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(S) QuinoxP(R)

CAS No.
1107608-80-9
Chemical Name:
(S) QuinoxP(R)
Synonyms
QuinoxP;(S) QuinoxP;(S,S)-QuinoxP*;(S) QuinoxP(R);3-bis((S)-tert-butyl(methyl)phosphino)quinoxaline;(S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline;(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline;2,3-bis((S)-tert-butyl(methyl)phosphaneyl)quinoxaline;2,3-Bis[(S)-(1,1-dimethylethyl)methylphosphino]quinoxaline;Quinoxaline, 2,3-bis[(S)-(1,1-dimethylethyl)methylphosphino]-
CBNumber:
CB82102711
Molecular Formula:
C18H28N2P2
Molecular Weight:
334.38
MDL Number:
MFCD10567042
MOL File:
1107608-80-9.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

(S) QuinoxP(R) Properties

Melting point 100-105 °C
Boiling point 447.6±45.0 °C(Predicted)
alpha +54.3° (c 1.0, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.54±0.59(Predicted)
form Powder
color orange
optical activity [α]22/D +55°, c = 1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335-H413
Precautionary statements  P273-P301+P312+P330-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22-36/37/38
Safety Statements  26
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
HS Code  2933.99.8290
NFPA 704
0
2 0

(S) QuinoxP(R) price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 694215 (S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 1107608-80-9 100mg $89.8 2024-03-01 Buy
TCI Chemical B5302 (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline >98.0%(HPLC) 1107608-80-9 100mg $213 2024-03-01 Buy
Strem Chemicals 15-0127 (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP* 1107608-80-9 100mg $116 2024-03-01 Buy
Strem Chemicals 15-0127 (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP* 1107608-80-9 500mg $458 2024-03-01 Buy
TRC B400220 (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 1107608-80-9 100mg $250 2021-12-16 Buy
Product number Packaging Price Buy
694215 100mg $89.8 Buy
B5302 100mg $213 Buy
15-0127 100mg $116 Buy
15-0127 500mg $458 Buy
B400220 100mg $250 Buy

(S) QuinoxP(R) Chemical Properties,Uses,Production

Reaction

  1. Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides.
  2. Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.
  3. Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction
  4. Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.
  5. Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.
  6. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes.
  7. Ligand for the silver-catalyzed asymmetric nitroso aldol reaction.
Reactions of 1107608-80-9_1
Reactions of 1107608-80-9_2

Uses

(S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is a useful reagent for organic synthesis of chiral tetraphenylenes, fused lactones and other useful intermediates.

(S) QuinoxP(R) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 67)Suppliers
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ATK CHEMICAL COMPANY LIMITED
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Shenzhen Nexconn Pharmatechs Ltd
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Aladdin Scientific
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Sphinx Scientific Laboratory(Tianjin) Co.,Ltd 022-66211289-860 18222589728 contact@sphinxpharm.com China 185 58
(S) QuinoxP QuinoxP (S,S)-QuinoxP* 2,3-Bis[(S)-(1,1-dimethylethyl)methylphosphino]quinoxaline (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline (S) QuinoxP(R) (S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (S,S)-(+)-2,3-Bis(t-butylMethylphosphino)quinoxaline (S,S)-QuinoxP* 3-bis((S)-tert-butyl(methyl)phosphino)quinoxaline Quinoxaline, 2,3-bis[(S)-(1,1-dimethylethyl)methylphosphino]- 2,3-bis((S)-tert-butyl(methyl)phosphaneyl)quinoxaline 1107608-80-9 Chiral Phosphine