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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

CAS No.
887919-35-9
Chemical Name:
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Synonyms
Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;(A-taPhos)2PdCl2;PdAMPHOS;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);pall;Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…;Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)
CBNumber:
CB8972714
Molecular Formula:
C32H58Cl2N2P2Pd
Molecular Weight:
710.1
MDL Number:
MFCD09265123
MOL File:
887919-35-9.mol
Last updated:2024-01-23 10:25:42

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Properties

storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Powder
color yellow
Water Solubility Insoluble in water.
InChI InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
InChIKey AWOFSUFKCXRJMV-UHFFFAOYSA-N
SMILES P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
1
2 0

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% 887919-35-9 1g $163 2024-03-01 Buy
Sigma-Aldrich 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% 887919-35-9 5g $776 2024-03-01 Buy
Alfa Aesar 045511 Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15% 887919-35-9 1g $236.65 2024-03-01 Buy
Strem Chemicals 46-0825 Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos 887919-35-9 250mg $55 2024-03-01 Buy
Strem Chemicals 46-0825 Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos 887919-35-9 1g $162 2024-03-01 Buy
Product number Packaging Price Buy
678740 1g $163 Buy
678740 5g $776 Buy
045511 1g $236.65 Buy
46-0825 250mg $55 Buy
46-0825 1g $162 Buy

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties,Uses,Production

Reaction

  1. Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
  2. Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.
Reactions of 887919-35-9

Chemical Properties

Yellow powder

Uses

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.

Uses

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.

Synthesis

To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.

14592-56-4
932710-63-9
887919-35-9
Synthesis of Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) from Bis(acetonitrile)dichloropalladium(II) and Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials

Global( 296)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 370 58
Henan Fengda Chemical Co., Ltd
+8613613820652 info@fdachem.com China 5085 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14764 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC
323-480-4688 United States 989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Nanjing Dolon Biotechnology Co.,Ltd.
18905173768 sales@dolonchem.com CHINA 2972 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58

View Lastest Price from Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II) pictures 2024-01-23 Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II)
887919-35-9
US $0.00 / KG 1KG 98% 100KG /month Shanghai Daken Advanced Materials Co.,Ltd
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II) pictures 2024-01-22 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II)
887919-35-9
US $8.00-0.80 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) pictures 2021-07-02 BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)
887919-35-9
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Pd(aMphos)Cl2, 15% Pd, Product of UMicore Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II) Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline) Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine)palladium(11) (SP-4-1)-Palladium dichloro-bis[4-[bis(1,1-dimethylethyl)phosphino-P]-N,N-dimethylbenzenamine] BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) PdCl2(AMphos)2 Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II), Pd 15% Bis(di-tert-butyl(4-diMethyl Bis[(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine] palladiuM(II) chloride Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II), Pd 15% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}dichloropalladium(II), Bis{4-[bis(tert-butyl)phosphanyl]-N,N-dimethylaniline}dichloropalladium(II) Bis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]dichloropalladiuM, 95% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride 95+% Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos Pd(amphos)Cl2 / Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) palladium(2+) io Bis[4-[bis(1,1-diMethylethyl)phosphino-Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II) Dichlorobis[di-t-butyl(p-dimethylaminophenyl)phosphino]palladium(Ⅱ) Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) adium Bis[di-tert-butyL BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM ISO 9001:2015 REACH Bis(di-tert-butyl(4-methylaminophenyl)phosphine)dichloropalladium(II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]pa... Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride (Pd-132) TIANFU-CHEM -BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) Bis[4-[bis(1,1-diMethylethyl)phosphino-κ… BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) (A-taPhos)2PdCl2 PdCl2(Amphos)2 Pd(amphos)Cl2 Pd132 PdAMPHOS pall Pd(Amphos)2Cl2 Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II) 4-lsopropylaniline(99-88-7) bis[4- [bis(1,1-dimethylethyl)phosphino-kP]-N,N- dimethylbenzenamine]dichloro-palladium(II) Dichlorodi-tert-butyl - (4-dimethylaminophenyl) phosphopalladium (II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]palladium(II) (AMPHOS)2PDCL2 887919-35-9 C32H56Cl2N2P2Pd Pd