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Zirconium tetrachloride

Zirconium tetrachloride
Zirconium tetrachloride structure
CAS No.
10026-11-6
Chemical Name:
Zirconium tetrachloride
Synonyms
ZrCl4;ZIRCONIUM CHLORIDE;ZirconiuM(IV) chlor;Zirconium(Ⅳ)chloride;tetrachlorozirconium;Zirconium tetrachlor;ZIRCONIUM(+4)CHLORIDE;Zrconium Tetrachloride;ZIRCONIUM(IV) CHLORIDE;tetra-zirconiumchlorid
CBNumber:
CB8298375
Molecular Formula:
Cl4Zr
Formula Weight:
233.04
MOL File:
10026-11-6.mol

Zirconium tetrachloride Properties

Melting point:
437 °C
Boiling point:
331°C
Density 
2.8 g/mL at 25 °C(lit.)
vapor pressure 
1 mm Hg ( 190 °C)
storage temp. 
Store below +30°C.
solubility 
Soluble in alcohol, ether, hydrochloric acid.
form 
powder
color 
White
Specific Gravity
2.803
PH
<1 (H2O, 20℃)(saturated aqueous solution)
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive & Hygroscopic
Merck 
14,10174
CAS DataBase Reference
10026-11-6(CAS DataBase Reference)
NIST Chemistry Reference
Zirconium tetrachloride(10026-11-6)
EPA Substance Registry System
Zirconium tetrachloride (10026-11-6)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS05
Signal word  Danger
Hazard statements  H290-H314-H302-H318
Precautionary statements  P280-P305+P351+P338-P310-P260h-P301+P330+P331-P303+P361+P353-P405-P501a
Hazard Codes  C
Risk Statements  14-22-34-35
Safety Statements  26-36/37/39-45-8
RIDADR  UN 2503 8/PG 3
WGK Germany  3
RTECS  ZH7175000
19
TSCA  Yes
HS Code  2827 39 85
HazardClass  8
PackingGroup  III
Toxicity LD50 in mice, rats (mg/kg): 665, 1688 orally (Zhilova, Kasparov)
NFPA 704
0
3 2

Zirconium tetrachloride price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 221880 Zirconium(IV) chloride ≥99.5% trace metals basis 10026-11-6 5g $96.2 2019-12-02 Buy
Sigma-Aldrich 221880 Zirconium(IV) chloride ≥99.5% trace metals basis 10026-11-6 100g $260 2019-12-02 Buy
Alfa Aesar 012104 Zirconium(IV) chloride, Reactor Grade 99.5+% (metals basis) 10026-11-6 10g $35.9 2019-12-02 Buy
Alfa Aesar 012104 Zirconium(IV) chloride, Reactor Grade 99.5+% (metals basis) 10026-11-6 100g $45.6 2019-12-02 Buy
Strem Chemicals 40-4046 Zirconium(IV) chloride, sublimed grade (99.95+%-Zr) 10026-11-6 50g $23 2019-12-02 Buy

Zirconium tetrachloride Chemical Properties,Uses,Production

Chemical Properties

White, lustrous crystals. Sublimes above 300C. Soluble in alcohol; decomposes in water.

Chemical Properties

Zirconium tetrachloride forms lustrous, white, monoclinic crystals that melt at 437 ℃. It is a corrosive powder. It is hygroscopic, and thus soluble in cold water, alcohol, ether, and concentrated hydrochloric acid. It reacts vigorously with water forming hydrogen chloride (irritating vapor) and zirconium oxychloride. When moist, zirconium tetrachloride reacts with common materials to form hydrochloric acid that is corrosive to many metals. Through hydrolysis to HCl, zirconium tetrachloride can irritate the respiratory tract and other superficial surfaces of the body on exposure. Zirconium tetrachloride readily forms coordinate bonds with oxygen and nitrogen in organic molecules.

Uses

For applications in organozirconium chemistry.1Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.2

Uses

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.1

Uses

Friedel-Crafts catalyst. Component of Ziegler-type catalysts in the condensation of ethylene. Starting material in the synthesis of a number of organic derivatives of zirconium, such as alkoxides and zircocene. The alkoxides have been shown to be of value in the curing of silicone plastic films. The alkoxyzirconium carboxylates are said to be useful in the water-repellent treatment of textiles and other fibrous materials.

Definition

ChEBI: A zirconium coordination entity comprising four chlorine atoms bound to a central zirconium atom.

General Description

White lustrous crystalline solid. Used as a source of pure zirconium, as a tanning agent, in analytical chemistry and in treating textiles. Zirconium tetrachloride is decomposed by water. Corrosive to metals in the presence of moisture and to tissue.

Air & Water Reactions

Reacts vigorously with water forming hydrochloric acid with the evolution of heat.

Reactivity Profile

Zirconium tetrachloride is corrosive to metals in the presence of moisture and to tissue. Behavior in Fire: Will not burn - sublimes above 626°F (331°C). May give off HCl fumes [USCG, 1999]. Zirconium tetrachloride is incompatible with alcohols (ethanol), lithium metal, and tetrahydrofuran.

Health Hazard

INHALATION: Irritating to upper respiratory tract; presumably caused by liberated HCl. EYES: Irritating. SKIN: Irritating. INGESTION: Burning pain in the mouth and throat, vomiting, watery or bloody diarrhea, retching, collapse, and convulsions.

Fire Hazard

Behavior in Fire: Will not burn - sublimes above 626°F (331°C). May give off HCl fumes.

Safety Profile

Moderately toxic by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. Ignites spontaneously in air. When heated to decomposition it emits toxic fumes of Cl-. See also ZIRCONIUM COMPOUNDS and HYDROCHLORIC ACID.

Purification Methods

Crystallise it repeatedly from conc HCl. It is hydrolysed by H2O to form white ZrOCl2 (see below) and HCl. [Krebs Z Anorg Allgem Chem 378 263 1970.]

Zirconium tetrachloride Preparation Products And Raw materials

Raw materials

Preparation Products


Zirconium tetrachloride Suppliers

Global( 175)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
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Mainchem Co., Ltd.
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Chemwill Asia Co.,Ltd.
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TopScience Biochemical
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View Lastest Price from Zirconium tetrachloride manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-04-04 Zirconium tetrachloride
10026-11-6
US $1.00-1.00 / kg 1 kg/桶 Zr ≥36% High quality purified manufacturer Chemwill Asia Co.,Ltd.
2019-11-08 Zirconium Chloride
10026-11-6
US $140.00 / KG 1KG 99% 100 Metric Ton/Metric Tons per Month Hebei Xibaijie Biotechnology Co., Ltd.
2019-08-21 zirconium oxychloride
10026-11-6
US $1.00 / g 1g 99.9% 10000kg Cangzhou Wanyou New Material Technology Co.,Ltd

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