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TETRAKIS(DIETHYLAMINO)TITANIUM

Description Reference
TETRAKIS(DIETHYLAMINO)TITANIUM
TETRAKIS(DIETHYLAMINO)TITANIUM structure
CAS No.
4419-47-0
Chemical Name:
TETRAKIS(DIETHYLAMINO)TITANIUM
Synonyms
TDEAT;amino)titanium(IV);titanium diethylamide;TITANIUM (IV) DIETHYLAMIDE;TETRAKIS(DIETHYLAMINO)TITANIUM;Tetrakis(diethylamion)titanium;TITANIUM TETRAKIS(DIETHYLAMIDE);TETRAKIS (DIETHYLAMIDO) TITANIUM;Titanium(IV) Diethylamide 99.99%;Titanium, tetrakis(diethylamino)-
CBNumber:
CB8264181
Molecular Formula:
C16H40N4Ti
Formula Weight:
336.38
MOL File:
4419-47-0.mol

TETRAKIS(DIETHYLAMINO)TITANIUM Properties

Melting point:
4 °C
Boiling point:
112 °C0.1 mm Hg(lit.)
Density 
0.931 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.536(lit.)
Flash point:
-18 °F
storage temp. 
Store at +2°C to +8°C.
solubility 
Reacts with air.
form 
liquid
Specific Gravity
0.95
color 
yellow to orange
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
3621431
CAS DataBase Reference
4419-47-0(CAS DataBase Reference)
NIST Chemistry Reference
Tetrakis(diethylamino)titanium(4419-47-0)
EPA Substance Registry System
Ethanamine, N-ethyl-, titanium(4+) salt (4419-47-0)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H225-H260-H314-H261-H318
Precautionary statements  P303+P361+P353-P305+P351+P338-P405-P501a-P210-P223-P231+P232-P280-P370+P378-P422
Hazard Codes  F,C,Xi
Risk Statements  11-14/15-34-36/37/38
Safety Statements  26-36/37/39-43-45-37/39-16
RIDADR  UN 3398 4.3/PG 1
WGK Germany  3
10-21
TSCA  Yes
HS Code  2921 19 50
HazardClass  4.3
PackingGroup  II

TETRAKIS(DIETHYLAMINO)TITANIUM price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.14018 Tetrakis(diethylamino)titanium for synthesis 4419-47-0 5 mL $258.07 2021-03-22 Buy
Sigma-Aldrich 469866 Tetrakis(diethylamido)titanium(IV) 99.999% trace metals basis 4419-47-0 25g $515 2021-03-22 Buy
Sigma-Aldrich 469866 Tetrakis(diethylamido)titanium(IV) 99.999% trace metals basis 4419-47-0 5g $284 2021-03-22 Buy
Alfa Aesar 040469 Tetrakis(diethylamino)titanium(IV) 99.99% (metals basis) 4419-47-0 50g $641 2021-03-22 Buy
Alfa Aesar 040469 Tetrakis(diethylamino)titanium(IV) 99.99% (metals basis) 4419-47-0 10g $166 2021-03-22 Buy

TETRAKIS(DIETHYLAMINO)TITANIUM Chemical Properties,Uses,Production

Description

Tetrakis (diethylamino) titanium is useful Ti-source precusor. Tetrakis (diethylamino) titanium is useful in TiN film deposition using the atomic layer deposition method1,2. It is also a useful compound during the process of etching a layer of diamond like carbon.

Reference

  1. Kim, Ju Youn, et al. "Comparison of TiN Films Deposited Using Tetrakisdimethylaminotitanium and Tetrakisdiethylaminotitanium by the Atomic Layer Deposition Method." Japanese Journal of Applied Physics 42.7A (2003):4245-4248.
  2. Katamreddy, Rajesh, et al. "Ti source precursors for atomic layer deposition of TiO2, STO and BST." Ecs Transactions 16.4(2008):660-71.
  3. Shoemaker, Erika Leigh, et al. "Process for reactive ion etching a layer of diamond like carbon." US, US8409458. 2013.

Chemical Properties

Clear dark red liquid

Purification Methods

Dissolve it in *C6H6, filter if a solid separates, evaporate under reduced pressure and distil it. It is an orange liquid which reacts violently with alcohols. [Bradley et al. J Chem Soc 3857 1960, Beilstein 4 IV 313.]

TETRAKIS(DIETHYLAMINO)TITANIUM Preparation Products And Raw materials

Raw materials

Preparation Products


TETRAKIS(DIETHYLAMINO)TITANIUM Suppliers

Global( 58)Suppliers
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City Chemical LLC
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INTATRADE GmbH +49 3493/605464
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Alfa Aesar 400-610-6006
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