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ChemicalBook >> CAS DataBase List >>1,2,4,5-TETRACYANOBENZENE

1,2,4,5-TETRACYANOBENZENE

1,2,4,5-TETRACYANOBENZENE Structure
1,2,4,5-TETRACYANOBENZENE structure
CAS No.
712-74-3
Chemical Name:
1,2,4,5-TETRACYANOBENZENE
Synonyms
TCNB;BENZENE-1,2,4,5-TETRACARBONITRILE;Tetracyanobenzene;pyromelliticnitrile;1,2,4,5-BENZENETETRACARBONITRILE;PYROMELLITONITRILE;Pyromellitotetrani;s-Tetracyanobenzene;TIMTEC-BB SBB008167;Pyromellitic nitrile
CBNumber:
CB8686763
Molecular Formula:
C10H2N4
Molecular Weight:
178.15
MDL Number:
MFCD00043481
MOL File:
712-74-3.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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1,2,4,5-TETRACYANOBENZENE Properties

Melting point 265-268 °C(lit.)
Boiling point 300.36°C (rough estimate)
Density 1.35 g/cm3
refractive index 1.5200 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility acetone: soluble25mg/mL, clear, colorless to yellow
form powder to crystal
color White to Almost white
Water Solubility Soluble in water.
BRN 1875027
Stability Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 712-74-3(CAS DataBase Reference)
EWG's Food Scores 1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H300-H311+H331
Precautionary statements  P261-P264-P280-P301+P310-P302+P352+P312-P304+P340+P311
Hazard Codes  T
Risk Statements  23/24/25
Safety Statements  36/37/39-45
RIDADR  UN 3439 6.1/PG 2
WGK Germany  3
RTECS  DB9100000
TSCA  N
HazardClass  6.1(a)
PackingGroup  II
HS Code  29269090
NFPA 704
1
4 0

1,2,4,5-TETRACYANOBENZENE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 391980 1,2,4,5-Tetracyanobenzene 97% 712-74-3 1g $21.84 2024-03-01 Buy
Sigma-Aldrich 391980 1,2,4,5-Tetracyanobenzene 97% 712-74-3 5g $173 2024-03-01 Buy
TCI Chemical T0988 1,2,4,5-Tetracyanobenzene >98.0%(HPLC)(N) 712-74-3 1g $75 2024-03-01 Buy
TCI Chemical T0988 1,2,4,5-Tetracyanobenzene >98.0%(HPLC)(N) 712-74-3 5g $301 2024-03-01 Buy
TRC B190088 Benzene-1,2,4,5-tetracarbonitrile 712-74-3 10mg $45 2021-12-16 Buy
Product number Packaging Price Buy
391980 1g $21.84 Buy
391980 5g $173 Buy
T0988 1g $75 Buy
T0988 5g $301 Buy
B190088 10mg $45 Buy

1,2,4,5-TETRACYANOBENZENE Chemical Properties,Uses,Production

Chemical Properties

solid

Uses

1,2,4,5-Tetracyanobenzene (TCB, TCNB) is suitable reagent used in the synthesis of o-3,4-dimethyltetrathiafulvalene (o-Me2TTF)-1,2,4,5-tetracyanobenzene (TCNB) 1:1 complex and radiative exciplexes of TCB in non-polar solvents.

1,2,4,5-Tetracyanobenzene (Pyromellitic acid tetranitrile, PMTN, TCB, TCNB, 1,2,4,5-benzenetetracarbonitrile ) may be used in the following studies:

  • Solid-state diffusion of TCNB into 9-methylanthracene molecular crystal nanorods forming cocrystal nanorods.
  • Synthesis of copper polyphthalocyanine (CuPPC) thin films, an elementoorganic semiconductor.
  • Preparation of charge transfer (CT) nanocrystallites which may have a potential use in nanofluidics to observe the rotational motion of nanoobjects.
  • Hydrothermal synthesis of Co2(terpy)2(btec)?H2O (terpy = 2,2′:6′,2"-terpyridine, btec = 1,2,4,5-benzenetetracarboxylate).

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 3520, 1962 DOI: 10.1021/jo01057a028

General Description

1,2,4,5-Tetracyanobenzene (TCNB, TCB) is a tetra substituted benzene. The IR and raman spectra of TCNB and its 1:1 complex with durene has been recorded. The time-resolved linear dichroism spectroscopic study of hexamethylbenzene-1,2,4,5-tetracyanobenzene charge-transfer complex has been investigated. The influence of magnetic field on the charge-transfer fluorescence of 1,2,4,5-tetracyanobenzene-doped poly(N-vinylcarbazole) thin film has been studied.

