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N-Formylmorpholine

N-Formylmorpholine structure

CAS No.: 4394-85-8

Chemical Name:: N-Formylmorpholine

Synonyms: 4-FORMYLMORPHOLINE;4-Morpholinecarbaldehyde;Formmorpholime;N-Formylmorphol;N-Formylmorfolin;N-Formyl Morpholin;N-FORMYLMORPHOLINE;TIMTEC-BB SBB007670;Morpholine, 4-formyl-;4-Formylmorpholine>

CBNumber:: CB8684608

Molecular Formula:: C5H9NO2

Molecular Weight:: 115.13

MDL Number:: MFCD00006170

MOL File:: 4394-85-8.mol

MSDS File:: SDS

Last updated:2023-12-24 21:24:35

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N-Formylmorpholine Properties

Melting point	20-23 °C (lit.)
Boiling point	236-237 °C (lit.)
Density	1.145 g/mL at 25 °C (lit.)
vapor pressure	0.03 hPa (20 °C)
refractive index	n20/D 1.485(lit.)
Flash point	>230 °F
storage temp.	Store below +30°C.
solubility	SOLUBLE
pka	-0.75±0.20(Predicted)
form	Liquid
color	Clear yellow
PH	10 (250g/l, H2O, 20℃)
explosive limit	1.2-8.2%(V)
Water Solubility	SOLUBLE
Sensitive	Hygroscopic
BRN	110293
LogP	-1.2 at 23℃
CAS DataBase Reference	4394-85-8(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	D1E63XO4RH
NIST Chemistry Reference	N-Formylmorpholine(4394-85-8)
EPA Substance Registry System	4-Morpholinecarboxaldehyde (4394-85-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H317

Precautionary statements

P261-P272-P280-P302+P352-P333+P313-P362+P364

Risk Statements

36/37/38

Safety Statements

23-24/25

WGK Germany

RTECS

QD9694000

Autoignition Temperature

345 °C DIN 51794

TSCA

Yes

HS Code

29349990

Toxicity

LD50 orally in Rabbit: > 7360 mg/kg LD50 dermal Rabbit > 18400 mg/kg

NFPA 704

	1
2		0

N-Formylmorpholine price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.18582	N-Formylmorpholine for synthesis	4394-85-8	100ML	$59.2	2024-03-01	Buy
Sigma-Aldrich	8.18582	N-Formylmorpholine for synthesis	4394-85-8	500ML	$166	2024-03-01	Buy
Sigma-Aldrich	250376	4-Formylmorpholine 99%	4394-85-8	100g	$51.4	2024-03-01	Buy
Sigma-Aldrich	250376	4-Formylmorpholine 99%	4394-85-8	500g	$173	2024-03-01	Buy
TCI Chemical	F0157	4-Formylmorpholine >99.0%(GC)	4394-85-8	25g	$22	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.18582	100ML	$59.2	Buy
8.18582	500ML	$166	Buy
250376	100g	$51.4	Buy
250376	500g	$173	Buy
F0157	25g	$22	Buy

N-Formylmorpholine Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

4-Formylmorpholine has been used in the preparation of:

adenine hydrochloride labelled with ¹⁴C
terphenyl dialdehyde

Uses

4-Formylmorpholine is widely used as a solvent and extracting agent for aromatics. It is used as a scrubbing agent for acidic gases. It is employed in the preparation of adenine hydrochloride labeled with 14C, 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde and terphenyl dialdehyde. It plays an important role in the desulfurization of natural gas, synthetic gas, flue gas and gasoline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 199, 1960 DOI: 10.1021/jo01072a012

General Description

Treatment of 4-formylmorpholine with sulphur tetrafluoride in the presence of potassium fluoride gives 4-(trifluoromethyl)morpholine in excellent yields. 4-Formylmorpholine reacts with series of 2-alkyl-2-cyclohexen-1-ones in the presence of POCl₃ to give the corresponding 3-alkyl-2-chloro-5,6-dihydrobenzaldehydes and allylic alcohols (by-product).

Flammability and Explosibility

Non flammable

N-Formylmorpholine synthesis

Synthesis of N-Formylmorpholine from Morpholine and Formic acid

N-Formylmorpholine Preparation Products And Raw materials

Raw materials

Methyl formate Morpholine Butanal, 2,2-dichloro-3-oxo- 1,1-Dichloroacetone N,N'-Dimorpholinomethane

Formaldehyde

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Preparation Products

Thiazole-4-carboxaldehyde Morpholine, 4-(methoxymethyl)- 3-Methoxybenzyl chloride 6-CHLORO-5-METHYLPYRIDINE-3-CARBALDEHYDE (E)-3,5-dichloro-4-(3-ethoxy-2-methyl-3-oxoprop-1-enyl)benzoic acid

[2，2’]bithiophenyl-5,5'-dicarbaldehyde 4-METHYL-2-THIAZOLECARBOXALDEHYDE 97 3-METHYL-1H-PYRAZOLE-4-CARBALDEHYDE 4,4'-Biphenyldicarboxaldehyde 4-Methylmorpholine

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N-Formylmorpholine Suppliers

Global( 353)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Hebei Duling International Trade Co. LTD	+8618032673083	sales05@hbduling.cn	China	15745	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7786	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58

Supplier	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Duling International Trade Co. LTD	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from N-Formylmorpholine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-24	N-Formylmorpholine 4394-85-8	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-11-02	N-formylmorpholine 4394-85-8	US $80.00 / kg	1kg	99%	100tons	Hebei Duling International Trade Co. LTD
2023-09-19	N-Formylmorpholine 4394-85-8	US $0.00 / kg	1kg	0.99	20tons	Hebei Yanxi Chemical Co., Ltd.

N-Formylmorpholine
4394-85-8
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

N-formylmorpholine
4394-85-8
US $80.00 / kg
99%
Hebei Duling International Trade Co. LTD

N-Formylmorpholine
4394-85-8
US $0.00 / kg
0.99
Hebei Yanxi Chemical Co., Ltd.

N-Formylmorpholine Spectrum

N-Formylmorpholine(4394-85-8)MS N-Formylmorpholine(4394-85-8)¹HNMR N-Formylmorpholine(4394-85-8)¹³CNMR N-Formylmorpholine(4394-85-8)IR1 N-Formylmorpholine(4394-85-8)IR2 N-Formylmorpholine(4394-85-8)Raman

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