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2,4-Difluorobenzyl bromide

2,4-Difluorobenzyl bromide structure

CAS No.: 23915-07-3

Chemical Name:: 2,4-Difluorobenzyl bromide

Synonyms: 1-(bromomethyl)-2,4-difluorobenzene;TIMTEC-BB SBB006567;2,4-Difluorobenzyl b;4-Difluorobenzyl broMide;2,4-DIFLUOROBENZYL BROMID;2,4-DIFLUOROBENZYL BROMIDE;à-bromo-2,4-difluorotoluene;α-bromo-2,4-difluorotoluene;a-Bromo-2,4-difluorotoluene;2,4-Difluoro Bromine Benzyl

CBNumber:: CB8220095

Molecular Formula:: C7H5BrF2

Molecular Weight:: 207.02

MDL Number:: MFCD00011649

MOL File:: 23915-07-3.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:58:48

Product description	Number	Pack Size	Price
2,4-Difluorobenzyl bromide 98%	264415	5g	$46.5
2,4-Difluorobenzyl bromide 98%	264415	25g	$125
2,4-Difluorobenzyl Bromide >98.0%(GC)	B1710	5g	$60
2,4-Difluorobenzyl Bromide >98.0%(GC)	B1710	25g	$239
2,4-Difluorobenzyl bromide	D447555	10g	$165
More product size

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2,4-Difluorobenzyl bromide Properties

Melting point	18 °C
Boiling point	28 °C
Density	1.613 g/mL at 25 °C(lit.)
refractive index	n20/D 1.525(lit.)
Flash point	104 °F
storage temp.	Inert atmosphere,2-8°C
form	Liquid
Specific Gravity	1.63
color	Clear yellow
Sensitive	Lachrymatory
BRN	4177539
InChI	1S/C7H5BrF2/c8-4-5-1-2-6(9)3-7(5)10/h1-3H,4H2
InChIKey	IBLMYGXJKQIGSN-UHFFFAOYSA-N
SMILES	Fc1ccc(CBr)c(F)c1
CAS DataBase Reference	23915-07-3(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS08

Signal word

Danger

Hazard statements

H226-H314-H317-H334

Precautionary statements

P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

PPE

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Codes

C,F

Risk Statements

10-34-42/43-36

Safety Statements

23-26-36/37/39-45-25-16

RIDADR

UN 2920 8/PG 2

WGK Germany

Hazard Note

Corrosive/Lachrymatory

HazardClass

PackingGroup

III

HS Code

29039990

Storage Class

3 - Flammable liquids

Hazard Classifications

Flam. Liq. 3
Resp. Sens. 1
Skin Corr. 1B
Skin Sens. 1

Limited Quantities

1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	2
3		0

2,4-Difluorobenzyl bromide price More Price(27)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	264415	2,4-Difluorobenzyl bromide 98%	23915-07-3	5g	$46.5	2023-01-07	Buy
Sigma-Aldrich	264415	2,4-Difluorobenzyl bromide 98%	23915-07-3	25g	$125	2023-01-07	Buy
TCI Chemical	B1710	2,4-Difluorobenzyl Bromide >98.0%(GC)	23915-07-3	5g	$60	2026-04-30	Buy
TCI Chemical	B1710	2,4-Difluorobenzyl Bromide >98.0%(GC)	23915-07-3	25g	$239	2026-04-30	Buy
TRC	D447555	2,4-Difluorobenzyl bromide	23915-07-3	10g	$165	2021-12-16	Buy

Product number	Packaging	Price	Buy
264415	5g	$46.5	Buy
264415	25g	$125	Buy
B1710	5g	$60	Buy
B1710	25g	$239	Buy
D447555	10g	$165	Buy

2,4-Difluorobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

2,4-Difluorobenzyl bromide has been used in the preparation of:

novel 1,2,4-triazolium derivatives
1,5-biaryl pyrrole EP₁ receptor antagonists

Synthesis

56456-47-4

23915-07-3

The general procedure for the synthesis of 2,4-difluorobenzyl bromide from 2,4-difluorobenzyl alcohol was as follows: to a solution of diethyl ether (10 mL) of 2,4-difluorobenzyl alcohol (450 mg, 3.12 mmol) was slowly added phosphorus tribromide (0.2 mL, 2.18 mmol) at 0 °C. The reaction mixture was stirred at room temperature for 2 hours. Upon completion of the reaction (monitored by thin layer chromatography), the reaction was quenched with ice water (20 mL) and extracted with ethyl acetate (2 x 20 mL). The organic layers were combined, washed sequentially with water (40 mL) and saturated saline (40 mL), dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give the crude product. Purification by silica gel column chromatography with 5% ethyl acetate/hexane as eluent gave 2,4-difluorobenzyl bromide (420 mg, 2.02 mmol, 65% yield) as a colorless liquid.1H NMR (200 MHz, CDCl3): δ 7.43-7.31 (m, 1H), 6.92-6.77 (m, 2H), 4.48 (s, 2H).

