ALLYL CINNAMATE
- CAS No.
- 1866-31-5
- Chemical Name:
- ALLYL CINNAMATE
- Synonyms
- Nsc20972;FEMA 2022;Wln: 1U2ov1U1r;ALLYL CINNAMATE;propenylcinnamate;Propenyl cinnamate;allyl (E)-cinnamate;Allyl CinnaMate allyl3-phenylacrylate;ALLYL CINNAMATE, 99+%
- CBNumber:
- CB8304551
- Molecular Formula:
- C12H12O2
- Molecular Weight:
- 188.22
- MDL Number:
- MFCD00026105
- MOL File:
- 1866-31-5.mol
| Boiling point | 150-152 °C15 mm Hg(lit.) |
|---|---|
| Density | 1.053 g/mL at 25 °C(lit.) |
| refractive index |
n |
| FEMA | 2022 | ALLYL CINNAMATE |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| color | A colourless or pale straw-coloured liquid. |
| Odor | at 100.00 %. fruity balsamic pineapple spicy cinnamyl plum apricot peach |
| Odor Type | fruity |
| JECFA Number | 19 |
| LogP | 2.93 |
| Substances Added to Food (formerly EAFUS) | ALLYL CINNAMATE |
| FDA 21 CFR | 172.515 |
| CAS DataBase Reference | 1866-31-5(CAS DataBase Reference) |
| EWG's Food Scores | 1-2 |
| FDA UNII | N8149Z51V9 |
| EPA Substance Registry System | 2-Propenoic acid, 3-phenyl-, 2-propenyl ester (1866-31-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P301+P312+P330 |
| Hazard Codes | Xn |
| Risk Statements | 22 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| RTECS | GD8050000 |
| HS Code | 29163100 |
| Toxicity | The acute oral LD50 value in rats was reported as 1.52 g/kg and the acute dermal LD50 value in rabbits as less than 5 g/kg(Levenstein, 1975). |
ALLYL CINNAMATE price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 1133999 | Allyl cinnamate United States Pharmacopeia (USP) Reference Standard | 1866-31-5 | 5x0.5ml | $397 | 2022-05-15 | Buy |
| TCI Chemical | C0878 | Allyl Cinnamate (stabilized with TBC) >98.0%(GC) | 1866-31-5 | 25g | $60 | 2021-12-16 | Buy |
| Sigma-Aldrich | W202207 | Allyl cinnamate ≥99% | 1866-31-5 | sample | $54.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | W202207 | Allyl cinnamate ≥99% | 1866-31-5 | 100g | $84 | 2024-03-01 | Buy |
| Sigma-Aldrich | W202207 | Allyl cinnamate ≥99% | 1866-31-5 | 1kg | $405 | 2024-03-01 | Buy |
ALLYL CINNAMATE Chemical Properties,Uses,Production
Identification
Description
A colorless liquid with peachor apricot-like aroma. It is used as a flavoring agent or adjuvant.
Regulatory Status
CoE: n/a
FDA: 21 CFR 172.515
FDA (other): n/a
JECFA: ADI: Acceptable. No safety concern at current levels of intake when used as a flavoring agent (1996).
Usage
Reported uses (ppm): (FEMA, 1994)
Natural occurrence
Not reported found in nature.
Chemical Properties
A colorless liquid with peach- or apricot-like aroma. It is used as a flavoring agent or adjuvant.
Occurrence
Has apparently not been reported to occur in nature.
Uses
Allyl Cinnamate is a synthetic flavoring agent that is a fairly stable, hazy, colorless to light yellow colored liquid of cherry odor. it is used for its cherry note in flavors and has application in baked goods and candies at 1–2 ppm.
Definition
ChEBI: Allyl cinnamate is a cinnamate ester.
Production Methods
Allyl cinnamate is produced by the direct esterification of allyl alcohol with cinnamic acid.
Preparation
By esterification of cinnamic acid with allyl alcohol in the presence of concentrated H2SO4.
Synthesis Reference(s)
Tetrahedron, 48, p. 1219, 1992 DOI: 10.1016/S0040-4020(01)90785-9
Tetrahedron Letters, 36, p. 113, 1995 DOI: 10.1016/0040-4039(94)02179-F
Safety Profile
Moderately toxic by ingestion. Human skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS
Metabolism
Many esters, including benzyl cinnamate, are rapidly hydrolysed in vivo. Cinnamic acid is known to conjugate with glycine in the animal body, or it may be converted to benzoic acid(Williams, 1959). In the rabbit, cinnamic acid is almost entirely excreted as hippuric acid, without formation of cinnamoyl glycine(El Masry, Smith & Williams, 1956) . In the dog, Quick(1928) observed a large excretion of glucuronide, probably benzoylglucuronide. Dakin (1909) named B-phenyl-B-oxopropionic acid, cinnamoyl glycine and acetophenone as minor metabolites in the dog.
ALLYL CINNAMATE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 18192627656 | 1012@dideu.com | China | 3422 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 29220 | 58 |
| Baoji Guokang Bio-Technology Co., Ltd. | 0917-3909592 13892490616 | gksales1@gk-bio.com | China | 9339 | 58 |
| Baoji Guokang Healthchem co.,ltd | +8615604608665 15604608665 | dominicguo@gk-bio.com | CHINA | 9427 | 58 |
View Lastest Price from ALLYL CINNAMATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-03-06 | Allyl cinnamate
1866-31-5
|
US $5.70 / Kg/Drum | 10g | 99% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2023-01-31 | Allyl Cinnamate
1866-31-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2021-07-13 | ALLYL CINNAMATE
1866-31-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- Allyl cinnamate
1866-31-5
- US $5.70 / Kg/Drum
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
-
- Allyl Cinnamate
1866-31-5
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- ALLYL CINNAMATE
1866-31-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd