ChemicalBook >> CAS DataBase List >>5,8-Dihydroxy-1,4-naphthoquinone

5,8-Dihydroxy-1,4-naphthoquinone

CAS No.
475-38-7
Chemical Name:
5,8-Dihydroxy-1,4-naphthoquinone
Synonyms
NAPHTHAZARIN;5,8-Dihydroxynaphthoquinone;5,8-Dihydroxynaphthalene-1,4-dione;Naphthazarone;Naphthazarine;NAPHTHAZALINE;Mordant Black 37;Naphthazarin (6CI);5,8-Dihydroxy-1,4-n;5,8-dihydroxy-4-naphthoquinone
CBNumber:
CB8194974
Molecular Formula:
C10H6O4
Molecular Weight:
190.15
MDL Number:
MFCD00001685
MOL File:
475-38-7.mol
MSDS File:
SDS
Last updated:2023-05-18 11:31:14

5,8-Dihydroxy-1,4-naphthoquinone Properties

Melting point 220-230 °C(lit.)
Boiling point 285.64°C (rough estimate)
Density 1.3366 (rough estimate)
refractive index 1.5280 (estimate)
storage temp. Sealed in dry,Room Temperature
pka 6.98±0.20(Predicted)
form powder to crystaline
color Dark red to Brown
Water Solubility Soluble in water (5520 mg/L 25.).
BRN 880561
CAS DataBase Reference 475-38-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII S9IX5I5C0K
NIST Chemistry Reference 1,4-Naphthalenedione, 5,8-dihydroxy-(475-38-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P280a-P304+P340-P305+P351+P338-P405-P501a-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-37/39-26
WGK Germany  3
RTECS  QL7970000
HS Code  2914409000
NFPA 704
1
2 0

5,8-Dihydroxy-1,4-naphthoquinone price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 388513 5,8-Dihydroxy-1,4-naphthoquinone technical grade 475-38-7 1g $293 2024-03-01 Buy
TCI Chemical D2070 5,8-Dihydroxy-1,4-naphthoquinone >75.0%(HPLC) 475-38-7 1g $401 2024-03-01 Buy
TCI Chemical D2070 5,8-Dihydroxy-1,4-naphthoquinone >75.0%(HPLC) 475-38-7 5g $406 2021-12-16 Buy
Alfa Aesar A18930 5,8-Dihydroxy-1,4-naphthoquinone, 97% 475-38-7 5g $415 2021-12-16 Buy
Alfa Aesar A18930 5,8-Dihydroxy-1,4-naphthoquinone, 97% 475-38-7 1g $98.2 2021-12-16 Buy
Product number Packaging Price Buy
388513 1g $293 Buy
D2070 1g $401 Buy
D2070 5g $406 Buy
A18930 5g $415 Buy
A18930 1g $98.2 Buy

5,8-Dihydroxy-1,4-naphthoquinone Chemical Properties,Uses,Production

Chemical Properties

dark purple to brown-black powder

Preparation

1,8-Dinitronaphthalene and 1,5-Dinitronaphthalene mixture or both alone and one of sulfur 40% fuming sulfuric ACID reaction, the product (5, 8 – dihydroxy – naphthoquinone) into Sulfurous acid?hydrogen salt.

Definition

ChEBI: A naphthoquinone that is 1,4-naphthoquinone in which the hydrogens at positions 5 and 8 are replaced by hydroxy groups.

Purification Methods

It crystallises in red-brown needles with a green shine from EtOH. It also crystallises from hexane and is further purified by sublimation at 2-10mm. [Huppert et al. J Phys Chem 89 5811 1985.] It is sparingly soluble in H2O but soluble in alkalis. The diacetate forms golden yellow prisms from CHCl3, m 192-193o and the 5,8-dimethoxy derivative has m 157o (155o) (from pet ether) [Bruce & Thompson J Chem Soc 1089 1955, IR: Schmand & Boldt J Am Chem Soc 97 447 1975, NMR: Brockmann & Zeeck Chem Ber 101 4221 1968]. The monothiosemicarbazone has m 168o(dec) from EtOH [Gardner et al. J Am Chem Soc 74 2106 1952]. [Beilstein 8 H 412, 8 III 3600.]

