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1,3,5-Trichlorobenzene

1,3,5-Trichlorobenzene Structure
1,3,5-Trichlorobenzene structure
CAS No.
108-70-3
Chemical Name:
1,3,5-Trichlorobenzene
Synonyms
TCB;Trichlorobenzene;1,3,5-TCB;ai3-22031;1.3.5-Tric;1,3,5-TrichL;s-Trichlorobenzene;1,3,5-Trichlorbenzol;SYM-TRICHLOROBENZENE;1,3,5-Trichlorobenze
CBNumber:
CB8852759
Molecular Formula:
C6H3Cl3
Molecular Weight:
181.45
MDL Number:
MFCD00000585
MOL File:
108-70-3.mol
Last updated:2023-12-26 17:07:23
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1,3,5-Trichlorobenzene Properties

Melting point 63 °C
Boiling point 208 °C(lit.)
Density 1.4528 (estimate)
vapor pressure 0.58 at 25 °C (quoted, Mackay et al., 1982)
refractive index 1.5693 (estimate)
Flash point 260 °F
storage temp. 0-6°C
solubility Soluble in benzene, ether, ligroin (Weast, 1986), glacial acetic acid, carbon disulfide, and petroleum ether (Windholz et al., 1983)
form powder or crystals
color Off-White
Water Solubility Insoluble in water.
Merck 14,9632
BRN 1635233
Henry's Law Constant 1.83, 2.04, 2.64, 4.49, and 5.24 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (EPICS-SPME, Dewulf et al., 1999)
Stability Stable. Incompatible with acids, strong oxidizing agents.
LogP 4.190
CAS DataBase Reference 108-70-3(CAS DataBase Reference)
FDA UNII 2HS4M0BX3C
NIST Chemistry Reference Benzene, 1,3,5-trichloro-(108-70-3)
EPA Substance Registry System 1,3,5-Trichlorobenzene (108-70-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335-H412
Precautionary statements  P261-P273-P280-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-38-22-52/53
Safety Statements  26-36-36/37-61
RIDADR  3077
WGK Germany  3
RTECS  DC2100100
Hazard Note  Harmful/Irritant
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29039990
Toxicity Drinking water standard: No MCLGs or MCLs have been proposed, however, a DWEL of 200 μg/L was recommended (U.S. EPA, 2000).
NFPA 704
1
2 0

1,3,5-Trichlorobenzene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T54607 1,3,5-Trichlorobenzene 99% 108-70-3 100g $80.1 2024-03-01 Buy
Sigma-Aldrich 03824 1,3,5-Trichlorobenzene certified reference material, TraceCERT 108-70-3 100mg $119 2024-03-01 Buy
Alfa Aesar L02132 1,3,5-Trichlorobenzene, 98% 108-70-3 50g $42.1 2023-06-20 Buy
Usbiological 411208 1,3,5-Trichlorobenzene 108-70-3 250mg $403 2021-12-16 Buy
TRC T773790 1,3,5-Trichlorobenzene 108-70-3 1g $405 2021-12-16 Buy
Product number Packaging Price Buy
T54607 100g $80.1 Buy
03824 100mg $119 Buy
L02132 50g $42.1 Buy
411208 250mg $403 Buy
T773790 1g $405 Buy

1,3,5-Trichlorobenzene Chemical Properties,Uses,Production

Description

Trichlorobenzenes (TCBs) are synthetic chemicals that occur in three different isomeric forms. The three chlorinated cyclic aromatic isomers are 1,2,3-trichlorobenzene (1,2,3-TCB), 1,2,4-trichlorobenzene (1,2,4-TCB), and 1,3,5-trichlorobenzene (1,3,5-TCB). 1,2,4-TCB is one of the 188 chemicals designated as a hazardous air pollutant under the Clean Air Act.

Chemical Properties

white to beige crystalline powder

Uses

1,3,5-Trichlorobenzene is used for someof these applications plus as a termite preparation and insecticide. These compounds are found as unintended by-products of the manufacture of the mono- and dichlorobenzenes.

Uses

1,3,5-Trichlorobenzene is an isomer of 1,2,4-Trichlorobenzene (T774220) which is a solvent in various organic chemical reactions.

