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Dichloro(1,5-cyclooctadiene)platinum(II)

Dichloro(1,5-cyclooctadiene)platinum(II) structure

CAS No.: 12080-32-9

Chemical Name:: Dichloro(1,5-cyclooctadiene)platinum(II)

Synonyms: pt(cod)cl2;Dichloro(1,5-cyclooctadiene)platinum;NSC 239486;ooctadiene)pL;Platinum(COD)dichloride;Dichloro(1,5-cyclooctadiene);5-cyclooctadiene)platinum(II);1,5-Cyclooctadienedichloroplatinum;Dichloro(1,5-cyclooctadiene)platin(II);(1,5-Cyclooctadiene)platinum dichloride

CBNumber:: CB8338684

Molecular Formula:: C8H12Cl2Pt

Molecular Weight:: 374.16

MDL Number:: MFCD00012413

MOL File:: 12080-32-9.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:59:07

Product description	Number	Pack Size	Price
Dichloro(1,5-cyclooctadiene)platinum(II)	244937	250mg	$50.3
Dichloro(1,5-cyclooctadiene)platinum(II)	244937	1g	$191
Dichloro(1,5-cyclooctadiene)platinum(II)	D3592	1g	$334
Dichloro(1,5-cyclooctadiene)platinum(II)	D3592	200mg	$114
Dichloro(1,5-cyclooctadiene)platinum(II), 99% 99%	78-0430	250mg	$54
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Dichloro(1,5-cyclooctadiene)platinum(II) Properties

Melting point	285 °C (dec.) (lit.)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Soluble in dichloromethane
form	Crystals or Crystalline Powder
color	White to pale yellow
Water Solubility	insoluble
Sensitive	Hygroscopic
InChI	InChI=1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey	VVAOPCKKNIUEEU-PHFPKPIQSA-L
SMILES	C1CC=CCCC=C1.[Pt](Cl)Cl \|c:2,6\|
CAS DataBase Reference	12080-32-9(CAS DataBase Reference)
FDA UNII	P4ZP76Z957
NIST Chemistry Reference	(Cyclocta-1,5-diene)platinum(ii)chloride(12080-32-9)
EPA Substance Registry System	Platinum, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12080-32-9)
UNSPSC Code	12161600
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

TSCA

TSCA listed

HS Code

28439000

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		1

Dichloro(1,5-cyclooctadiene)platinum(II) price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	244937	Dichloro(1,5-cyclooctadiene)platinum(II)	12080-32-9	250mg	$50.3	2026-04-30	Buy
Sigma-Aldrich	244937	Dichloro(1,5-cyclooctadiene)platinum(II)	12080-32-9	1g	$191	2026-04-30	Buy
TCI Chemical	D3592	Dichloro(1,5-cyclooctadiene)platinum(II)	12080-32-9	1g	$334	2026-04-30	Buy
TCI Chemical	D3592	Dichloro(1,5-cyclooctadiene)platinum(II)	12080-32-9	200mg	$114	2026-04-30	Buy
Strem Chemicals	78-0430	Dichloro(1,5-cyclooctadiene)platinum(II), 99% 99%	12080-32-9	250mg	$54	2026-04-30	Buy

Product number	Packaging	Price	Buy
244937	250mg	$50.3	Buy
244937	1g	$191	Buy
D3592	1g	$334	Buy
D3592	200mg	$114	Buy
78-0430	250mg	$54	Buy

Dichloro(1,5-cyclooctadiene)platinum(II) Chemical Properties,Uses,Production

Chemical Properties

white to pale yellow

Uses

it is used in Hydrosilyation reactions.

Uses

Catalyst for:

Hydrogenative cyclization of allenynes
Stereoselective tandem hydrosilylation-Hiyama coupling reactions
Amino alkene cyclohydroamination
Hydrative cyclization reactions
Direct amination of allylic alcohols under mild conditions

Potential anticancer agent

reaction suitability

core: platinum
reagent type: catalyst

Synthesis

10025-99-7

5259-72-3

12080-32-9

2.1.4.1 Synthesis of cis-dichloro(1,5-cyclooctadiene)platinum(II), [Pt(cod)Cl2] (0014): K2PtCl4 (1.000 g, 2.4 mmol) was dissolved in water (16 mL) and the resulting solution was filtered. Acetic acid (24 mL) and 1,5-cyclooctadiene (cod) (1.00 mL, 8.1 mmol) were sequentially added to the filtrate under light protection. The reaction mixture was stirred and heated in a water bath at about 100°C. Within 30 minutes, the dark red solution gradually changed to a pale yellow color with the formation of a precipitate. After about 2 h, the solution was concentrated to a volume of 10 mL by distillation under reduced pressure, after which the resulting precipitate was separated by centrifugation and washed sequentially with water, ethanol and ether. Product yield: 703 mg (80%).1H NMR (CDCl3) δ: 5.60 (4H, t, CH), 2.70 (2H, m, CH2-CH), 2.30-2.16 (2H, m, CH2-CH) ppm; 13C{1H} NMR (CDCl3) δ: 100.0 (CH), 30.0 (CH2) ppm. 195Pt NMR (CDCl3) δ: -3340 ppm.

