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Methyl cyanoformate

CAS No.
17640-15-2
Chemical Name:
Methyl cyanoformate
Synonyms
Methyl carbonocyanidate;cyklona;Cyklon A;CH3OC(O)CN;METHYL CYANOFORMATE;Methylcyanomethanoate;cyanoformatemethylester;Cyanoformic acid methyl;Methyl cyanoforMate 99%;Methyl cyanoformate ,98%
CBNumber:
CB8748128
Molecular Formula:
C3H3NO2
Molecular Weight:
85.06
MDL Number:
MFCD00013420
MOL File:
17640-15-2.mol
MSDS File:
SDS
Last updated:2022-12-21 16:56:50

Methyl cyanoformate Properties

Melting point 185-186 °C
Boiling point 100-101 °C (lit.)
Density 1.072 g/mL at 25 °C (lit.)
refractive index n20/D 1.374(lit.)
Flash point 79 °F
BRN 1742994
FDA UNII 7S9M7F9JLT
EPA Substance Registry System Carbonocyanidic acid, methyl ester (17640-15-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06
Signal word  Danger
Hazard statements  H226-H300+H310+H330-H315-H319
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T+
Risk Statements  10-26/27/28-36/38-36/37/38
Safety Statements  26-28-36/37-45
RIDADR  UN 3275 6.1/PG 2
WGK Germany  3
RTECS  LQ7525000
10-19-21
HazardClass  3.2
PackingGroup  III

Methyl cyanoformate price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 319813 Methyl cyanoformate 99% 17640-15-2 5g $105 2024-03-01 Buy
Sigma-Aldrich 319813 Methyl cyanoformate 99% 17640-15-2 25g $429 2024-03-01 Buy
Usbiological 455885 Methyl Cyanoformate 17640-15-2 250mg $355 2021-12-16 Buy
TRC M295250 Methyl cyanoformate 17640-15-2 250mg $85 2021-12-16 Buy
American Custom Chemicals Corporation CHM0030773 METHYL CYANOFORMATE 95.00% 17640-15-2 10G $1059.45 2021-12-16 Buy
Product number Packaging Price Buy
319813 5g $105 Buy
319813 25g $429 Buy
455885 250mg $355 Buy
M295250 250mg $85 Buy
CHM0030773 10G $1059.45 Buy

Methyl cyanoformate Chemical Properties,Uses,Production

Description

Methyl cyanoformate is the organic compound with the formula CH3OC(O)CN. It is used as a reagent in organic synthesis as a source of the methoxy carbonyl group , in which context it is also known as Mander's reagent. It was also the active ingredient in the pesticide product Zyklon A.

Chemical Properties

Colorless liquid; ethereal odor. Decomposedby alkalies and water. Soluble in alcohol, benzene,ether.

Uses

Organic synthesis.

Uses

Selective acylating reagent.

Purification Methods

Purify the ester by fractionation through a 45cm glass helices packed column or a 30cm spinning band column. [Sheppard J Org Chem 27 3756 1962.] It has been distilled through a short Vigreux column (p 11), and further purified by recrystallisation from Et2O at -40o as white crystals which melt at room temperature. NMR:  4.0 ( C3), and IR: 2250 (CN) and 1750 (CO) cm-1 . [Childes & Weber JOrg Chem 41 3486 1976, Beilstein 2 III 1587.]

280-57-9
7677-24-9
79-22-1
17640-15-2
Synthesis of Methyl cyanoformate from Triethylenediamine and Trimethylsilyl cyanide and Methyl chloroformate
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Carbonocyanidic acid, methyl ester carbonocyanidicacid,methylester CH3OC(O)CN Cyanoformate methyl ester cyanoformatemethylester Cyanoformicacid,methylester cyano-formicacimethylester Cyklon A cyklona Methylcyanomethanoate Methylester kyseliny kyanmravenci methylesterkyselinykyanmravenci oxalicacidmethylester-nitrile METHYL CYANOFORMATE 2-Oxo-2-methoxyacetonitrile Carbonocyanidic acid methyl Cyanoformic acid methyl Methyl cyanoformate ,98% Methyl cyanoforMate 99% Methyl carbonocyanidate 17640-15-2 NCCO2CH3 Organic Building Blocks Esters Building Blocks C2 to C5 Carbonyl Compounds C2 to C5 Carbonyl Compounds Esters