Uses

Trichlorobenzenes are primarily used as solvents in chemical manufacturing industries. 1,2,4-Trichlorobenzene is economically the most important isomer. 1,2,4-Trichlorobenzene is used as a solvent in chemical reactions to dissolve oils, waxes, and resins. Furthermore, it is also used as a dye carrier. 1,2,3- Trichlorobenzene is used as an intermediate for pesticides production, pigments, and dyes. 1,3,5-Trichlorobenzene is not marketed commercially and has very limited use as a chemical intermediate. Besides, trichlorobenzenes can also be used as degreasing agents, as septic tanks and drain cleaners, and as an ingredient in wood preservatives and abrasive formulations. Other minor uses include metal work, anticorrosive paint, and corrosion inhibitor in sprays. In the past, mixed isomers of trichlorobenzenes were used to control termites; however, their use has been discontinued.

Definition

ChEBI: 1,3,5-trichlorobenzene is a trichlorobenzene carrying chloro substituents at positions 1, 3 and 5.

General Description

White to off-white crystals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Can react vigorously with oxidizing materials. .

Fire Hazard

1,3,5-Trichlorobenzene is combustible.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic vapors of Cl-.

Environmental Fate

Biological. Under aerobic conditions, soil microbes degraded 1,3,5-trichlorobenzene to 1,3- and 1,4-dichlorobenzene and carbon dioxide (Kobayashi and Rittman, 1982). A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,3,5-trichlorobenzene to 2,4,6-trichlorophenol (Ballschiter and Scholz, 1980).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,3,5- trichlorobenzene underwent reductive dechlorination yielding 1,3-dichlorobenzene. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 9.5 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. The sunlight irradiation of 1,3,5-trichlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 56 d yielded 160 ppm pentachlorobiphenyl (Uyeta et al., 1976). A photooxidation half-life of 6.17 months was reported for the vapor-phase reaction of 1,3,5-trichlorobenzene with OH radicals (Atkinson, 1985).

Purification Methods

Recrystallise it from dry *benzene or toluene. [Beilstein 5 IV 666.]

Toxicity evaluation

The liver is themain target of trichlorobenzenes irrespective of the route of exposure. The mechanisms of liver toxicity induced by these chemicals have not been illustrated. It might involve intermediate arene oxides formed during initial transformation to trichlorophenols. In addition, exposure to 1,2,4-TCB induced porphyria in rats by inducing daminolevulinic acid (ALA) synthetase, a rate-limiting enzyme in the biosynthesis of heme, and also heme oxygenase, a ratelimiting enzyme in the degradation of heme synthetase, and therefore increasing heme production.

1,3,5-Trichlorobenzene synthesis

19752-55-7
108-70-3
Synthesis of 1,3,5-Trichlorobenzene from 1-Bromo-3,5-dichlorobenzene

1,3,5-Trichlorobenzene Preparation Products And Raw materials

Raw materials

2,4,6-Trichloroaniline 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene ethyl 2-methoxyacrylate 1,3-Dibromo-5-chlorobenzene
2,2',4,4',6,6'-HEXACHLOROBIPHENYL 2,4,6-Trichloroiodobenzene PENTACHLOROBENZENE 1,2,3,5-Tetrachlorobenzene LINDANE
1-Bromo-3,5-dichlorobenzene

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Preparation Products

2,4,6-Trichlorobenzoic acid 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 3,5-Dichloroaniline 3',5'-DICHLORO-2,2,2-TRIFLUOROACETOPHENONE
3,5-Dichlorophenol

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1,3,5-Trichlorobenzene Suppliers

Global( 297)Suppliers
Supplier Tel Email Country ProdList Advantage
Yancheng Green Chemicals Co.,Ltd
+undefined-86-25-86655873 info@royal-chem.com China 114 58
Ningxia Jinhua Chemical Co.,Ltd
025-52279164 info@nxjhchem.com China 79 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7378 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9352 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Xiamen AmoyChem Co., Ltd 		+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Supplier Advantage
Yancheng Green Chemicals Co.,Ltd
58
Ningxia Jinhua Chemical Co.,Ltd
58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Xiamen AmoyChem Co., Ltd 		58

