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Phosphorus tribromide

Phosphorus tribromide
Phosphorus tribromide structure
CAS No.
7789-60-8
Chemical Name:
Phosphorus tribromide
Synonyms
PBr3;extrema[qr];tribromophosphine;Phosphortribromid;tribroMophosphane;PHOSPHORUS BROMIDE;phosphorousbromide;phosphrous broMide;Phosphorous bromide;Phosphorus(Ⅲ)bromide
CBNumber:
CB8372891
Molecular Formula:
Br3P
Formula Weight:
270.69
MOL File:
7789-60-8.mol

Phosphorus tribromide Properties

Melting point:
-40 °C
Boiling point:
175 °C(lit.)
Density 
2.88 g/mL at 20 °C(lit.)
vapor pressure 
0.27 psi ( 54 °C)
refractive index 
n20/D 1.697(lit.)
Flash point:
172.9°C
storage temp. 
-20°C
form 
Liquid
Specific Gravity
2.88
color 
Clear to slightly hazy colorless to yellow or light brown
Water Solubility 
reacts
FreezingPoint 
-40℃
Sensitive 
Moisture Sensitive
Merck 
14,7357
BRN 
3903060
Stability:
Stable, but reacts violently with water. Incompatible with moisture, strong bases, strong oxidizing agents, reactive metals, acids, alcohols.
CAS DataBase Reference
7789-60-8(CAS DataBase Reference)
NIST Chemistry Reference
Phosphorus tribromide(7789-60-8)
EPA Substance Registry System
Phosphorous tribromide(7789-60-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  C
Risk Statements  34-37-40-14-67
Safety Statements  26-45-36/37-36/37/39
RIDADR  UN 3264 8/PG 2
WGK Germany  2
RTECS  TH4460000
21
TSCA  Yes
HS Code  2812 90 00
HazardClass  8
PackingGroup  II
Hazardous Substances Data 7789-60-8(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

NFPA 704

Diamond Hazard Value Description
0
3 2
W
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
Instability   2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
Special   W

(NFPA, 2010)

Phosphorus tribromide price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 157783 Phosphorus tribromide 97% 7789-60-8 100g $61.5 2018-11-13 Buy
Sigma-Aldrich 157783 Phosphorus tribromide 97% 7789-60-8 500g $135 2018-11-13 Buy
TCI Chemical P1743 Phosphorus Tribromide >98.0%(T) 7789-60-8 300g $37 2018-11-22 Buy
Alfa Aesar 040191 Phosphorus(III) bromide, 99% (metals basis) 7789-60-8 25g $38.8 2018-11-16 Buy
Alfa Aesar 040191 Phosphorus(III) bromide, 99% (metals basis) 7789-60-8 100g $66.5 2018-11-16 Buy

Phosphorus tribromide Chemical Properties,Uses,Production

Chemical Properties

(possibly hazy) liquid

Uses

Used in tests for skin corrosivity.

General Description

A colorless fuming liquid with a pungent odor. Corrosive to metals and tissue. Boiling point 347°F (175°C). Freezing point -40°F (-40°C).

Air & Water Reactions

Fumes in air. Decomposed by water to form phosphoric acid and hydrobromic acid. Reaction with warm water is very rapid and may be violent [Mellor v.8. 1032 1940].

Reactivity Profile

Phosphorus tribromide reacts with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive; the reactions may be violent. Forms complexes with potassium or sodium metal that explode when shocked. Drop wise addition to 3-phenylpropanol caused an explosion when stirring of the mixture was discontinued [Chem. Brit., 1974, 10, 101-102].

Health Hazard

Inhalation causes severe irritation of nose, throat, and lungs. Ingestion causes burns of mouth and stomach. Contact with eyes or skin causes severe burns.

Safety Profile

Probably highly toxic. A corrosive irritant to the eyes, skin, and mucous membranes. Wdl react with water, steam, or acids to produce heat, toxic and corrosive fumes. Violent reaction or ignition with calcium hydroxide + sodium carbonate, phenylpropanol, sulfuric acid, oleum, fluorosulfuric acid, chlorosulfuric acid, 1,1,1 -tris(hydroxymethyl)methane, water, potassium, sodium, RuO4. When heated to decomposition it emits very toxic fumes of Brand POx. See also PHOSPHIDES and BROMIDES.

Purification Methods

It is decomposed by moisture, it should be kept dry and is corrosive. Purify it by distillation through an efficient fractionating column [see Whitmore & Lux J Am Chem Soc 54 3451] in a slow stream of dry N2, i.e. under strictly dry conditions. [Gay & Maxson Inorg Synth II 147 1946, Org Synth Col Vol II 358 1943.] Dissolve it in CCl4, dry it over CaCl2, filter and distil it. Store it in sealed ampoules under N2 and keep it away from light. HARMFUL VAPOURS.

Phosphorus tribromide Preparation Products And Raw materials

Raw materials

Preparation Products


Phosphorus tribromide Suppliers

Global( 213)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Yancheng Longshen Chemical Co.,Ltd.
86-0515-88706880 86-18352073353
86-0515-88706880 sales@longshenchem.com CHINA 78 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21967 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6374 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20095 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20104 58
Secco work (Beijing) chemical technology co., LTD 010-69755668;
010-69755668 1139670422@qq.com China 3571 54
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727 shenlinxing@macklin.cn China 15724 55
Shanghai Kaisai Chemical Co., Ltd 021-33516711 , 33516722
021-33516776 kaisaichem@163.com China 5957 58

View Lastest Price from Phosphorus tribromide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-18 Phosphorus tribromide
7789-60-8
US $1.00 / kg 1kg 99% Customized career henan chemical co

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