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Fluroxypyr

CAS No.
69377-81-7
Chemical Name:
Fluroxypyr
Synonyms
ADVANCE;4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid;((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci;ef-689;ff4014;FLUROXYPYR;Advance(TM);Fluroxypyr(Starane);Fluroxypyr Solution;Fluroxypyr Standard
CBNumber:
CB8389671
Molecular Formula:
C7H5Cl2FN2O3
Molecular Weight:
255.03
MDL Number:
MFCD01311822
MOL File:
69377-81-7.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:20

Fluroxypyr Properties

Melting point 57.5°C
Boiling point 399.4±37.0 °C(Predicted)
Density 1.3
storage temp. Sealed in dry,2-8°C
solubility DMSO (Slightly), Methanol (Slightly)
pka 2.22±0.10(Predicted)
color White to Off-White
Merck 13,4229
BRN 7136185
LogP 3.160 (est)
CAS DataBase Reference 69377-81-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 8O40SHO197
NIST Chemistry Reference Fluroxypyr(69377-81-7)
Pesticides Freedom of Information Act (FOIA) Fluroxypyr
EPA Substance Registry System Fluroxypyr (69377-81-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H412
Precautionary statements  P273-P501
Risk Statements  52/53
Safety Statements  61
RIDADR  UN3077(solid)
WGK Germany  2
RTECS  AF2500000
Toxicity LD50 orally in rats: 2405 mg/kg; i.p. in male, female rats: 458, 519 mg/kg; percutaneous in rabbits >5000 mg/kg (Paul)

Fluroxypyr price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45758 Fluroxypyr PESTANAL?, analytical standard 69377-81-7 100mg $79.8 2024-03-01 Buy
TRC F598780 Fluroxypyr 69377-81-7 250mg $205 2021-12-16 Buy
American Custom Chemicals Corporation PST0000137 FLUROXYPYR 95.00% 69377-81-7 500MG $721.88 2021-12-16 Buy
American Custom Chemicals Corporation PST0000137 FLUROXYPYR 95.00% 69377-81-7 5G $1299.38 2021-12-16 Buy
Atlantic Research Chemicals CA002427 [(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]aceticacid(Fluroxypyr) 95% 69377-81-7 250mgs: $130.78 2021-12-16 Buy
Product number Packaging Price Buy
45758 100mg $79.8 Buy
F598780 250mg $205 Buy
PST0000137 500MG $721.88 Buy
PST0000137 5G $1299.38 Buy
CA002427 250mgs: $130.78 Buy

Fluroxypyr Chemical Properties,Uses,Production

Chemical Properties

White crystalline solid.

Uses

Fluroxypyr is a systemic and selective herbicide. Fluroxypyr is used for the control of broad-leaved weeds in small grain cereals, maize, pastures, range land and turf. Fluroxypyr is a synthetic auxin .

Uses

Fluroxypyr is a systemic and selective herbicide. Fluroxypyr is used for the control of broad-leaved weeds in small grain cereals, maize, pastures, range land and turf. Fluroxypyr is a synthetic auxin.

Definition

ChEBI: An aminopyridine that is pyridin-4-amine substituted by chloro groups at positions 3 and 5, a fluoro group at position 6 and a carboxymethoxy group at position 2.

Trade name

methyl ester: AGROSTAR; BOFIX FFC®; CABADEX®; CASCADE®; DOWCO® 433 MHE; FOREFRONT®; GALAXY GL184®; PARADIGM®; PASTUREGARD®; STARANE®; TOMAHAWK®; VISTA®; WIDEMATCH®, (fluroxypyr + clopyralid); XRM-5084®

Potential Exposure

Those who manufacture, distribute or use this pyridinecarboxylic acid/pyridine herbicide.

Environmental Fate

The DT50 in soil is relatively short, ranging from 5 to 9 days in experiments conducted in the laboratory. This rapid degradation is due to microbes.Because of its rapid soil degradation, little fluroxypyr is available for other dissipation processes, e.g., leaching.