View Lastest Price from 1,3,5-Trichlorobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,3,5-Trichlorobenzene pictures 2024-04-10 1,3,5-Trichlorobenzene
108-70-3
 US $0.00 / Kg/Drum 25Kg/Drum 99 1mt Changde Changlian Chemical Co., Ltd.
1,3,5-Trichlorobenzene pictures 2024-04-10 1,3,5-Trichlorobenzene
108-70-3
 US $0.00 / KG 25KG 99 1mt Yancheng Green Chemicals Co.,Ltd
1,3,5-Trichlorobenzene pictures 2024-04-10 1,3,5-Trichlorobenzene
108-70-3
 US $0.00 / Kg/Drum 25Kg/Drum 99 1mt Ningxia Jinhua Chemical Co.,Ltd

1,3,5-Trichlorobenzene Spectrum

1,3,5-Trichlorobenzene(108-70-3)MS1,3,5-Trichlorobenzene(108-70-3)1HNMR1,3,5-Trichlorobenzene(108-70-3)13CNMR1,3,5-Trichlorobenzene(108-70-3)IR11,3,5-Trichlorobenzene(108-70-3)IR21,3,5-Trichlorobenzene(108-70-3)IR31,3,5-Trichlorobenzene(108-70-3)Raman

108-70-3(1,3,5-Trichlorobenzene)Related Search:

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IMP. A (EP): CHLORPHENAMINE (USP: CHLORPHENIRAMINE) p-Dichlorobenzene 1-Hydroxy-2,4,5-trichlorobenzene Pentachlorophenol sodium salt hydrate 2,4,6-Trichlorophenol
1-Methoxy-2,4,6-trichlorobenzene HEXACHLOROBENZENE 1-Amino-2，4，6-trichlorobenzene 1,3,5-Trichloro-2,4,6-trifluorobenzene 2,3,4,6-TETRACHLOROPHENOL SODIUM SALT
2,4,5,6-TETRACHLORO-M-XYLENE 1,2,3,5-Tetrachlorobenzene TERT-BUTYL PENTACHLOROPHENYL CARBONATE

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Benzene,1,3,5-trichloro- I,3,5-TrichlorbenzolVW,16 s-Trichlorobenzene trichloro-1,3,5benzene 1,3,5-TRICHLOROBENZENE PESTANAL, 250 MG 1 3 5-TRICHLOROBENZENE TECH. 90% 1,3,5-TRICHLOROBENZENE, 1000MG, NEAT 1,3,5-Trichlorbenzol 1,3,5-TRICHLOROBENZENE pure 1,3,5-Trichlorobenzene,99% 1,3,5-Trichlorobenzene 1.3.5-Trichlorobenzene 1g [108-70-3] 1,3,5-trichloro-benzen ai3-22031 SYM-TRICHLOROBENZENE 1,3,5-Trichlorobenze 1,3,5-Trichlorobenzene in Isooctane 1,3,5-Trichlorobenzene, 99.0%(GC) 1.3.5-Tric 1,3,5-TrichL 1,3,5-Trichlorobenzene 10 μg/mL in Cyclohexane 1,3,5-trichlorobenzeneSolution,100mg/L,1ml 1,3,5-TrichlorobenzeneSolution,10,000mg/L,5ml 1,3,5-Trichlorobenzene > 1,3,5-trichlorobenzeneSolution,1,000mg/L,1ml 1,3,5-TrichlorobenzeneSolution,10,000mg/L,1ml 1,3,5-Trichlorobenzene ISO 9001：2015 REACH 108-70-3 C6H3Cl3 1,3,5-Trichlorobenzene 1,3,5-Trichlorobenzene (1,3,5-TCB) pure, 99% Trichlorobenzene TCB 1,3,5-TCB Anagrelide Impurity 9 108-70-3 C6Cl3H3 C6H3CI3 108703 Building Blocks Aryl C6 Organic Building Blocks Halogenated Hydrocarbons Analytical Standards AromaticsChemical Class Chemical Class ChloroVolatiles/ Semivolatiles Halogenated TP - TZ T-ZAlphabetic Aryl C6 Halogenated Hydrocarbons Pesticides&Metabolites Q-ZAlphabetic Organics Benzene derivates Alpha Sort