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ChemicalBook >> CAS DataBase List >>(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Structure
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE structure
CAS No.
828927-94-2
Chemical Name:
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE
Synonyms
(R,S)-O-PINAP;(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1S)-;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine,Min.95%(R,S)-O-PINAP;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP
CBNumber:
CB82466259
Molecular Formula:
C38H29N2OP
Molecular Weight:
560.62
MDL Number:
MFCD11973799
MOL File:
828927-94-2.mol
Last updated:2023-04-23 13:52:06
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(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Properties

Melting point 178-181°C
alpha -160.4° (c 0.53, CHCl3)
Boiling point 726.4±60.0 °C(Predicted)
pka 3.45±0.30(Predicted)
form crystal
color colorless
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1783 (S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP 828927-94-2 250mg $114 2021-12-16 Buy
Strem Chemicals 15-1783 (S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP 828927-94-2 1g $342 2021-12-16 Buy
Product number Packaging Price Buy
15-1783 250mg $114 Buy
15-1783 1g $342 Buy

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Chemical Properties,Uses,Production

Reaction

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
  2. With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
  3. With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
Reactions of 828927-94-2

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Suppliers

Global( 12)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41132 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Rhawn Reagent 400-400-1332688 18019345275 amy@rhawn.cn China 15503 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-88888888 420970979@qq.com China 2806 58
Shanghai Han-Xiang Chemical Co., Ltd. 15971444841 amber@biochempartner.com China 3063 58
Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44941 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 025-025-58280381 15720605021 zhang_lei@jsnchem.com China 1457 58
Shanghai Haohong Pharmaceutical Co., Ltd. 400-8210725 4008210725 malulu@leyan.com China 39997 58
Beijing Solarbio Science & Tecnology Co., Ltd. 010-50973130 17801761073 Gsiyu@solarbio.com China 50751 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Bide Pharmatech Ltd. 60
LaaJoo 58
Rhawn Reagent 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Shanghai Han-Xiang Chemical Co., Ltd. 58
Energy Chemical 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 58
Shanghai Haohong Pharmaceutical Co., Ltd. 58
Beijing Solarbio Science & Tecnology Co., Ltd. 58
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine,Min.95%(R,S)-O-PINAP (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE (R,S)-O-PINAP (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE (S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1S)- 828927-94-2 Chiral Phosphine PINAP Series