2-Bromo-1-bromomethyl-5-chlorobenzene
- CAS No.
- 66192-24-3
- Chemical Name:
- 2-Bromo-1-bromomethyl-5-chlorobenzene
- Synonyms
- 2-Bromo-1-bromomethyl-5-chlorobenzene;Benzene, 1-bromo-2-(bromomethyl)-4-chloro-
- CBNumber:
- CB82502904
- Molecular Formula:
- C7H5Br2Cl
- Molecular Weight:
- 284.38
- MDL Number:
- MFCD09743743
- MOL File:
- 66192-24-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Bromo-1-bromomethyl-5-chlorobenzene | B680600 | 1g | $80 |
| 2-Bromo-1-bromomethyl-5-chlorobenzene | FB19053 | 50g | $95 |
| 2-Bromo-1-bromomethyl-5-chlorobenzene | FB19053 | 100g | $152 |
| 2-Bromo-1-bromomethyl-5-chlorobenzene | FB19053 | 25g | $60 |
| 2-Bromo-1-bromomethyl-5-chlorobenzene | FB19053 | 250g | $305 |
| More product size | |||
| Melting point | 63-64°C |
|---|---|
| Boiling point | 281.5±25.0 °C(Predicted) |
| Density | 1.933 |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Solid |
| color | White |
| InChI | InChI=1S/C7H5Br2Cl/c8-4-5-3-6(10)1-2-7(5)9/h1-3H,4H2 |
| InChIKey | UTKGZXVMMFBCJC-UHFFFAOYSA-N |
| SMILES | C1(Br)=CC=C(Cl)C=C1CBr |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 |
2-Bromo-1-bromomethyl-5-chlorobenzene price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | B680600 | 2-Bromo-1-bromomethyl-5-chlorobenzene | 66192-24-3 | 1g | $80 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB19053 | 2-Bromo-1-bromomethyl-5-chlorobenzene | 66192-24-3 | 50g | $95 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB19053 | 2-Bromo-1-bromomethyl-5-chlorobenzene | 66192-24-3 | 100g | $152 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB19053 | 2-Bromo-1-bromomethyl-5-chlorobenzene | 66192-24-3 | 25g | $60 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB19053 | 2-Bromo-1-bromomethyl-5-chlorobenzene | 66192-24-3 | 250g | $305 | 2021-12-16 | Buy |
2-Bromo-1-bromomethyl-5-chlorobenzene Chemical Properties,Uses,Production
Chemical Properties
Colourless Oil
Synthesis
14495-51-3
66192-24-3
The general procedure for the synthesis of 2-bromo-5-chlorobenzyl bromide from 2-bromo-5-chlorotoluene was as follows: 20.5 g (100 mmol) of 2-bromo-5-chlorotoluene was dissolved in 200 mL of carbon tetrachloride, followed by the addition of 0.2 g (1 mmol) of AIBN (azobisisobutyronitrile) and 19.6 g (110 mmol) of N-bromosuccinimide (NBS). The resulting mixture was refluxed for 2 h and then cooled to room temperature. The reaction mixture was sequentially washed twice with 50 mL of water, then with 50 mL of brine solution and finally dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure to give an oil containing a small amount of unreacted material. The oily substance was dissolved in 20 mL of hexane and recrystallized at room temperature to give 22.7 g (80% yield) of 2-bromo-1-bromomethyl-5-chlorobenzene. The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.50 (d, 1H, J = 8.7 Hz), 7.45 (d, 1H, J = 2.4 Hz), 7.15 (dd, 1H, J = 8.7 Hz, 2.4 Hz), 4.53 (s, 2H).
References
[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 31, p. 6404 - 6409
[2] Patent: WO2005/123054, 2005, A1. Location in patent: Page/Page column 25
[3] Patent: WO2006/46030, 2006, A2. Location in patent: Page/Page column 28
[4] Organic Letters, 2015, vol. 17, # 19, p. 4654 - 4657
[5] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 19, p. 2903 - 2909
2-Bromo-1-bromomethyl-5-chlorobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Affinity（Wuhan）Ltd. | +86-+undefined-0411-39805809 +86-+undefined-15841022315 | sales@affinitytech.cn | China | 126 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20128 | 58 |
| Hefei Lbao Physical & Chemical Science Co.,Ltd | +1-5184799099 | lbaochemicals@gmail.com | China | 656 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29833 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 9948 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
| Finetech Industry Limited | +86-27-8746-5837 +8619945049750 | info@finetechnology-ind.com | China | 9629 | 58 |
View Lastest Price from 2-Bromo-1-bromomethyl-5-chlorobenzene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-01-24 | 1-Bromo-2-(bromomethyl)-4-chlorobenzene
66192-24-3
|
US $0.00 / kg | 1kg | 98% | Customise | Hefei Lbao Physical & Chemical Science Co.,Ltd | |
 |
2025-09-25 | 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
|
US $80.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2025-04-04 | 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- 1-Bromo-2-(bromomethyl)-4-chlorobenzene
66192-24-3
- US $0.00 / kg
- 98%
- Hefei Lbao Physical & Chemical Science Co.,Ltd
-
- 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
- US $80.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
