ChemicalBook >> CAS DataBase List >>p-Tolunitrile

p-Tolunitrile

p-Tolunitrile structure

CAS No.: 104-85-8

Chemical Name:: p-Tolunitrile

Synonyms: CNT;4-METHYLBENZONITRILE;4-TOLUNITRILE;P-CYANO TOLUENE;4-methylcyanobenzene;p-Tolunitril;P-Tounitrile;P-TOLUNITRILE;p-Tolumitrile;p-Toluonitril

CBNumber:: CB8223531

Molecular Formula:: C8H7N

Molecular Weight:: 117.15

MDL Number:: MFCD00001827

MOL File:: 104-85-8.mol

MSDS File:: SDS

Last updated:2023-12-05 17:42:12

Request For Quotation

p-Tolunitrile Properties

Melting point	26-28 °C(lit.)
Boiling point	103-106 °C20 mm Hg(lit.)
Density	0.981 g/mL at 25 °C(lit.)
refractive index	1.5285-1.5305
Flash point	185 °F
storage temp.	Store below +30°C.
solubility	alcohol: very soluble
form	Viscous Liquid
color	Clear
Specific Gravity	0.981
Water Solubility	<0.1 g/100 mL at 17 ºC
Merck	14,9538
BRN	507386
Exposure limits	NIOSH: IDLH 25 mg/m3
Stability	Stable. Incompatible with strong oxidizing agents, strong bases.
InChIKey	VCZNNAKNUVJVGX-UHFFFAOYSA-N
CAS DataBase Reference	104-85-8(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	H20555V8NO
NIST Chemistry Reference	Benzonitrile, 4-methyl-(104-85-8)
EPA Substance Registry System	p-Tolunitrile (104-85-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS08

Signal word

Danger

Hazard statements

H315-H319-H334-H335

Precautionary statements

P261-P264-P271-P302+P352-P304+P340+P312-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38-43-36/38

Safety Statements

26-36/37-37-36

WGK Germany

RTECS

XV0700000

Hazard Note

Irritant

TSCA

Yes

HS Code

29269095

NFPA 704

	1
2		0

p-Tolunitrile price More Price(28)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	132330	p-Tolunitrile 98%	104-85-8	25g	$58.3	2024-03-01	Buy
Sigma-Aldrich	132330	p-Tolunitrile 98%	104-85-8	100g	$88.2	2024-03-01	Buy
TCI Chemical	T0307	p-Tolunitrile >98.0%(GC)	104-85-8	25g	$35	2024-03-01	Buy
TCI Chemical	T0307	p-Tolunitrile >98.0%(GC)	104-85-8	100g	$92	2024-03-01	Buy
Alfa Aesar	B23029	p-Tolunitrile, 98+%	104-85-8	50g	$37.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
132330	25g	$58.3	Buy
132330	100g	$88.2	Buy
T0307	25g	$35	Buy
T0307	100g	$92	Buy
B23029	50g	$37.65	Buy

p-Tolunitrile Chemical Properties,Uses,Production

Chemical Properties

This substance is a clear colorless liquid or beige solid that exhibits toxicity and flammability. It should avoid contact with the skin.

Uses

p-Tolunitrile is a reagent used in the preparation of 1H-Indazoles from imidates and nitrosobenzenes.

Synthesis Reference(s)

Synthetic Communications, 15, p. 1299, 1985 DOI: 10.1080/00397918508077278
Tetrahedron Letters, 27, p. 1925, 1986 DOI: 10.1016/S0040-4039(00)84413-5

General Description

Beige solid at 62.6° F.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Nitriles, such as p-Tolunitrile, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.

Fire Hazard

p-Tolunitrile is combustible.

Purification Methods

Melt the nitrile, dry it with MgSO4, fractionally crystallise it from its melt, then fractionally distil it under reduced pressure in a 6-in spinning band column. [Brown J Am Chem Soc 81 3232 1959.] It can also be crystallised from *benzene/pet ether (b 40-60o). [Beilstein 9 H 489, 9 I 194, 9 II 330, 9 III 2348, 9 IV 1738.]

p-Tolunitrile synthesis

Synthesis of p-Tolunitrile from 4-Methylbenzylamine

p-Tolunitrile Preparation Products And Raw materials

Raw materials

4-Methylbenzamide oxime 4-Methylstyrene 4-Methylbenzylamine 4-Methylbenzyl chloride

