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9-Bromophenanthrene

CAS No.
573-17-1
Chemical Name:
9-Bromophenanthrene
Synonyms
9 - bromide;9 - broMine fe;9-Bromophenathrene;9-Bromophenanthene;9-BROMOPHENANTHRENE;9-bromo-phenanthren;9-phenathrylbromide;9-Bromo Phenantrene;9-Phenathryl bromide;9-Phenanthryl bromide
CBNumber:
CB8312934
Molecular Formula:
C14H9Br
Molecular Weight:
257.13
MDL Number:
MFCD00001174
MOL File:
573-17-1.mol
MSDS File:
SDS
Last updated:2024-02-29 11:36:44

9-Bromophenanthrene Properties

Melting point 60-64 °C (lit.)
Boiling point 180-190 °C/2 mmHg (lit.)
Density 1.4251 (rough estimate)
refractive index 1.6404 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility chloroform: 50 mg/mL, clear
form Powder
color Light yellow
BRN 1869927
InChI InChI=1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H
InChIKey RSQXKVWKJVUZDG-UHFFFAOYSA-N
SMILES C1=C2C(C3C(C(Br)=C2)=CC=CC=3)=CC=C1
CAS DataBase Reference 573-17-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII N4XAW27Z35
NIST Chemistry Reference Phenanthrene, 9-bromo-(573-17-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
RTECS  SF7197000
8
Hazard Note  Irritant
HS Code  29036990
NFPA 704
1
0 0

9-Bromophenanthrene price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B75409 9-Bromophenanthrene 96% 573-17-1 10g $76 2024-03-01 Buy
Sigma-Aldrich B75409 9-Bromophenanthrene 96% 573-17-1 25g $79.6 2024-03-01 Buy
TCI Chemical B0838 9-Bromophenanthrene >98.0%(GC) 573-17-1 25g $99 2024-03-01 Buy
TCI Chemical B0838 9-Bromophenanthrene >98.0%(GC) 573-17-1 250g $625 2024-03-01 Buy
Alfa Aesar L09033 9-Bromophenanthrene, 98% 573-17-1 5g $26.65 2024-03-01 Buy
Product number Packaging Price Buy
B75409 10g $76 Buy
B75409 25g $79.6 Buy
B0838 25g $99 Buy
B0838 250g $625 Buy
L09033 5g $26.65 Buy

9-Bromophenanthrene Chemical Properties,Uses,Production

Description

9-Bromophenanthrene is a luminescent material that fluoresces at short wavelengths and can be used as a molecular probe to detect the presence of other compounds and the mechanism of reaction, among other things.

Chemical Properties

light yellow powder. soluble in toluene, and chloroform (50 mg/ml).

Uses

9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.

Preparation

9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.

91-20-3
573-17-1
Synthesis of 9-Bromophenanthrene from Naphthalene
Global( 367)Suppliers
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Nanjing Triumpharm Co.,Ltd
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ATK CHEMICAL COMPANY LIMITED
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View Lastest Price from 9-Bromophenanthrene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
9-Bromophenanthrene pictures 2024-03-29 9-Bromophenanthrene
573-17-1
US $35.00 / KG 1KG 98% 300MT/year Speranza Chemical Co., Ltd.
9-Bromophenanthrene pictures 2024-02-29 9-Bromophenanthrene
573-17-1
US $450.00 / g 1g 97 500 Kg R&D Scientific Inc.
9-Bromophenanthrene pictures 2023-12-26 9-Bromophenanthrene
573-17-1
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
9-BROMOPHENANTHRENE 9-Bromophenathrene 9-Bromophenanthrene,95% 9-Bromophenanthrene,97% Phenanthrene, 9-bromo- 9-Bromoanth raceme 96% 9-Bromophenanthrene,96% 9-BroMophenanthrene, 96% 10GR 9-BroMophenanthrene, 96% 25GR 9-BROMOPHENANTHRENE FOR SYNTHESIS 9 - broMine fe 9-bromo-phenanthren 9-Phenanthryl bromide 9-Phenathryl bromide 9-phenathrylbromide 9-Bromophenanthrene > 9 - bromide 9-Bromophenanthrene ISO 9001:2015 REACH 9-Bromophenanthrene-98% 9-Bromophenanthene 9-Bromo Phenantrene 573-17-1 573-17-2 C14H9B BrC14H9 C149Br Halogenated Hydrocarbons Organic Building Blocks Building Blocks C13 to C37+ Aryl ARYL HALIDE blocks Bromides Miscellaneous Aryl C13 to C37+ Halogenated Hydrocarbons Aromatic Compounds bc0001