Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(R)-DM-BINAP

(R)-DM-BINAP

(R)-DM-BINAP Structure
(R)-DM-BINAP structure
CAS No.
137219-86-4
Chemical Name:
(R)-DM-BINAP
Synonyms
Xylbinap;(R)-(+)-XyL;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
CBNumber:
CB8381549
Molecular Formula:
C52H48P2
Molecular Weight:
734.89
MDL Number:
MFCD01630821
MOL File:
137219-86-4.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:35
Request For Quotation

(R)-DM-BINAP Properties

Melting point 203-206°C
Boiling point 825.3±65.0 °C(Predicted)
alpha 169 º (c=1 in chloroform)
storage temp. Inert atmosphere,Room Temperature
Water Solubility Insoluble in water
form crystal
color white to pale yellow
optical activity [α]20/D +169°, c = 1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Risk Statements  36/37/38
Safety Statements  26-37
WGK Germany  3
TSCA  No
HS Code  2931.90.6000
NFPA 704
1
2 0

(R)-DM-BINAP price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692379 (R)-DM-BINAP 137219-86-4 100mg $78.7 2024-03-01 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 137219-86-4 200mg $60 2024-03-01 Buy
TCI Chemical X0070 (R)-(+)-XylBINAP >97.0%(HPLC) 137219-86-4 1g $203 2024-03-01 Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 137219-86-4 500mg $214 2021-12-16 Buy
Alfa Aesar H27680 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 137219-86-4 100mg $72.4 2021-12-16 Buy
Product number Packaging Price Buy
692379 100mg $78.7 Buy
X0070 200mg $60 Buy
X0070 1g $203 Buy
H27680 500mg $214 Buy
H27680 100mg $72.4 Buy

(R)-DM-BINAP Chemical Properties,Uses,Production

Reaction

  1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
  2. Ligand used in the enantioselective fluorination of oxindoles.
  3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
  4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
  5. Asymmetric hydroboration of unsaturated imines.
Reactions of 137219-86-4

Uses

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-DM-BINAP Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-DM-BINAP Suppliers

Global( 122)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49390 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Jinan Honest Pharm Co., Ltd 		+8615318812076 zpy8217@163.com China 286 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
Baoji Guokang Healthchem co.,ltd 		+8615604608665 15604608665 dominicguo@gk-bio.com CHINA 9427 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
Richest Group Ltd 		58
Jinan Honest Pharm Co., Ltd 		58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		58
Baoji Guokang Healthchem co.,ltd 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58

View Lastest Price from (R)-DM-BINAP manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl pictures 2020-06-02 (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
137219-86-4
 US $6.00 / kg 1kg High quality Professional Factory Ms Ella chemwill_asia@126.com www.chemwill.com Chemwill Asia Co.,Ltd.
(R)-DM-BINAP pictures 2019-08-30 (R)-DM-BINAP
137219-86-4
 US $1.00-2.00 / KG 1KG 95%-99% 100KG Career Henan Chemical Co
  • (R)-DM-BINAP pictures
  • (R)-DM-BINAP
    137219-86-4
  • US $1.00-2.00 / KG
  • 95%-99%
  • Career Henan Chemical Co

(R)-DM-BINAP Spectrum

(R)-DM-BINAP(137219-86-4)1HNMR(R)-DM-BINAP(137219-86-4)31PNMR

137219-86-4((R)-DM-BINAP)Related Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-(+)-TolBINAP
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]
(R)-3,5-XYLYL-BINAP (S)-Ru(OAc)2(DM-BINAP) (S)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-Ru(OAc)2(DM-BINAP) RuCl2[(R)-DM-BINAP][(R)-DAIPEN]
RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] (R)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]

1of4

(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL (R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL RAC-XYLYL-BINAP (R)-3,5-XYLYL-BINAP (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP (R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl (R)-3,5-Xyl-BINAP (R)-DM-BINAP Xylbinap (r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy PHOSPHINE, 1,1''-[(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)- (R)-(+)-2,2μ-Bis[di(3,5-xylyl)phosphino]-1,1μ-binaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine] 2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL 2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL (R)-(+)-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (R)-3,5-XYLYL-BINAP (R)-Xylyl-BINAP 1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-Phosphine (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, 98%((R)-Xylyl-BINAP) 98% (R)-XylBINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98% (R)-(+)-XylBINAP (R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP) (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (R)-(+)-XyL (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap (r)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl 137219-86-4 BINAP Series Chiral Phosphine