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tert-Butylamine

tert-Butylamine
tert-Butylamine structure
CAS No.
75-64-9
Chemical Name:
tert-Butylamine
Synonyms
cp11093;erbumine;T-BUTYLAMINE;tert-C4H9NH2;Ter-butyl amine;TERT-BUTYLAMINE;2-AMINOISOBUTANE;Butylamine, tert;AKOS BBS-00004218;butylamine,tertiary
CBNumber:
CB8854238
Molecular Formula:
C4H11N
Formula Weight:
73.14
MOL File:
75-64-9.mol

tert-Butylamine Properties

Melting point:
-67 °C
Boiling point:
46 °C(lit.)
Density 
0.696 g/mL at 25 °C(lit.)
vapor density 
2.5 (vs air)
vapor pressure 
5.7 psi ( 20 °C)
refractive index 
n20/D 1.377(lit.)
Flash point:
−36.4 °F
storage temp. 
Flammables area
solubility 
water: miscible1000g/L at 25°C
pka
10.68(at 25℃)
form 
Liquid
color 
Clear
PH
12 (100g/l, H2O, 20℃)
Odor
Like ammonia.
explosive limit
1.5-9.2%(V)
Water Solubility 
MISCIBLE
Sensitive 
Air Sensitive
Merck 
14,1545
BRN 
605267
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents. Highly flammable.
CAS DataBase Reference
75-64-9(CAS DataBase Reference)
NIST Chemistry Reference
2-Propanamine, 2-methyl-(75-64-9)
EPA Substance Registry System
2-Propanamine, 2-methyl-(75-64-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,C,T
Risk Statements  11-20/22-35-25-20-52/53
Safety Statements  16-26-36/37/39-45-28A-61
RIDADR  UN 3286 3/PG 2
WGK Germany  1
RTECS  EO3330000
2-10
Autoignition Temperature 716 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29211980
Hazardous Substances Data 75-64-9(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 80 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.

NFPA 704

Diamond Hazard Value Description
4
0
Health  
Flammability   4 Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Includes pyrophoric substances. Flash point below room temperature at 22.8 °C (73 °F). (e.g. acetylene, propane, hydrogen gas)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

tert-Butylamine price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 391433 tert-Butylamine ≥99.5% 75-64-9 100ml $58.2 2018-11-13 Buy
Sigma-Aldrich 391433 tert-Butylamine ≥99.5% 75-64-9 1l $353 2018-11-13 Buy
TCI Chemical B0709 tert-Butylamine >98.0%(GC)(T) 75-64-9 25mL $15 2018-11-22 Buy
TCI Chemical B0709 tert-Butylamine >98.0%(GC)(T) 75-64-9 100mL $17 2018-11-22 Buy
Alfa Aesar A11135 tert-Butylamine, 98% 75-64-9 500ml $26.4 2018-11-13 Buy

tert-Butylamine Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Chemical Properties

Butyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:

Uses

Intermediate for rubber accelerators, insecti- cides, fungicides, dyestuffs, pharmaceuticals.

Definition

ChEBI: A primary aliphatic amine that is ethylamine substituted by two methyl groups at position 1.

General Description

A clear colorless liquid with an ammonia-like odor. Flash point 70°F. Less dense (at 6.2 lb / gal) than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion.

Air & Water Reactions

Highly flammable. May be sensitive to air . Soluble in water.

Reactivity Profile

tert-Butylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides. Undergoes highly exothermic reaction with 2,2-dibromo-1,3-dimethylcyclopropanoic acid [J. Chem. Soc., 1, 1979, 2324].

Hazard

Skin irritant. Flammable, dangerous fire risk.

Health Hazard

Inhalation causes irritation of nose, mouth, and lungs. Ingestion causes irritation of mouth and stomach. Contact with liquid causes severe irritation of eyes and moderate irritation of skin.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire.

Fire Hazard

Flash Point (°F): 16 ℃; Flammable Limits in Air (%): 1.7-8.9 (at 212 °F); Fire Extinguishing Agents: Dry chemical, alcohol foam, carbon dioxide; Fire Extinguishing Agents Not To Be Used: Water may be ineffective; Special Hazards of Combustion Products: Toxic oxides of nitrogen may form; Behavior in Fire: No data; Ignition Temperature (°F): 716; Electrical Hazard: No data; Burning Rate: 7 mm/min.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: Liquid will attack some plastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Poison by ingestion. Moderately toxic to humans by inhalation. A corrosive liquid. See also n-BUTYLAMINE and AMINES. Very dangerous fire hazard when exposed to heat or flame. Very exothermic reaction with 2,2-dibromo-l,3 dimethylcyclopropanoic acid. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx.

Potential Exposure

Alert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Rinse out mouth and do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy

Shipping

UN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material

Purification Methods

Dry it with KOH or LiAlH4, and/or distil it from CaH2 or BaO. [Beilstein 4 IV 657.]

Incompatibilities

May form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.

tert-Butylamine Preparation Products And Raw materials

Raw materials

Preparation Products


tert-Butylamine Suppliers

Global( 218)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Nanjing Finetech Chemical Co., Ltd.
025-85710122 17714198479
025-85710122 sales@fine-chemtech.com CHINA 892 55
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6374 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20095 58
QUALITY CONTROL CHEMICALS INC.
(323) 306-3136
(626) 453-0409 orders@qcchemical.com United States 8409 58
Shanghai Song Yuan Chemical Technology Co., Ltd. 18521000990
86-021-33275113 1492698924@qq.com China 6606 50
Nanjing Huang Tai Pharmaceutical Technology Co. Ltd. 18551845925QQ3569572487
025-58803650 3237333966@qq.com China 1844 58
Jinan Renyuan Chemical Co., Ltd. 18396852370
1840274076@qq.com CHINA 147 58
Shanghai Chen Yu Chemical Co., Ltd. 13012824065
021-60488310 121597535@qq.com China 107 58
Shanghai Wei Nie Chemical Technology Co., Ltd. 13046668259
657990292@qq.com CHINA 50 58

tert-Butylamine Spectrum


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