ChemicalBook >> CAS DataBase List >>5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
![5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Structure](CAS/20180808/GIF/942939-38-0.gif)
- CAS No.
- 942939-38-0
- Chemical Name:
- 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
- Synonyms
- f]azepine;Reaxys ID: 21143615;5-(11bS)-Dinaphtho[2;5-(11bS)-Dinaphtho[2,1-d;2]dioxaphosphepin-4-yl-5H-dibenz[b;3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine;(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
- CBNumber:
- CB82750837
- Molecular Formula:
- C34H22NO2P
- Molecular Weight:
- 507.53
- MDL Number:
- MFCD22666424
- MOL File:
- 942939-38-0.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 246 °C |
|---|---|
| Boiling point | 711.5±63.0 °C(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| pka | -2.70±0.20(Predicted) |
| form | solid |
| color | yellow |
| Sensitive | air sensitive, moisture sensitive |
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 744646 | (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine ≥95% (elemental analysis) | 942939-38-0 | 100mg | $110 | 2024-03-01 | Buy |
| Sigma-Aldrich | 744646 | (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine ≥95% (elemental analysis) | 942939-38-0 | 500mg | $350 | 2024-03-01 | Buy |
| Strem Chemicals | 15-1227 | (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97% | 942939-38-0 | 100mg | $90 | 2024-03-01 | Buy |
| Strem Chemicals | 15-1227 | (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97% | 942939-38-0 | 500mg | $354 | 2024-03-01 | Buy |
| Ambeed | A857931 | (S)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine 98%99%ee | 942939-38-0 | 5g | $990 | 2021-12-16 | Buy |
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Chemical Properties,Uses,Production
Reaction
- The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
- The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
- The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction.
Uses
Phosphorous precursor for ligand synthesis
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Preparation Products And Raw materials
Raw materials
Preparation Products
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Suppliers
Global( 36)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44700 | 61 |
| Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 7182 | 65 |
| Tianjin Derchemist Science & Technology Co., Ltd. | 22-58627059 13920586291 | zdcomcon@126.com | China | 3296 | 50 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 18112977050 | cb6@aikonchem.com | China | 16687 | 50 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
| Shanghai Chiral bio-compound co., Ltd. | 021-5068 3667/17749785980/1029026415; 17749785980 | 1029026415@qq.com | China | 3013 | 58 |
| Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-65511006 18625597674 | sales@kingorgchem.com | China | 953 | 55 |
| LaaJoo | 021-60702684 18516024827 | huang.jiayi@sinocompound.com | China | 2654 | 58 |
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)-dibenzo[b,f]azepine >=95% (elemental analysis)
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
(S)-(+)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)-5H-DIBENZ[B,F]AZEPINE,MIN.97%
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
Reaxys ID: 21143615
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
5-(11bS)-Dinaphtho[2,1-d
5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl
5H-Dibenz[b,f]azepine, 5-(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-
2]dioxaphosphepin-4-yl-5H-dibenz[b
5-(11bS)-Dinaphtho[2
f]azepine
5-((11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-5H-dibenzo[b,f]azepine
3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
5-(11bS)-Dinaphtho[2,1-d:1’,2’-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl
942939-38-0
C34H22NO2P
Chiral Phosphine
CPN