References

[1] Chemistry - An Asian Journal, 2018, vol. 13, # 8, p. 1053 - 1059
[2] Dalton Transactions, 2008, # 47, p. 6724 - 6731
[3] Organometallics, 2014, vol. 33, # 15, p. 4027 - 4034
[4] Journal of the American Chemical Society, 2015, vol. 137, # 42, p. 13464 - 13467
[5] Journal of Inorganic Biochemistry, 2016, vol. 160, p. 275 - 286

Dichloro(1,5-cyclooctadiene)platinum(II) Preparation Products And Raw materials

Raw materials

Stannous chloride dihydrate Potassium tetrachloroplatinate(II) 1,5-Cyclooctadiene 1-Propanol [1E,5Z,pR]-1,5-Cyclooctadiene

Dichloromethane Acetic acid Tetraethylammonium Chloride

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Preparation Products

DICHLORO(DICYCLOPENTADIENYL)PLATINUM(II) DIIODO(1,5-CYCLOOCTADIENE)PLATINUM (II)

Dichloro(1,5-cyclooctadiene)platinum(II) Suppliers

Global( 229)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16513	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13843	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21590	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2972	58
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	sales@worldyachem.com	China	967	58
Wuhan Pengo Technology.,Ltd.	+86-27-81330736 +86-13628634921	sunny.w@boronicgroup.com	CHINA	171	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Springchem New Material Technology Co.,Limited	57
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Shanghai Worldyang Chemical Co.,Ltd.	58
Wuhan Pengo Technology.,Ltd.	58

View Lastest Price from Dichloro(1,5-cyclooctadiene)platinum(II) manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-04-17	Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9	US $2.00-5.00 / kg	1kg	99%	100kg	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2026-03-20	Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9	US $0.00 / KG	1KG	99%	100 MT	Hebei Chuanghai Biotechnology Co., Ltd
2024-04-28	Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9	US $50.00 / kg	1kg	99.10%	50000kg	Ouhuang Engineering Materials (Hubei) Co., Ltd

Dichloro(1,5-cyclooctadiene)platinum(II)
12080-32-9
US $2.00-5.00 / kg
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Dichloro(1,5-cyclooctadiene)platinum(II)
12080-32-9
US $0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

Dichloro(1,5-cyclooctadiene)platinum(II)
12080-32-9
US $50.00 / kg
99.10%
Ouhuang Engineering Materials (Hubei) Co., Ltd

Dichloro(1,5-cyclooctadiene)platinum(II) Spectrum

Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)MS Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)¹HNMR Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)¹³CNMR Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)IR1 Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)IR2 Dichloro(1,5-cyclooctadiene)platinum(II)(12080-32-9)Raman

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Dichloro(1,5-cyclooctadiene)platinum(II) 250 dec. Dichloro(1,5-cyclooctadiene)platinum(II),98% Dichloro(1,5-cyclooctadiene)platinum(II), Pt 51.6-52.6% Dichloro(1,5-cyclooctadiene)platinum(II),99% Dichloro(cycloocta-1,5-diene)platinum(II),Pt52.1% Dichloro(1,5-cyclooctadiene)platinum(II) ,98% [C%:24.15-27.15%] Dichloro(1,5-cyclooctadiene)platinum(II),Pt(COD)Cl2 Dichloro(1,5-cyclooctadiene)platin(II) Dichloro(1,5-cyclooctadiene)platinum(Ⅱ) Dichloro(1,5-cyclooctadiene)platinum(II) (1,5-Cyclooctadiene)platinum(II) dichloride (1,5-Cyclooctadiene)platinum dichloride NSC 239486 Dichloro(1,5-cyclooctadiene) (1,5-CYCLOOCTADIENE)PLATINUM(II) DICHLORIDE 1,5-Cyclooctadienedichloroplatinum dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-platinu Platinum, dichloro(1,5-cyclooctadiene)- Platinum, dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]- DICHLORO(1,5-CYCLOOCTADIENE)PLATINATE (II) DICHLORO(1,5-CYCLOOCTADIENE)PLATINUM(II) DICHLORO(CYCLOOCTA-1,5-DIENE)PLATINUM(II) DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PLATINUM (II) dichloro[(1,2,5,6-eta)-cycloocta-1,5-diene]platinum Platinum(COD)dichloride 5-cyclooctadiene)platinum(II) ooctadiene)pL Dichloro(1,5-cyclooctadiene)platinum(II) ISO 9001：2015 REACH Dichloro[(1,2,5,6-η)-1,5-cyclooctadiene]-platinum pt(cod)cl2 Dichloro(1,5-cyclooctadiene)platinum Dichloro(1,5-cyclooctadiene) platinium(II) (1Z,5Z)-cycloocta-1,5-diene dichloroplatinum ichloro(1,5-cyclooctadiene)platinum(II) Dichloro(1,5-cyclooctadiene)platinum (Ⅱ) 12080-32-9 PtCl2C8H12 C8H12Cl2Pt PtCl215C8H12 Catalysis and Inorganic Chemistry Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes Pt (Platinum) Compounds Synthetic Organic Chemistry Transition Metal Compounds chemical reaction,pharm,electronic,materials organometallic complexes Pt