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2-Bromotoluene

CAS No.
95-46-5
Chemical Name:
2-Bromotoluene
Synonyms
1-BROMO-2-METHYLBENZENE;a13-26648;2-Bromtoluol;o-bromo-toluen;2-BROMOTOLUENE;2-bromo-toluen;2-tolylbromide;O-BROMOTOLUENE;2-Tolyl bromide;O-TOLYL BROMIDE
CBNumber:
CB8854692
Molecular Formula:
C7H7Br
Molecular Weight:
171.03
MDL Number:
MFCD00000068
MOL File:
95-46-5.mol
Last updated:2023-12-25 17:47:29

2-Bromotoluene Properties

Melting point -27 °C (lit.)
Boiling point 58-60 °C/10 mmHg (lit.)
Density 1.422 g/mL at 25 °C (lit.)
refractive index n20/D 1.555(lit.)
Flash point 174 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.422
color Clear colorless to light yellow
Water Solubility <0.1 g/100 mL at 15 ºC
Merck 14,1439
BRN 1904176
Dielectric constant 4.2800000000000002
Stability Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 95-46-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII TBG2F2VA19
NIST Chemistry Reference Benzene, 1-bromo-2-methyl-(95-46-5)
EPA Substance Registry System o-Bromotoluene (95-46-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H411
Precautionary statements  P264-P270-P273-P301+P312-P391-P501
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  36/37/39-37/39-26
WGK Germany  3
RTECS  XS7965500
Hazard Note  Harmful/Irritant
TSCA  Yes
PackingGroup  III
HS Code  29036990
NFPA 704
2
2 0

2-Bromotoluene price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B82006 2-Bromotoluene 99% 95-46-5 25g $52.1 2024-03-01 Buy
Sigma-Aldrich B82006 2-Bromotoluene 99% 95-46-5 100g $90 2024-03-01 Buy
TCI Chemical B0659 2-Bromotoluene 95-46-5 25G $24 2024-03-01 Buy
TCI Chemical B0659 2-Bromotoluene 95-46-5 500G $211 2024-03-01 Buy
Alfa Aesar A12315 2-Bromotoluene, 99% 95-46-5 25g $43.65 2024-03-01 Buy
Product number Packaging Price Buy
B82006 25g $52.1 Buy
B82006 100g $90 Buy
B0659 25G $24 Buy
B0659 500G $211 Buy
A12315 25g $43.65 Buy

2-Bromotoluene Chemical Properties,Uses,Production

Chemical Properties

liquid

Uses

2-Bromotoluene was used in the synthesis of (±)-isocomene. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported. 2-Bromotoluene is used in manufacturing pharmaceuticals (especially for nonsteroidal antiinflammatory drugs; Meclofenamic acid, Mefenamic acid) and other organic compounds

General Description

Clear colorless to pale beige liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Bromotoluene reacts with strong oxidizing agents.

Fire Hazard

2-Bromotoluene is combustible.

Purification Methods

Fractionally distil it through an efficient column. It can be separated from its isomers by gas chromatography on a column of “Sil-o-cel” firebrick (30-40mesh, 80 parts) coated with 5% (20 parts) of ICI E301 con rubber with N2 carrier gas at 170o/atm and 100mL/minute and using a conductivity cell detector. [Cowley et al. J Chem Soc 1801 1959, Beilstein 5 H 304, 5 I 153, 5 II 234 5 III 704, 5 IV 825.]

333-27-7
583-53-9
95-46-5
Synthesis of 2-Bromotoluene from Methyl trifluoromethanesulfonate and 1,2-Dibromobenzene
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View Lastest Price from 2-Bromotoluene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromotoluene pictures 2023-12-26 2-Bromotoluene
95-46-5
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-Bromotoluene pictures 2020-01-08 2-Bromotoluene
95-46-5
US $0.10 / KG 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
2-Bromotoluene pictures 2019-07-12 2-Bromotoluene
95-46-5
US $1.00 / KG 1KG 99% 100kg Career Henan Chemical Co
  • 2-Bromotoluene pictures
  • 2-Bromotoluene
    95-46-5
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • 2-Bromotoluene pictures
  • 2-Bromotoluene
    95-46-5
  • US $0.10 / KG
  • 99.0%
  • Shaanxi Dideu Medichem Co. Ltd
1-Brom-2-methylbenzol 1-bromo-2-methyl-benzen 1-Methyl-2-bromobenzene a13-26648 Benzene,1-bromo-2-methyl- o-bromo-toluen o-Methylbromobenzene Toluene, o-bromo- toluene,2-bromo- Toluene,o-bromo- 2-BROMO-1-METHYLBENZENE 2-BROMOTOLUENE 2-BROMOTOLUENE / 1-BROMO-2-METHYLBENZENE 2-bromo-toluen 2-Bromtoluol 2-Methylphenylbromide 2-Tolyl bromide 2-tolylbromide 2-Methylbromobenzene o-methylphenyl bromide ORTHO BROMO TOLUENE O-TOLYL BROMIDE o-Bromomethylbenzene O-BROMOTOLUENE Adjacent broMine toluene 3-Bromotoluene,>99% 2-Bromotoluene,99% 1-Bromo-2-methylbenzene, 2-Methylbromobenzene 2-BroMotoluene, 99% 25ML 2-Bromo-1-methyL 2-Bromotoluene > 2-Bromotoluene ISO 9001:2015 REACH 2-BROMOTOLUENE For Synthesis 1-BROMO-2-METHYLBENZENE 95-46-5 CH3C6H4Br ARYL HALIDE Halogenated Hydrocarbons Organic Building Blocks C7 Aryl Building Blocks alkyl bromide Building Blocks Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Intermediates Organics Halogen toluene Miscellaneous Bromine Compounds Aryl C7 Halogenated Hydrocarbons