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2-Methoxyethyl acetate

CAS No.
110-49-6
Chemical Name:
2-Methoxyethyl acetate
Synonyms
ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE;egmea;2-Methoxyacetate;METHYL GLYCOL ACETATE;MeCsAc;EM ACETATE;2-methoxyethyl;3-OXABUTYL ACETATE;CH3C(O)O(CH2)2OCH3;Methylglykolacetat
CBNumber:
CB8852810
Molecular Formula:
C5H10O3
Molecular Weight:
118.13
MDL Number:
MFCD00008719
MOL File:
110-49-6.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:28

2-Methoxyethyl acetate Properties

Melting point −65 °C(lit.)
Boiling point 145 °C(lit.)
Density 1.009 g/mL at 25 °C(lit.)
vapor pressure 4.7 hPa (20 °C)
refractive index n20/D 1.402(lit.)
Flash point 111 °F
storage temp. Store below +30°C.
solubility Soluble in alcohol and ether (Weast, 1986).
form Solid
color White
explosive limit 1.7-8.8%(V)
Water Solubility Miscible (Lyman et al., 1982)
λmax λ: 254 nm Amax: 1.00
λ: 275 nm Amax: 0.15
λ: 300 nm Amax: 0.05
λ: 350-400 nm Amax: 0.01
Merck 14,6039
BRN 1700761
Henry's Law Constant (x 10-6 atm?m3/mol): 3.28 at 30.00 °C (headspace-GC, Hovorka et al., 2002)
Exposure limits NIOSH REL: TWA 0.1 ppm (0.5 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 25 ppm (120 mg/m3); ACGIH TLV: TWA 5 ppm (24 mg/m3).
CAS DataBase Reference 110-49-6(CAS DataBase Reference)
EWG's Food Scores 4-7
FDA UNII I62493E04O
Proposition 65 List Ethylene Glycol Monomethyl Ether Acetate
EPA Substance Registry System Ethylene glycol monomethyl ether acetate (110-49-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H302+H312+H332-H360FD
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P308+P313
Hazard Codes  T
Risk Statements  60-61-20/21/22
Safety Statements  53-45
RIDADR  UN 1189 3/PG 3
WGK Germany  1
RTECS  KL5950000
Autoignition Temperature 380 °C DIN 51794
HS Code  2915 39 00
HazardClass  3
PackingGroup  III
Toxicity LD50 orally in rats: 3.4 g/kg (Smyth)
IDLA 200 ppm
NFPA 704
2
2 0

2-Methoxyethyl acetate price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.06061 2-Methoxyethyl acetate for synthesis 110-49-6 1L $79.9 2024-03-01 Buy
Sigma-Aldrich 8.06061 2-Methoxyethyl acetate for synthesis 110-49-6 2.5L $214 2024-03-01 Buy
Sigma-Aldrich 109886 2-Methoxyethyl acetate reagent grade, 98% 110-49-6 1l $141 2024-03-01 Buy
Sigma-Aldrich 109886 2-Methoxyethyl acetate reagent grade, 98% 110-49-6 4l $413 2024-03-01 Buy
Sigma-Aldrich 8.06061 2-Methoxyethyl acetate for synthesis 110-49-6 100mL $37.1 2023-06-20 Buy
Product number Packaging Price Buy
8.06061 1L $79.9 Buy
8.06061 2.5L $214 Buy
109886 1l $141 Buy
109886 4l $413 Buy
8.06061 100mL $37.1 Buy

2-Methoxyethyl acetate Chemical Properties,Uses,Production

Description

Methoxyethyl acetate is a colorless liquid with a mild, ether-like odor. Odor threshold= 0.33 ppm. Molecular weight= 118.15; Specific gravity (H2O:1)= 1.01;Boiling point=145℃; Freezing/Melting point=65℃; Vapor pressure= 2 mmHg at 20℃; Flash point=48.9℃ (cc); Autoignition temperature=380℃. Explosive limits: LEL= 1.7%; UEL= 8.2%. Hazard Identification (based on NFPA-704 M Rating System): Health 1, Flammability 2, Reactivity 0. Soluble in water.

Chemical Properties

Methoxyethyl acetate is a colorless liquid. Mild, ethereal odor.

Chemical Properties

CLEAR LIQUID

Physical properties

Colorless liquid with a mild, ether-like odor. Experimentally determined detection and recognition odor threshold concentrations were 1.6 mg/m3 (330 ppbv) and 3.1 mg/m3 (640 ppbv), respectively (Hellman and Small, 1974).

Uses

Lacquer industry; textile printing; manufacture of photographic film, coatings, and adhesives

Uses

Industrial solvent.

General Description

A clear colorless liquid with a pleasant odor. Flash point of 135°F. Denser than water and soluble in water. Vapors are heavier than air.

Air & Water Reactions

Flammable. Water soluble. Reacts slowly in water to form acetic acid and methyl alcohol; the reaction is not violent.

Reactivity Profile

Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion, inhalation, and skin absorption. Moderate fire risk. Toxic by skin absorption.

Health Hazard

May cause irritation if splashed into eyes. Can be absorbed through the skin. Swallowing a large single dose or absorbing larged amount through skin could result in death. It is unlikely that air levels of the compound would be dangerous unless it is heated.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire.