References

[1] Patent: US2012/329788, 2012, A1. Location in patent: Page/Page column 26

2,4-Difluorobenzyl bromide Preparation Products And Raw materials

Raw materials

2,4-Difluorobenzyl alcohol Formaldehyde 1,3-Difluorobenzene Phosphorus tribromide Diethyl ether

Preparation Products

2,4-Difluorophenylacetic acid 4-(2,4-Difluorobenzyl)piperidine hydrochloride Benzaldehyde, 2-[(2,4-difluorophenyl)methoxy]-

2,4-Difluorobenzyl bromide Suppliers

Global( 306)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20124	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13843	58
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58
Changzhou Carman Chemical Co., Ltd.	15061933924		CHINA	514	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Fluoropharm Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Changzhou Carman Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from 2,4-Difluorobenzyl bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-12-01	2,4-Difluorobenzyl bromide 23915-07-3	US $0.00-0.00 / KG	1KG	98.0%	10000KGS	Shaanxi Dideu New Materials Co. Ltd
2025-09-25	2,4-Difluorobenzyl bromide 23915-07-3	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2019-07-06	2,4-Difluorobenzyl bromide 23915-07-3	US $1.00 / KG	1KG	99%	Customized	Career Henan Chemical Co

2,4-Difluorobenzyl bromide
23915-07-3
US $0.00-0.00 / KG
98.0%
Shaanxi Dideu New Materials Co. Ltd

2,4-Difluorobenzyl bromide
23915-07-3
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

2,4-Difluorobenzyl bromide
23915-07-3
US $1.00 / KG
99%
Career Henan Chemical Co

2,4-Difluorobenzyl bromide Spectrum

2,4-Difluorobenzyl bromide(23915-07-3)MS 2,4-Difluorobenzyl bromide(23915-07-3)¹HNMR 2,4-Difluorobenzyl bromide(23915-07-3)¹³CNMR 2,4-Difluorobenzyl bromide(23915-07-3)IR1 2,4-Difluorobenzyl bromide(23915-07-3)Raman

23915-07-3(2,4-Difluorobenzyl bromide)Related Search:

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4-CHLORO-2-TRICHLOROMETHYL-QUINOLINE Methyl bromide 2,3-Difluorobenzyl bromide 98%,2,3-DIFLUOROBENZYL BROMIDE

1of4

4-Difluorobenzyl broMide alpha-BroMo-2,4-difluorotoluene, 98% 5GR ALPHA-BROMO-2,4-DIFLUOROTOLUENE Toluene, α-broMo-2,4-difluoro- (8CI) 1-(Bromomethyl)-2,4-difluorobenzene, alpha-Bromo-2,4-difluorotoluene 2,4-Difluorobenzyl broMide 98%, 4-Difluorobenzyl broMide 98% 2,4-DIFLUOROBENZYL BROMIDE TIMTEC-BB SBB006567 2,4-DIFLUOROBENZYL BROMID Benzene, 1-(bromomethyl)-2,4-difluoro- à-bromo-2,4-difluorotoluene α-bromo-2,4-difluorotoluene a-Bromo-2,4-difluorotoluene 2,4-Difluorobenzylbromide,98% alpha-Bromo-2,4-difluorotoluene,98% 2,4-Difluorobenzyl bromide,α-Bromo-2,4-difluorotoluene 2,4-Difluorobenzyl b 2,4-Difluoro Bromine Benzyl 2,4-Difluorobenzyl Bromide > 2,4-Difluorobenzyl bromide ISO 9001：2015 REACH 1-(bromomethyl)-2,4-difluorobenzene 23915-07-3 BENZYL HALIDE Aryl C7 Building Blocks Halogenated Hydrocarbons Organic Building Blocks Aromatic Halides (substituted) Benzene series Miscellaneous Fluorinated benzene series Fluoro-contained benzyl bromide series Fluorine series