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Tetramethylene sulfoxide

CAS No.
1600-44-8
Chemical Name:
Tetramethylene sulfoxide
Synonyms
Thiophane oxide;thiophane1-oxide;Thiolane 1-oxide;Thiophane 1-oxide;thiophanemonoxide;1λ?-thiolan-1-one;Thiophane monoxide;Thiophene sulfoxide;Tetrametylene sulfoxide;TETRAMETHYLENE SULFOXIDE
CBNumber:
CB8853165
Molecular Formula:
C4H8OS
Molecular Weight:
104.17
MDL Number:
MFCD00005477
MOL File:
1600-44-8.mol
MSDS File:
SDS
Last updated:2023-11-28 16:31:44

Tetramethylene sulfoxide Properties

Boiling point 235-237 °C(lit.)
Density 1.158 g/mL at 25 °C(lit.)
refractive index n20/D 1.52(lit.)
Flash point >230 °F
form Liquid
color Clear colorless to yellow
Water Solubility Fully miscible in water.
BRN 105274
Dielectric constant 5.6(25℃)
CAS DataBase Reference 1600-44-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII FL7PF5FLM2
EPA Substance Registry System Thiophene, tetrahydro-, 1-oxide (1600-44-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Safety Statements  24/25
WGK Germany  3
RTECS  XN0830000
TSCA  T
HS Code  29041000
Toxicity mouse,LD50,intraperitoneal,3500mg/kg (3500mg/kg),International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine. Vol. 3, Pg. 41, 1961.
NFPA 704
1
0 0

Tetramethylene sulfoxide price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T22403 Tetrahydrothiophene 1-oxide 96% 1600-44-8 25g $108 2024-03-01 Buy
TCI Chemical T0146 Tetramethylene Sulfoxide >95.0%(GC) 1600-44-8 25g $68 2024-03-01 Buy
TCI Chemical T0146 Tetramethylene Sulfoxide >95.0%(GC) 1600-44-8 500g $597 2024-03-01 Buy
Alfa Aesar A17502 Tetrahydrothiophene 1-oxide 97% 1600-44-8 10g $36.65 2024-03-01 Buy
Alfa Aesar A17502 Tetrahydrothiophene 1-oxide 97% 1600-44-8 50g $148.65 2024-03-01 Buy
Product number Packaging Price Buy
T22403 25g $108 Buy
T0146 25g $68 Buy
T0146 500g $597 Buy
A17502 10g $36.65 Buy
A17502 50g $148.65 Buy

Tetramethylene sulfoxide Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid

Uses

In a comparative study of aromatic fluorodenitration with Potassium fluoride, in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane.

Definition

ChEBI: Tetrahydrothiophene 1-oxide is a member of tetrahydrothiophenes.

Synthesis Reference(s)

Journal of the American Chemical Society, 63, p. 2939, 1941 DOI: 10.1021/ja01856a021
The Journal of Organic Chemistry, 50, p. 1787, 1985 DOI: 10.1021/jo00210a055
Synthetic Communications, 24, p. 2393, 1994 DOI: 10.1080/00397919408010545

Purification Methods

Shake the oxide with BaO for 4 days, then distil it from CaH2 under reduced pressure. [Beilstein 17 III/IV 36, 17/1 V 38.]

Tetramethylene sulfoxide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 135)Suppliers
Supplier Tel Email Country ProdList Advantage
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View Lastest Price from Tetramethylene sulfoxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetramethylene sulfoxide pictures 2023-07-27 Tetramethylene sulfoxide
1600-44-8
US $1.50 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
TetraMethylene sulfoxide, 98+% 5GR Tetrahydrothiophene 1-oxide 96% TETRAMETHYLENE SULFOXIDE TETRAMETHYLENE SULPHOXIDE tetrahydro-thiophen1-oxide Tetrametylene sulfoxide Thiolane 1-oxide Thiophane 1-oxide Thiophane monoxide Thiophane oxide thiophane1-oxide thiophanemonoxide Thiophene sulfoxide Thiophene-1-oxide, tetrahydro- TETRAHYDROTHIOPHENE 1-OXIDE TETRAHYDROTHIOPHENE OXIDE TETRAHYDROTHIOPHENE-S-OXIDE Tetramethylene sulfoxide, 98+% Thiophene, tetrahydro-, 1-oxide Tetramethylene Sulfoxide > 1λ?-thiolan-1-one Tetramethylene Sulfoxid 1600-44-8 Thiophenes Heterocyclic Building Blocks Building Blocks