Properties and Applications

ash red to black. Soluble in water for red light brown, soluble in ethanol for yellow brown, with green fluorescence. In concentrated sulfuric acid to dark yellow green, heating to rouge red, dilution after brown black precipitation. Dye aqueous solution to join sodium hydroxide to red, the air oxidation into blue.

Standard Ironing Fastness Light Fastness Fulling Persperation Fastness Soaping Water
Alkali Acid
ISO 5 6 5 4 5 5 5

108-31-6
123-31-9
475-38-7
Synthesis of 5,8-Dihydroxy-1,4-naphthoquinone from CIS-BUTENEDIOIC ANHYDRIDE and Hydroquinone
Global( 134)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Speranza Chemical Co., Ltd.
+86-86-075521030354 +8618688942810 sophieliu@speranzachem.com China 723 55
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
Alfa Chemistry
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Sense Chemicals (Shanghai) Co., Ltd.
+86-21-52751036; +8613818977689 david.dai@sensechemicals.com China 224 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Henan Alfa Chemical Co., Ltd
+8618339805032 alfa4@alfachem.cn China 12755 58
Nanjing Doge Biomedical Technology Co., Ltd
+86-25-58227606 +86-15305155328 sales@dogechemical.com China 4128 58

View Lastest Price from 5,8-Dihydroxy-1,4-naphthoquinone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5,8-Dihydroxy-1,4-naphthoquinone pictures 2022-10-10 5,8-Dihydroxy-1,4-naphthoquinone
475-38-7
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
5,8-Dihydroxy-1,4-naphthoquinone pictures 2020-01-08 5,8-Dihydroxy-1,4-naphthoquinone
475-38-7
US $2.00 / KG 1g 98%MIN ASK Career Henan Chemical Co
,8-Dihydroxy-[1,4]naphthoquinone ,8-Dihydroxy-1,4-naphthalenedione 1,4-Naphthoquinone, 5,8-dihydroxy- 2,3-Dihydro-1,4,5,8-naphthalenetetrone 5,8-dihydroxy-4-naphthalenedione 5,8-dihydroxy-4-naphthoquinone Naphthazarine Naphthazarone 5,8-DIHYDROXY-1,4-NAPHTHALENEDIONE 5,8-DIHYDROXY-1,4-NAPHTHOQUINONE DIHYDROXY-1,4-NAPHTHOQUINONE,5,8- 5,8-HYDROXY-1,4-NAPHTHOQUINONE NAPHTHAZALINE 5,8-DIHYDROXY-1,4-NAPHTHOQUINONE, TECH. 5,8-Dihydroxy-1,4-naphthoquinone,tech.90% 5,8-Dihydroxy-1,4-n 5,8-Dihydroxy-1,4-naphthoquinone,98% 5,8-Dihydroxy-1,4-naphthalenedione Naphthazarin 5,8-dihydroxy-2,3-dihydronaphthalene-1,4-dione 5,8-Dihydroxy-1,4-naphthoquinone> 1,4-Naphthalenedione, 5,8-dihydroxy- C.I.Mordant Black 37:C.I.57010 Mordant Black 37 5,8-Dihydroxynaphthoquinone NAPHTHAZARIN 5,8-Dihydroxynaphthalene-1,4-dione Naphthazarin (6CI) Naturally,Apoptosis,Naphthazarin,stress,microtubules,mitochondrial,AIF,Inhibitor,p21,lysosomal,inhibit,oxidative,p53-dependent,anti-tumor 475-38-7 HO2C10H4O2 Carbonyl Compounds C10 Building Blocks Organic Building Blocks Ketones API intermediates