ChemicalBook >> CAS DataBase List >>Bis(acetonitrile)dichloropalladium(II)
Bis(acetonitrile)dichloropalladium(II)
- CAS No.
- 14592-56-4
- Chemical Name:
- Bis(acetonitrile)dichloropalladium(II)
- Synonyms
- BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE;(MeCN)2PdCl2;bis(acetonitrile)dichloropalladium;Palladium, bis(acetonitrile)dichloro-;TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;DICHLOROBIS(ACETONITRILE)PALLADIUM(II);BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;e)dichL;Bis(acetonitriL;Bis(Acetonitrile)Pd(II)
- CBNumber:
- CB8245652
- Molecular Formula:
- C4H6Cl2N2Pd
- Molecular Weight:
- 259.43
- MDL Number:
- MFCD00013122
- MOL File:
- 14592-56-4.mol
- MSDS File:
- SDS
Last updated:2023-08-15 17:37:19
| Melting point | 300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in acetonitrile, acetone, chloroform |
| form | Fine Crystalline Powder |
| color | Orange to rust-brown |
| Water Solubility | insoluble |
| CAS DataBase Reference | 14592-56-4(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311+H331 | |||||||||
| Precautionary statements | P280-P301+P310+P330-P302+P352+P312-P304+P340+P311 | |||||||||
| Hazard Codes | T,Xn | |||||||||
| Risk Statements | 23/24/25-36/37/38-20/21/22 | |||||||||
| Safety Statements | 16-27-36/37-45-36-26 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439090 | |||||||||
| NFPA 704 |
|
Bis(acetonitrile)dichloropalladium(II) price More Price(53)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 225657 | Bis(acetonitrile)dichloropalladium(II) 99% | 14592-56-4 | 500mg | $77 | 2024-03-01 | Buy |
| Sigma-Aldrich | 225657 | Bis(acetonitrile)dichloropalladium(II) 99% | 14592-56-4 | 5g | $502 | 2024-03-01 | Buy |
| TCI Chemical | B1676 | Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) | 14592-56-4 | 1g | $279 | 2024-03-01 | Buy |
| TCI Chemical | B1676 | Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) | 14592-56-4 | 5g | $1046 | 2024-03-01 | Buy |
| Alfa Aesar | 010002 | Bis(acetonitrile)dichloropalladium(II), Pd 40.5% | 14592-56-4 | 1g | $123 | 2023-06-20 | Buy |
Bis(acetonitrile)dichloropalladium(II) Chemical Properties,Uses,Production
Reaction
- Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
- Catalyst for the aza-Michael reaction of carbamates with enones.
- Catalyst for the rearrangement of allylic imidates to allylic amides.
- Catalyst for the Nazarov cyclization of α-alkoxy dienones.
- Catalyst for the diamination of conjugated dienes.
- Three component Michael addition, cyclization, cross-coupling reaction.
- C-H activation of indoles.
- Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.
Chemical Properties
Light yellow to Brown powder to crystaline.
Physical properties
Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride.
Uses
It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.
Uses
suzuki reaction
Uses
Catalyst used in an ether-directed aza-Claisen rearrangement.
Application
Synthesis of Oxindoles
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II)
(3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred
at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to
room temperature, the reaction is diluted with EtOAc and filtered with a
glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.
Preparation
Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.
General Description
This product has been enhanced for catalytic efficiency.
Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 369)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 | huahandingcheng@sina.com | China | 342 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
View Lastest Price from Bis(acetonitrile)dichloropalladium(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-08-15 | Bis(acetonitrile)dichloropalladium(II)
14592-56-4
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2022-09-24 | Bis(acetonitrile)dichloropalladium(II)
14592-56-4
|
US $0.00 / kg | 1kg | 99% | 1000kg | henan kanbei chemical co.,ltd | |
 |
2021-11-13 | Bis(acetonitrile)dichloropalladium(II)
14592-56-4
|
US $10.00 / KG | 1KG | 99% | 5tons | Hebei Guanlang Biotechnology Co., Ltd. |
-
- Bis(acetonitrile)dichloropalladium(II)
14592-56-4
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Bis(acetonitrile)dichloropalladium(II)
14592-56-4
- US $0.00 / kg
- 99%
- henan kanbei chemical co.,ltd
-
- Bis(acetonitrile)dichloropalladium(II)
14592-56-4
- US $10.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
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DICHLOROBIS(ACETONITRILE)PALLADIUM(III)
BIS(ACETONITRILE)DICHLOROPALLADATE (II)
BIS(ACETONITRILE)DICHLOROPALLADIUM(II)
bis (acetontrile) dichloropalladium (II)
BIS(ACETONITRILE)DICHLOROPALLADIUM(II), 99.99%
BIS(ACETONITRILE)DICHLOROPALLADIUM(II),99%
TRANS-BIS(ACETONITRILE) DICHLOROPALLADIUM(II)
BIS-(ACETONITRIL)DICHLOROPALLADIUM(II)
Dichlorobis(acetonitrile)palladium(II),99%
Palladium(II)chloro-bis(acetonitrile)
DICHLOROBIS(ACETONITRILE)PALLADIUM(II) (41%PD)
BIS(ACETONITRILE)PALLADIUM (II) CHLORIDE 99%
BIS(ACETONITRILE)PALLADIUM()CHLORIDE
Bis(acetonitrile)dichloropalladium(II), Pd 40.5%
Trans-dichlorobis(acetonitrile)palladium(II) Can be used to form catalysts in situ by separate addition of ligand
Bis(acetonitriL
e)dichL
PALLADIUM(2+) ION BIS(ACETONITRILE) DICHLORIDE
Bis(acetonitrile)palladium(Ⅱ) chloride
Acetonitrile - dichloropalladium (2:1)
(II)Bis(acetonitrile)dichloropalladium(II)
TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHL
Bis(acetonitrile)palladium(II) Dichloride >
Bis(acetonitrile)dichloropalladium(II) ISO 9001：2015 REACH
Bis(Acetonitrile)Pd(II)
palladium(2+) bis(acetonitrile) dichloride
Bis(Acetonitrile)Dichloropalladium (II) extrapure, 99%, ~41% Pd
DICHLOROBIS (ACETONITRILE) PALLADIUM (II) For Synthesis
TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE
(MeCN)2PdCl2
DICHLOROBIS(ACETONITRILE)PALLADIUM(II)
BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE
BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE
bis(acetonitrile)dichloropalladium
Palladium, bis(acetonitrile)dichloro-
Di-(acetonitrile) palladium chloride
chloranuidylpalladiobis(ylium)]chloranuide
14592-56-4
C4H6Cl2N2Pd
C4H6N2PdCl2
C4Cl4N2Pd
Catalysis and Inorganic Chemistry
Homogeneous Pd Catalysts
Transition Metal Compounds
Homogeneous Catalysts