Purification Methods

Crystallise the tetra-nitrile from EtOH and sublime in vacuo. [Lawton & McRitchie J Org Chem 24 26 1959, Bailey et al. Tetrahedron 19 161 1963, Beilstein 9 IV 3800.]

1,2,4,5-TETRACYANOBENZENE synthesis

89-05-4
712-74-3
Synthesis of 1,2,4,5-TETRACYANOBENZENE from Pyromellitic acid

1,2,4,5-TETRACYANOBENZENE Preparation Products And Raw materials

Raw materials

Ammonium hydroxide N,N-Dimethylformamide Acetamide Toluene Pyromellitic Dianhydride
Urea Thionyl chloride 1,2-Dichlorobenzene 4,5-dibromobenzene-1,2-dicarbonitrile PYROMELLITIC DIIMIDE
1,2,4,5-BENZENETETRACARBOXAMIDE 1,2,4,5-TETRABROMOBENZENE Pyromellitic acid ZINC CYANIDE

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Preparation Products

1,2,4,5-tetra(1H-tetrazol-5-yl)benzene

1,2,4,5-TETRACYANOBENZENE Suppliers

Global( 148)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. 		0431-80514535 13634302652 Extension@chemextension.com CHINA 967 58
career henan chemical co 		+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
CHEMSOON CO.,LTD. 		+8613761723174 sales01@chemsoon.com China 1211 58
Shanghai Daeyeon Chemicals Co., Ltd 		021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58
Career Henan Chemica Co 		+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Henan Alfa Chemical Co., Ltd 		+8618339805032 alfa4@alfachem.cn China 12755 58
Alfa Chemistry 		+1-5166625404 Info@alfa-chemistry.com United States 21317 58
Shaanxi Didu New Materials Co. Ltd 		+86-89586680 +86-13289823923 1026@dideu.com China 9309 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. 		58
career henan chemical co 		58
CHEMSOON CO.,LTD. 		58
Shanghai Daeyeon Chemicals Co., Ltd 		58
Career Henan Chemica Co 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Henan Alfa Chemical Co., Ltd 		58
Alfa Chemistry 		58
Shaanxi Didu New Materials Co. Ltd 		58

View Lastest Price from 1,2,4,5-TETRACYANOBENZENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,2,4,5-Tetracyanobenzene 97% pictures 2021-07-02 1,2,4,5-Tetracyanobenzene 97%
712-74-3
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
1,2,4,5-TETRACYANOBENZENE pictures 2020-01-13 1,2,4,5-TETRACYANOBENZENE
712-74-3
 US $6.68 / KG 1KG 97%-99% 1kg-1000kg Career Henan Chemical Co

1,2,4,5-TETRACYANOBENZENE Spectrum

1,2,4,5-TETRACYANOBENZENE(712-74-3)MS1,2,4,5-TETRACYANOBENZENE(712-74-3)IR1,2,4,5-TETRACYANOBENZENE(712-74-3)Raman1,2,4,5-TETRACYANOBENZENE(712-74-3)FT-IR

712-74-3(1,2,4,5-TETRACYANOBENZENE)Related Search:

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1,2,4,5-Benzenetetranitrile 1,2,4,5-Benzentetrakarbonitril Benzene, 1,2,4,5-tetracyano- Pyromellitic nitrile Pyromellitic tetranitrile pyromellitictetranitrile Pyromellitotetranitrile s-Tetracyanobenzene sym-Tetracyanobenzene PYROMELLITONITRILE PYROMELLITIC ACID TETRANITRILE TIMTEC-BB SBB008167 1,2,4,5-TETRACYANOBENZENE 1,2,4,5-Benzenetetracarbonitrile, Pyromellitic acid tetranitrile 1,2,4,5-Benzenetetracarbonitrile,99% 1,2,4,5-Tetracyanobenzene 97% 1,2,4,5-Tetracyanobenzene, 97% solid Pyromellitotetrani pyromelliticnitrile Tetracyanobenzene TCNB BENZENE-1,2,4,5-TETRACARBONITRILE 1,2,4,5-BENZENETETRACARBONITRILE 712-74-3 C6H2CN4 C10H2N4 Organic Building Blocks Nitrogen Compounds Cyanides/Nitriles C10 to C27 Building Blocks Phthalonitriles & Naphthalonitriles Phthalonitriles (Building Blocks for Phthalocyanines) Building Blocks C10 to C27 Chemical Synthesis Cyanides/Nitriles Nitrogen Compounds Organic Building Blocks Aromatic Nitriles Functional Materials Phthalonitriles & Naphthalonitriles Phthalonitriles (Building Blocks for Phthalocyanines)