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METHYLTRIPHENOXYPHOSPHONIUM IODIDE

CAS No.
17579-99-6
Chemical Name:
METHYLTRIPHENOXYPHOSPHONIUM IODIDE
Synonyms
methyl(triphenoxy)phosphanium;Triphenylphosphine Methiodide;Methyltriphenoxyphosphorus(1+);TRIPHENYL PHOSPHITE METHIODIDE;TRIPHENYL PHOSPHITE METHOIODIDE;METHYLTRIPHENOXYPHOSPHONIUM IODIDE;Methyltriphenoxyphosphorus(1+) Iodide;Methyltriphenoxyphosphonium iodide,95%;Methyltriphenoxyphosphonium iodide 96%;Phosphorus(1+), methyltriphenoxy-, iodide (1:1), (T-4)-
CBNumber:
CB8686334
Molecular Formula:
C19H18IO3P
Molecular Weight:
452.22
MDL Number:
MFCD00011911
MOL File:
17579-99-6.mol
MSDS File:
SDS
Last updated:2023-05-04 15:12:38

METHYLTRIPHENOXYPHOSPHONIUM IODIDE Properties

Melting point 142-146 °C(lit.)
storage temp. 0-6°C
solubility Chloroform (Slightly), DMSO (Slightly, Sonicated), Methanol (Sparingly)
form solid
color Dark Orange to Very Dark Brown
BRN 3580189
Stability Hygroscopic, Moisture Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3
3-8-10
HS Code  29310099

METHYLTRIPHENOXYPHOSPHONIUM IODIDE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 226432 Methyltriphenoxyphosphonium iodide 96% 17579-99-6 10g $54 2024-03-01 Buy
Sigma-Aldrich 226432 Methyltriphenoxyphosphonium iodide 96% 17579-99-6 50g $257 2024-03-01 Buy
Usbiological 282861 Methyltriphenoxyphosphonium iodide 17579-99-6 2g $396 2021-12-16 Buy
TRC M330990 Methyltriphenoxyphosphonium iodide 17579-99-6 100g $970 2021-12-16 Buy
American Custom Chemicals Corporation ING0004505 METHYLTRIPHENOXYPHOSPHONIUM IODIDE 95.00% 17579-99-6 10G $1187.53 2021-12-16 Buy
Product number Packaging Price Buy
226432 10g $54 Buy
226432 50g $257 Buy
282861 2g $396 Buy
M330990 100g $970 Buy
ING0004505 10G $1187.53 Buy

METHYLTRIPHENOXYPHOSPHONIUM IODIDE Chemical Properties,Uses,Production

Chemical Properties

Yellow-Brownish Solid

Uses

Used in the transformation of the 5′-hydroxyl group in nucleosides to the 5′-deoxy-5′-iodo group.

Uses

Methyltriphenoxyphosphonium Iodide is used in the transformation of the 5?hydroxyl group in nucleosides to the 5?deoxy-5?iodo group

Uses

Methyltriphenoxyphosphonium Iodide is used in the transformation of the 5’-hydroxyl group in nucleosides to the 5’-deoxy-5’-iodo group.

Purification Methods

Gently heat the impure iodide with good grade Me2CO. The saturated solution obtained is decanted rapidly from undissolved salt and treated with an equal volume of dry Et2O. The iodide separates as flat needles which are collected by centrifugation, washed several times with dry Et2O, and dried in a vacuum over P2O5. For this recrystallisation it is essential to minimise the time of contact with Me2CO and to work rapidly and with rigorous exclusion of moisture. If the crude material is to be used, it should be stored under dry Et2O, and dried and weighed in vacuo immediately before use. [Landauer & Rydon J Chem Soc 224 1953, Hudson et al. J Chem Soc Perkin Trans 1 982 1974, Beilstein 6 IV 704.]

101-02-0
74-88-4
17579-99-6
Synthesis of METHYLTRIPHENOXYPHOSPHONIUM IODIDE from Triphenyl phosphite and Iodomethane

METHYLTRIPHENOXYPHOSPHONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 33)Suppliers
Supplier Tel Email Country ProdList Advantage
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696; info@hanhongsci.com China 42982 64
Chemsky(shanghai)International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32344 50
Thermo Fisher Scientific 800-810-5118 cnchemical@thermofisher.com China 17779 75
Shanghai T&W Pharmaceutical Co., Ltd. +86 21 61551611 China 9901 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Aikon International Limited 025-58859352 18068836627 sales01@aikonchem.com China 15085 58

17579-99-6(METHYLTRIPHENOXYPHOSPHONIUM IODIDE)Related Search:

Methyltriphenoxyphosphonium iodide 96% TRIPHENYL PHOSPHITE METHIODIDE TRIPHENYL PHOSPHITE METHOIODIDE METHYLTRIPHENOXYPHOSPHONIUM IODIDE Methyltriphenoxyphosphorus(1+) Iodide Triphenylphosphine Methiodide Methyltriphenoxyphosphonium iodide,95% Methyltriphenoxyphosphorus(1+) Phosphorus(1+), methyltriphenoxy-, iodide (1:1), (T-4)- methyl(triphenoxy)phosphanium 17579-99-6 C19H18IO3P C19H18O3PI CH3PIOC6H53 Synthetic Reagents C-X Bond Formation (Halogen) Iodination Phosphorylating and Phosphitylating Agents