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(R)-DM-BINAP

Reaction
(R)-DM-BINAP
(R)-DM-BINAP structure
CAS No.
137219-86-4
Chemical Name:
(R)-DM-BINAP
Synonyms
Xylbinap;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy
CBNumber:
CB8381549
Molecular Formula:
C52H48P2
Formula Weight:
734.89
MOL File:
137219-86-4.mol

(R)-DM-BINAP Properties

Melting point:
203-206°C
alpha 
169 º (c=1 in chloroform)
form 
crystal
color 
white to pale yellow
optical activity
[α]20/D +169°, c = 1 in chloroform
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
WGK Germany  3
Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

(R)-DM-BINAP price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692379 (R)-DM-BINAP 137219-86-4 100mg $34.3 2018-11-20 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 137219-86-4 200mg $46 2018-11-22 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 137219-86-4 1g $158 2018-11-22 Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 137219-86-4 500mg $249 2018-11-13 Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 137219-86-4 100mg $83.2 2018-11-13 Buy

(R)-DM-BINAP Chemical Properties,Uses,Production

Reaction

  1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
  2. Ligand used in the enantioselective fluorination of oxindoles.
  3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
  4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
  5. Asymmetric hydroboration of unsaturated imines.

(R)-DM-BINAP Preparation Products And Raw materials

Raw materials

Preparation Products


(R)-DM-BINAP Suppliers

Global( 72)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21745 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20672 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23967 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8260 58
LaaJoo 021-60702684
021-60702684 zhu.yijing@sinocompound.com China 2771 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30163 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24555 81

View Lastest Price from (R)-DM-BINAP manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-04-04 (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
137219-86-4
US $6.00 / kg 1kg High quality Professional Factory Ms Ella chemwill_asia@126.com www.chemwill.com Chemwill Asia Co.,Ltd.

137219-86-4((R)-DM-BINAP)Related Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN] (S)-DM-BINAP,RAC-XYLYL-BINAP,(S)-3,5-XYLYL-BINAP,(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(S)-3,5-xylyl-BINAP,(S)-(-)-2,2''-BIS(DI(3,5-XYLYL)PHOSPHINO)-1,1''-BINAPHTYL (S)-3,5-XYLYL-BINAP,(S)-(-)-2,2''-BIS(DI(3,5-XYLYL)PHOSPHINO)-1,1''-BINAPHTHYL (S)-3,5-XYLYL-BINAP,(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , 98% ((S)-Xylyl-BINAP) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] (R)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2] DM-BINAP,2,2μ-Bis[di(3,5-xylyl)phoshino]-1,1μ-binaphthyl, 3,5-Xylyl-BINAP, 2,2μ-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1μ-binaphthyl,RACEMIC-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (RAC-XYLYL-BINAP),RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL, 98% RAC-3,5-XYLYL-BINAP,rac-2,2'-Bis(di(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl,98%rac-Xylyl-BINAP,RAC-XYLYL-BINAP (S)-Ru(OAc)2(DM-BINAP) (S)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-Ru(OAc)2(DM-BINAP)

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