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3-Nitroaniline

3-Nitroaniline
3-Nitroaniline structure
CAS No.
99-09-2
Chemical Name:
3-Nitroaniline
Synonyms
ci37030;c.i.37030;azobasemna;C.I. 37030;Nitranilin;3-Nitroani;Azobase MNA;devoloranger;3-Nitroanilin;m-Xitroanilin
CBNumber:
CB8715335
Molecular Formula:
C6H6N2O2
Formula Weight:
138.12
MOL File:
99-09-2.mol

3-Nitroaniline Properties

Melting point:
111-114 °C(lit.)
Boiling point:
306 °C
Density 
0,901 g/cm3
vapor pressure 
1 mm Hg ( 119 °C)
refractive index 
1.6396 (estimate)
Flash point:
196 °C
storage temp. 
Store below +30°C.
solubility 
1.25g/l
form 
Crystals, Crystalline Powder and/or Chunks
Colour Index 
37030
pka
2.466(at 25℃)
Specific Gravity
0.901
color 
Yellow to ochre-yellow to orange
Water Solubility 
1.25 g/L
Merck 
14,6581
BRN 
636962
CAS DataBase Reference
99-09-2(CAS DataBase Reference)
NIST Chemistry Reference
m-Nitroaniline(99-09-2)
EPA Substance Registry System
Benzenamine, 3-nitro-(99-09-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T
Risk Statements  23/24/25-33-52/53
Safety Statements  28-36/37-45-61-28A
RIDADR  UN 1661 6.1/PG 2
WGK Germany  2
RTECS  BY6825000
8
Autoignition Temperature 521℃
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214210
Hazardous Substances Data 99-09-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P405 Store locked up.

3-Nitroaniline price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45989 3-Nitroaniline analytical standard 99-09-2 250mg $30.1 2018-11-13 Buy
Sigma-Aldrich N9829 3-Nitroaniline 98% 99-09-2 5g $30.5 2018-11-13 Buy
TCI Chemical N0117 3-Nitroaniline >98.0%(GC) 99-09-2 25g $30 2018-11-22 Buy
TCI Chemical N0117 3-Nitroaniline >98.0%(GC) 99-09-2 500g $135 2018-11-22 Buy
Alfa Aesar A10629 3-Nitroaniline, 98% 99-09-2 500g $83.2 2018-11-13 Buy

3-Nitroaniline Chemical Properties,Uses,Production

Chemical Properties

ochre-yellow to orange crystalline powder

Uses

Dyestuff intermediate.

General Description

Yellow needles or yellow powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Thermal stability of 3-Nitroaniline is reduced by various impurities. 3-Nitroaniline may be sensitive to prolonged exposure to light. 3-Nitroaniline may react explosively with ethylene oxide at 266° F. 3-Nitroaniline is incompatible with acids (nitric, sulfuric), acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . Unstable when heated.

Hazard

Moderate fire risk. Toxic when absorbed by skin.

Fire Hazard

Flash point data for 3-Nitroaniline are not available; however, 3-Nitroaniline is probably combustible.

Purification Methods

Purify it as for o-nitroaniline. Warning: it is absorbed through the skin. [Beilstein 12 IV 1589.]

3-Nitroaniline Preparation Products And Raw materials

Raw materials

Preparation Products


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