Preparation Products

4-Cyanobenzaldehyde 4-Methylbenzene-1-carboximidamide hydrochloride 4-(4-METHYLPIPERAZINOMETHYL)BENZOIC ACID 4-METHYL-BENZAMIDINE Acrivastine

5-Methylquinoline 4-METHYL-3-NITROBENZAMIDE 4-Methyl-3-nitrobenzoic acid 2,4,6-trip-tolyl-1,3,5-triazine (4-CYANOBENZYL)PHOSPHONIC ACID DIETHYL ESTER

4-(Difluoromethyl)benzonitrile (-)-[(S)-1-Bromoethyl]benzene 4-METHYL(THIOBENZAMIDE)

1of3

p-Tolunitrile Suppliers

Global( 377)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Dalian Richfortune Chemicals Co., Ltd	0411-84820922 8613904096939	sales@richfortunechem.com	China	303	57
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12453	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9350	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58

Supplier	Advantage
Dalian Richfortune Chemicals Co., Ltd	57
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Yanxi Chemical Co., Ltd.	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58

View Lastest Price from p-Tolunitrile manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-05	p-Tolunitrile 104-85-8	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-06	p-Tolunitrile 104-85-8	US $30.00-10.00 / KG	50KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.
2023-08-08	p-Tolunitrile 104-85-8	US $0.00-0.00 / kg	1kg	99%	50tons	Hebei Yanxi Chemical Co., Ltd.

p-Tolunitrile
104-85-8
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

p-Tolunitrile
104-85-8
US $30.00-10.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

p-Tolunitrile
104-85-8
US $0.00-0.00 / kg
99%
Hebei Yanxi Chemical Co., Ltd.

p-Tolunitrile Spectrum

p-Tolunitrile(104-85-8)MS p-Tolunitrile(104-85-8)¹HNMR p-Tolunitrile(104-85-8)¹³CNMR p-Tolunitrile(104-85-8)IR1 p-Tolunitrile(104-85-8)Raman p-Tolunitrile(104-85-8)ESR

104-85-8(p-Tolunitrile)Related Search:

4-Nitrotoluene Sodium p-toluenesulfonate m-Toluic acid acrylonitrile-butadiene rubber p-Toluenesulfonic acid

4-Chlorotoluene Tosyl chloride p-Toluenesulfonamide 2-TOLUNITRILE Ethyl 4-cyanobenzoate

2-NITRO-4-(TRIFLUOROMETHYL)BENZONITRILE Phenyl benzonitrile 4-Cyanobenzoic acid 4-Acetylbenzonitrile 1,4-Dicyanobenzene

4,4'-BIPHENYLDICARBONITRILE Tetrafluoroterephthalonitrile Trifluoro-p-tolunitrile

1of4

Nitril kyseliny p-toluylove nitrilkyselinyp-toluylove p-Tolunitril p-Tolunitrile, 98% 100GR p-Tolunitrile, 98% 5GR P-TOLUNITRILE FOR SYNTHESIS 250 ML P-TOLUNITRILE FOR SYNTHESIS 50 ML p-Tolunitrile 1-Methyl-4-cyanobenzene 4-methyl-benzonitril 4-Toluenkarbonitril Benzonitrile,4-methyl- AKOS BBS-00004251 4-METHYLBENZENECARBONITRILE 4-CYANOTOLUENE 4-Toluyl nitrile p-Tolylnitrile P-TOLYL CYANIDE p-toluonitrile P-TOLUNITRILE p-toluic nitrile p-Toluenenitrile P-METHYLBENZONITRILE para-tolunitrile p-Tolumitrile P-Tounitrile 4-METHYLBENZONITRILE(4-CYANOTOLUENE) p-Toluonitril p-Tolunitrile, 98+% para-methylbenzonitrile JACS-104-85-8 4-Methylbenzonitrile,>98% p-Methylbenzonitrile / 4-Tolunitrile 4-METHYLBENZONITRILE 4-methylcyanobenzene 4-TOLUNITRILE P-CYANO TOLUENE CNT Tranexamic Acid Impurity 12 p-toluenitrile 104-85-8 C8H7N Benzonitriles (Building Blocks for Liquid Crystals) Building Blocks for Liquid Crystals Cyanides/Nitriles Nitrogen Compounds Organic Building Blocks C8 to C9 Building Blocks Pyridines ,Halogenated Heterocycles Aromatic Nitriles Benzene derivatives Benzonitriles (Building Blocks for Liquid Crystals) Building Blocks for Liquid Crystals Functional Materials Phenyls & Phenyl-Het Phenyls & Phenyl-Het Nitrile