Safety Profile

Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. hfddly toxic by inhalation and skin contact. Human systemic effects by inhalation: eye lachrymation, cough, and pulmonary changes. Experimental reproductive effects. Mutation data reported. An inhalation irritant in humans. An eye irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. A moderate explosion hazard. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

Potential Exposure

Methoxyethyl acetate is used as a solvent for resins, oils, greases and inks. It is also an ingredient of lacquers, paints and adhesives.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 2448 h after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray.

Environmental Fate

Chemical/Physical. Hydrolyzes in water forming methyl cellosolve and acetic acid. At an influent concentration of 1,024 mg/L, treatment with GAC resulted in an effluent concentration of 886 mg/L. The adsorbability of the carbon used was 28 mg/g carbon (Guisti et al., 1974).

storage

Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. Prior to working with this chemical you should be trained on its proper handling and storage. Before entering confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. 2-Methoxyethyl acetate must be stored to avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) and strong caustics, since violent reactions occur. Sources of ignition, such as smoking and open flames are prohibited where 2-methoxyethyl acetate is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Wherever 2-methoxyethyl acetate is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

Shipping

UN1189 Ethylene glycol monomethyl ether acetate, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Shake the methoxy-ethane with anhydrous Na2CO3, filter and distil it in a vacuum. Redistillation can be then be carried out at atmospheric pressure. [Dunbar & Bolstad J Org Chem 21 1041 1956, Beilstein 2 IV 214.]

Incompatibilities

Forms explosive mixture with air. Strong oxidants, strong bases, strong acids, and nitrates. May be able to form explosive peroxides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Beware of possible presence of peroxides in which case open burning may be used

292638-84-7
623-73-4
67-56-1
110-49-6
946-39-4
946-38-3
623-91-6
141-05-9
Synthesis of 2-Methoxyethyl acetate from 1,2-Ethanediyl, 1-phenyl- (9CI) and Ethyl diazoacetate and Methanol
Global( 191)Suppliers
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View Lastest Price from 2-Methoxyethyl acetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methoxyethyl acetate pictures 2023-11-22 2-Methoxyethyl acetate
110-49-6
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
2-Methoxyethyl acetate pictures 2023-11-14 2-Methoxyethyl acetate
110-49-6
US $0.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
2-Methoxyethyl acetate pictures 2023-09-06 2-Methoxyethyl acetate
110-49-6
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
METHOXYETHANOL ACETATE 2-METHOXYETHYL ACETATE, 99+%, HPLC GRADE GLYCOL MONOMETHYL ETHER ACETATE Ethylene glycol methyl ether acetate EM ACETATE 1-Acetoxy-2-methoxyethane~Ethylene glycol monomethyl ether acetate~Methyl Cellosolve(rg acetate Acetic acid 2-methoxyethyl 2-METHOXYETHYL ACETATE REAGENT GRADE 2-methoxyethyl acetate methylglycol acetate 1-Acetoxy-2-methoxyethane, Ethylene glycol monomethyl ether acetate, Methyl Cellosolve(R) acetate 2-Methoxyethyl acetate ,99% 2-METHOXYETHYLACETATE,REAGENT ETHYLENEGLYCOLMONOMETHYLETHERMONO-ACETATE ETHYLENEGLYCOLMONOMETHYLACETATE 2-METHOXYYETHYLACETATE Ethylenglycolmonomethyletheracetat Ethylene Glycol Monomethyl Ether Acetate Acetic Acid 2-Methoxyethyl Ester Methyl Cellosolve Acetate Methyl Glycol Acetate 2-Methoxyethyl acetate,98% O-METHYL GLYCOL ACETATE ACETIC ACID 2-METHOXYETHYL ACETATE ACETIC ACID 2-METHOXYETHYL ESTER 3-OXABUTYL ACETATE 2-METHOXYETHANOL ACETATE 2-METHOXYETHYL ACETATE 1-ACETOXY-2-METHOXYETHANE (2-METHOXYETHYL) ACETATE FOR SYNTHESIS METHOXYETHYL ACETATE METHYL CELLOSOLVE ACETATE METHYL CELLOSOLVE(R) ACETATE METHYL CELLOSOLVE(TM) ACETATE Methyl Cellosolve Acetate (Carbide and Carbon Chem.) 2-Methoxyaethylacetat 2-methoxy-ethanoacetate 2-methoxyethyl 2-Methoxy-ethyl acetaat 2-Methoxyethyl ester of acetic acid 2-methoxy-ethylacetaat 2-Methoxyethyle, acetate de 2-methoxyethyle,acetatede 2-methoxyethyle,acetatede(french) 2-Methoxyethylester kyseliny octove 2-methoxyethylesterkyselinyoctove 2-methyoxyethylacetate 2-Metossietilacetato Acetate de L'ether monomethylique de L'ethylene-glycol Acetate de methyle glycol acetatede2-methoxyethyle acetatedel’ethermonomethyliquedel’ethylene-glycol acetatedel’ethermonomethyliquedel’ethylene-glycol(french) acetatedemethyleglycol acetatedemethyleglycol(french) Acetato di metil cellosolve acetatodimetilcellosolve acetoxy-2-methoxyethane acetylmethylcellosolve Aethylenglykolmethylaetheracetat beta-Methoxyethyl acetate beta-methoxyethylacetate