Global( 35)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	94838	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006608290; 18621169109	market03@meryer.com	China	40241	62
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24539	81
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44751	61
Shanghai Longsheng chemical Co.,Ltd.	021-58099652-8005 13585536065	bin.wu@shlschem.com	China	9816	59
Maya High Purity Chemicals	+86 (573) 82222445 (0)18006601000 452520369	sales@maya-r.com	China	11714	57
TOKYO CHEMICAL INDUSTRY CO., LTD.	03-36680489	Sales-JP@TCIchemicals.com	Japan	28398	80
TCI Europe	320-37350700	sales@tcieurope.eu	Europe	23680	75
TCI AMERICA	800-4238616	sales@tciamerica.com	Americas	23662	75

Supplier	Advantage
Alfa Chemistry	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Shanghai Longsheng chemical Co.,Ltd.	59
Maya High Purity Chemicals	57
TOKYO CHEMICAL INDUSTRY CO., LTD.	80
TCI Europe	75
TCI AMERICA	75

259259-80-8((1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II))Related Search:

N-Benzylcinchonidinium chloride (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) (1S,2S)-1,2-BIS(2,4,6-TRIMETHYLPHENYL)ETHYLENEDIAMINE MESO-1,2-BIS(P-TOLYL)ETHYLENEDIAMINE (R)-(1-(2,4,6-Trimethylphenyl)ethyl)amine

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

1of2

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) (S)-AMAC Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)- (S,S)-AMAC (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) 259259-80-8 C32H38CoN2O4 Co (Cobalt) Compounds Homogeneous Catalysts Transition Metal Compounds Catalysts for Organic Synthesis Classes of Metal Compounds Asymmetric Synthesis Metal Complexes Asymmetric Synthesis Catalysts for Organic Synthesis Classes of Metal Compounds Co (Cobalt) Compounds Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Transition Metal Compounds