ChemicalBook >> CAS DataBase List >>1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

CAS No.
18422-53-2
Chemical Name:
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
Synonyms
D-EPOXONE;D-EPOXONE(R);D-Epoxone(rg;-[1,4]dioxolan]-7-one;Shi’s epoxidation catalyst;shi epoxidation diketal catalyst;Shi Epoxidation Diketal Catalyst 98%;1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&;1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &;1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo
CBNumber:
CB9122633
Molecular Formula:
C12H18O6
Molecular Weight:
258.27
MDL Number:
MFCD11865369
MOL File:
18422-53-2.mol
Last updated:2023-04-23 13:52:06

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Properties

Melting point 102-104 °C(lit.)
Boiling point 341.9±42.0 °C(Predicted)
Density 1.28±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,2-8°C
solubility Soluble in chloroform and methanol.
form Solid
color White to Pale Yellow
optical activity [α]20/D 120.9°, c = 1 in chloroform
BRN 1319073

SAFETY

Risk and Safety Statements

Safety Statements  22-24/25
WGK Germany  3
HS Code  29329990
NFPA 704
1
0 0

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 520160 Shi Epoxidation Diketal Catalyst 98% 18422-53-2 5g $222 2024-03-01 Buy
Alfa Aesar L18989 D-Epoxone, 98% 18422-53-2 1g $50.65 2024-03-01 Buy
Alfa Aesar L18989 D-Epoxone, 98% 18422-53-2 5g $203.65 2024-03-01 Buy
TRC S354000 Shi Epoxidation Diketal Catalyst 18422-53-2 1g $120 2021-12-16 Buy
TRC S354000 Shi Epoxidation Diketal Catalyst 18422-53-2 5g $485 2021-12-16 Buy
Product number Packaging Price Buy
520160 5g $222 Buy
L18989 1g $50.65 Buy
L18989 5g $203.65 Buy
S354000 1g $120 Buy
S354000 5g $485 Buy

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Chemical Properties,Uses,Production

Chemical Properties

White Solid

Uses

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline''s reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

Uses

Shi Epoxidation Diketal Catalyst is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

Uses

1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 115)Suppliers
Supplier Tel Email Country ProdList Advantage
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 6992 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
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Henan Tianfu Chemical Co.,Ltd.
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Shanghai Time Chemicals CO., Ltd.
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ATK CHEMICAL COMPANY LIMITED
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Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
BOC Sciences
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Chongqing Chemdad Co., Ltd
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View Lastest Price from 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,2:4,5-di-o-isopropylidene-beta-d-erythro-2,3-hexodiulo-2,6-pyranose pictures 2024-04-15 1,2:4,5-di-o-isopropylidene-beta-d-erythro-2,3-hexodiulo-2,6-pyranose
18422-53-2
US $1.00-1.00 / mg 100mg 0.99 5ton/month ANHUI SHENGZHIKAI BIOTECHNOLOGY CO.,LTD
1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose pictures 2022-10-01 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose
18422-53-2
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE pictures 2019-07-06 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
18422-53-2?
US $1.00 / kg 1kg 98% 100KG Career Henan Chemical Co
1,2:4,5-DI-O-ISOPROPYLIDEN-BETA-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE shi epoxidation diketal catalyst di-O-isopropylidene-beta-D-erythro-2,3-hexodiulopyranose D-EPOXONE D-EPOXONE(R) 1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo D-Epoxone(rg 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- & 1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO& 1,2:4,5-di-o-isopropylidene-á-d-erythro-2,3-hexodiulo-2,6-pyranose 1,2:4,5-di-o-isopropylidene-β-d-erythro-2,3-hexodiulo-2,6-pyranose Shi’s epoxidation catalyst Shi Epoxidation Diketal Catalyst 98% (3'aR,4S,7'aR)-2,2,2',2'-tetramethylspiro[1,3-dioxolane-4,6'-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7'-one 4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE -[1,4]dioxolan]-7-one (3aR,4'R,7aR)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one (3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE USP/EP/BP 1,2:4,5-di-O-isopropylidene-β-D-erythro-hexo-2,3-diulo-2,6-pyranose 1,2:4,5-Bis-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose C12H18O6 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 18422-53-2 (4S,7''aR)-2,2,2'',2''-tetramethylspiro[1,3-dioxolane-4,6''-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7''-one 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose β-D-erythro-2,3-Hexodiulo-2,6-pyranose, 1,2:4,5-bis-O-(1-methylethylidene)- 18422-53-2 Epoxidation Monosaccharide Asymmetric Synthesis Carbohydrates Chiral Catalysts, Ligands, and Reagents BioChemical Biochemicals and Reagents