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(S)-(R)-JOSIPHOS

(S)-(R)-JOSIPHOS structure

CAS No.: 162291-02-3

Chemical Name:: (S)-(R)-JOSIPHOS

Synonyms: Josiphos SL-J001-2 / (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine;(S)-(R)-JOSIPHOS;JOSIPHOS SL-J001-2;97% (S)-(R)-JOSIPHOS;(S)1 (1R)2(DIPHENYLPHOSPHINO)FERROCENYL&;(S)-1-[(R)-2-(Diphenylphosphino)ferrocenyl];(S)1[(1R)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos;(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicycloh...;(S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE;(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

CBNumber:: CB8268578

Molecular Formula:: C36H44FeP210*

Molecular Weight:: 594.53

MDL Number:: MFCD00800285

MOL File:: 162291-02-3.mol

MSDS File:: SDS

Last updated:2023-05-04 15:15:12

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(S)-(R)-JOSIPHOS Properties

alpha	+360° (c 0.5, CHCl3)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	orange
Stability	store cold

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H319-H315-H335
Precautionary statements	P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
F	10
HS Code	29319090

(S)-(R)-JOSIPHOS price More Price(21)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	88718	(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ≥97%	162291-02-3	1g	$662	2024-03-01	Buy
Sigma-Aldrich	88718	(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ≥97%	162291-02-3	5g	$2250	2023-01-07	Buy
Strem Chemicals	26-1211	(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, min. 97% (S)-(R)-JOSIPHOS	162291-02-3	100mg	$107	2024-03-01	Buy
Strem Chemicals	26-1211	(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, min. 97% (S)-(R)-JOSIPHOS	162291-02-3	500mg	$375	2024-03-01	Buy
Sigma-Aldrich	88718	(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ≥97%	162291-02-3	100mg	$87.6	2024-03-01	Buy

Product number	Packaging	Price	Buy
88718	1g	$662	Buy
88718	5g	$2250	Buy
26-1211	100mg	$107	Buy
26-1211	500mg	$375	Buy
88718	100mg	$87.6	Buy

(S)-(R)-JOSIPHOS Chemical Properties,Uses,Production

Reactions

Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic,functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain.4 These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
Pd-catalyzed, enantioselective, intramolecular α-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles.
Asymmetric boron conjugate addition of α,β-unsaturated carbonyl compounds catalyzed by
CuOTf/Josiphos under non-alkaline conditions.
Chiral amides via copper-catalyzed enantioselective conjugate addition.
Ruthenium-catalyzed enantioselective synthesis of β-amino alcohols from 1,2-diols by “borrowing hydrogen”.
Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes.

Chemical Properties

Dark orange powder

General Description

sold in collaboration with Solvias AG

(S)-(R)-JOSIPHOS Preparation Products And Raw materials

Raw materials

DICYCLOHEXYLPHOSPHINE

Preparation Products

(S)-(R)-JOSIPHOS Suppliers

Global( 84)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	402	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Wuhan Pengo Technology.,Ltd.	+86-27-81330736 +86-13628634921	sunny.w@boronicgroup.com	CHINA	171	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Wuhan Pengo Technology.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58

View Lastest Price from (S)-(R)-JOSIPHOS manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-07-27	Josiphos SL-J001-2 / (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine 162291-02-3	US $0.00-0.00 / g	1KG	0.99	500kg	XINXIANG RUNYU MATERIAL CO., LTD.
	2019-07-06	di(naphthalen-1-yl)phosphine oxide 162291-02-3	US $1.00 / KG	1G	98%	1MT	Career Henan Chemical Co

Josiphos SL-J001-2 / (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
162291-02-3
US $0.00-0.00 / g
0.99
XINXIANG RUNYU MATERIAL CO., LTD.

di(naphthalen-1-yl)phosphine oxide
162291-02-3
US $1.00 / KG
98%
Career Henan Chemical Co

162291-02-3((S)-(R)-JOSIPHOS)Related Search:

1,3-BIS(DIMETHYLPHOSPHINO)PROPANE JOSIPHOS SL-J011-1,JOSIPHOS SL-J011-2 (R)-(S)-JOSIPHOS,(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphineethanoladduct,min.97%(R)-(S)-JOSIPHOS,JOSIPHOS SL-J001-1 TRIHEXYLPHOSPHINE TRIISOPROPYLPHOSPHINE

JOSIPHOS SL-J005-1 JOSIPHOS SL-J002-2 JOSIPHOS SL-J002-1,Josiphos SL-J002-1, (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS) JOSIPHOS SL-J009-1 DICYCLOHEXYLPHOSPHINE

Ferrocene JOSIPHOS SL-J003-1 Josiphos SL-J004-2, (1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS),JOSIPHOS SL-J004-2 (S)-(R)-JOSIPHOS 1,3-BIS(PHOSPHINO)PROPANE

JOSIPHOS SL-J418-2 JOSIPHOS SL-J013-1 Josiphos SL-J003-2, (1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]ferrocene (acc to CAS)

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(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct,97% (S)-(R)-JOSIPHOS (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct (S)-(R)-JOSIPHOS (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine >=97% (2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene JOSIPHOS SL-J001-2 (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (S)-(+)-1-[(R)-2-(Diphenylphospino)ferrocenyl] ethylbicyclohexylphosphine 97% (S)-(R)-JOSIPHOS Ferrocene, 1-[(1S)-1-(dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)-, (2S)- (S,S)-1-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]-2-(DIPHENYLPHOSPHINO)FERROCENE (S)-(R)-JOSIPHOS (S)1[(1R)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos (S)-1-[(R)-2-(Diphenylphosphino)ferrocenyl] (S)1 (1R)2(DIPHENYLPHOSPHINO)FERROCENYL& (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphineethanoladduct,min.97%(S)-(R)-JOSIPHOS (S)-(R)-Josiphos, Josiphos SL-J001-2, (2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS) (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine ethanol adduct cyclopentane,dicyclohexyl-[(1S)-1-(2-diphenylphosphanylcyclopentyl)ethyl]phosphane,iron (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicycloh... (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine [(S)-(R)-Josiphos] Josiphos SL-J001-2 / (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine (S)-(+)-1-[(Rp)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphineethanoladduct (2Rp)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene 162291-02-3 Privileged Ligands Solvias Ligands Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine Ferrocene Series Josiphos Series organophosphine ligand