ChemicalBook >> CAS DataBase List >>2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- CAS No.
- 7428-60-6
- Chemical Name:
- 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- Synonyms
- Tris(trimethylsilyl)silanol;Tris(trimethylsilyl)silanol >=95%;Hydroxy-tris(trimethylsilyl)silane;2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- CBNumber:
- CB84805003
- Molecular Formula:
- C9H28OSi4
- Molecular Weight:
- 264.66
- MDL Number:
- MFCD00093727
- MOL File:
- 7428-60-6.mol
- MSDS File:
- SDS
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- price
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Chemical Properties,Uses,Production
Uses
Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
Synthesis of 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- from TETRAKIS(TRIMETHYLSILYL)SILANE
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Preparation Products And Raw materials
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
Tris(trimethylsilyl)silanol
Tris(trimethylsilyl)silanol >=95%
Hydroxy-tris(trimethylsilyl)silane
7428-60-6
C9H28OSi4