Metabolism

Fluroxypyr is stable under acidic conditions and moderately stable in alkaline conditions; e.g., the DT50 in water at pH 9 is 185 days. Degradation occurs at temperatures above its melting point. Fluroxypyr is stable in light.
Plant. The metabolism of fluroxypyr has not been fully described. Conjugates of fluroxypyr have been observed in tolerant plants.
Soil. Fluroxypyr is rapidly metabolized by soil microbes via the removal of the carboxyl group or acetic acid group, yielding 4-amino-3,5-dichloro-6-fluoro- 2-methoxypyridine, and 4-amino-3,5-dichloro-6-fluoro-2- pyridinol, respectively.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.

Toxicity evaluation

Mammalian Toxicity. Fluroxypyr appears to be rapidly excreted, unmodified, in the urine of animals. The acute oral LD50 for rat is 2405 mg/kg.
Weed Resistance/Modified Crop Tolerance. Fuerst et al. (48) reported fluroxypyr resistance in yellow starthistle (Centaurea solstitialis). No crops with modified tolerance toward fluroxypyr are currently in production.

Incompatibilities

May not be compatible with nitrates. Moisture may cause hydrolysis or other forms of decompo sition; forming a strong acid. Temperatures above 250℃ can cause decomposition. Methyl ester: Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is suffi ciently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solu tions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Waste Disposal

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an after burner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti cide containers.

1737-93-5
69377-81-7
Synthesis of Fluroxypyr from 3,5-Dichloro-2,4,6-trifluoropyridine

Fluroxypyr Preparation Products And Raw materials

Global( 193)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9352 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 7838 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58

View Lastest Price from Fluroxypyr manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Fluroxypyr pictures 2023-02-07 Fluroxypyr
69377-81-7
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
Fluroxypyr pictures 2020-11-16 Fluroxypyr
69377-81-7
US $40.00 / Kg/Bag 1Kg/Bag 99% 20 Tons Longyan Tianhua Biological Technology Co., Ltd
	Fluroxypyr pictures 2019-07-06 Fluroxypyr
69377-81-7
US $11.00 / KG 1KG 99% 1000KG Career Henan Chemical Co
  • Fluroxypyr pictures
  • Fluroxypyr
    69377-81-7
  • US $10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • Fluroxypyr pictures
  • Fluroxypyr
    69377-81-7
  • US $40.00 / Kg/Bag
  • 99%
  • Longyan Tianhua Biological Technology Co., Ltd
  • 	Fluroxypyr pictures
  • Fluroxypyr
    69377-81-7
  • US $11.00 / KG
  • 99%
  • Career Henan Chemical Co
ff4014 [(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]acetic acid 2-[(4-AMino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic Acid 2-((4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy)acetic acid ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)acetic acid ef-689 FLUROXYPYR 4,5-amino-3,5-dichloro-6-fluoro-2-pyridinyloxyacetic acid fluroxypyr 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid 2-(4-Amino-3,5-dichloro-6-fluoropyrin-2-yl)oxyacetic acid Fluroxypyr(Starane) FLUROXYPYR PESTANAL (4-AMINO-3,5-DI CHLO Acetic acid, (4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy- fluroxypyr (bsi,iso) Fluroxypyr Solution, 1000ppm Aceticacid, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]- 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid octan-2-yl ester Advance(TM) Fluroxypyr Solution Fluroxypyr Standard Fluroxypyr @100 μg/mL in MeOH Commercial Fluroxypyr 250g/L EC Selective Broadleaf Herbicide 69377-81-7 ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid ADVANCE 69377-81-7 C7H5CI2FN2O3 C7H5Cl2FN2O3 Alpha sort E-GAlphabetic F FA - FLPesticides&Metabolites Herbicides Pesticides&Metabolites Pyridine