NICKELOCENE
- CAS No.
- 1271-28-9
- Chemical Name:
- NICKELOCENE
- Synonyms
- Nickelocene,99%;BIS(CYCLOPENTADIENYL)NICKEL;di(cyclopenta-1,3-dien-1-yl)nickel;bis(B7;Nikelocen;NICKELOCENE;Nickelocene>Nickelocene(NiCp2);nickelbiscyclopentadiene;DI(CYCLOPENTADIENYL)NICKEL
- CBNumber:
- CB9136861
- Molecular Formula:
- C10H10Ni10*
- Molecular Weight:
- 188.88
- MDL Number:
- MFCD00001441
- MOL File:
- 1271-28-9.mol
- MSDS File:
- SDS
| Melting point | 171-173 °C(lit.) |
|---|---|
| storage temp. | 2-8°C |
| Water Solubility | Insoluble in water |
| form | crystal |
| color | dark green |
| Sensitive | Air & Moisture Sensitive |
| CAS DataBase Reference | 1271-28-9(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | JR8F745XV5 |
| NIST Chemistry Reference | Nickelocene(1271-28-9) |
| Proposition 65 List | Nickelocene |
| EPA Substance Registry System | Nickelocene (1271-28-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H228-H302-H317-H350 | |||||||||
| Precautionary statements | P201-P210-P280-P301+P312+P330-P302+P352-P308+P313 | |||||||||
| Hazard Codes | F,T | |||||||||
| Risk Statements | 49-11-22-43 | |||||||||
| Safety Statements | 53-36/37/39-45 | |||||||||
| RIDADR | UN 1325 4.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QR6500000 | |||||||||
| F | 10-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 4.2 | |||||||||
| PackingGroup | I | |||||||||
| HS Code | 29319090 | |||||||||
| Toxicity | mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968. | |||||||||
| NFPA 704 |
|
NICKELOCENE price More Price(14)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | N7524 | Bis(cyclopentadienyl)nickel(II) | 1271-28-9 | 5g | $71.6 | 2024-03-01 | Buy |
| TCI Chemical | D1574 | Nickelocene >98.0%(T) | 1271-28-9 | 1g | $52 | 2024-03-01 | Buy |
| TCI Chemical | D1574 | Nickelocene >98.0%(T) | 1271-28-9 | 5g | $147 | 2024-03-01 | Buy |
| Alfa Aesar | 087899 | Bis(cyclopentadienyl)nickel, dry | 1271-28-9 | 2g | $44 | 2024-03-01 | Buy |
| Alfa Aesar | 087899 | Bis(cyclopentadienyl)nickel, dry | 1271-28-9 | 50g | $301.65 | 2024-03-01 | Buy |
NICKELOCENE Chemical Properties,Uses,Production
Chemical Properties
GREEN TO DARK GREEN CRYSTALS OR CRYST. POWDER
Chemical Properties
Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.
Uses
Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.
Uses
Catalyst, complexing agent.
Uses
This metal alkyl may be used to synthesize hybrid organic-inorganic polymeric molecular layer deposition (MLD). Bis(cyclopentadienyl) nickel (Cp 2 Ni) may be used as a Ni precursor for the atomic layer deposition (ALD) of NiO/carbon nanotubes hybrids.
General Description
Dark liquid in an 8-10% solution in toluene. Insoluble in water.
Air & Water Reactions
Highly flammable. The neat material is sensitive to air. . Insoluble in water.
Reactivity Profile
Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
Hazard
Toxic by inhalation and skin contact, a carcinogen (OSHA).
Health Hazard
ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.
Fire Hazard
NICKELOCENE is flammable.
Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.
Purification Methods
Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]
NICKELOCENE Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 | sales@tjzxchem.com | China | 559 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10297 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12468 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 15093356674; | laboratory@coreychem.com | China | 30255 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Hunan russell chemicals technology co ltd | 731-88557738 +8613739093081 | sales01@russellchem.com | CHINA | 291 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2255 | 58 |
Related articles
- Nickelocene: Chemical Properties and Uses
- Nickelocene, also known as dicyclopentadienyl nickel, is a dark green crystal. Due to the filling electrons in the anti-bond o....
- Oct 12，2019
View Lastest Price from NICKELOCENE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | NICKELOCENE
1271-28-9
|
US $7.00 / kg | 1kg | 99% | 100kg | Career Henan Chemical Co |
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- NICKELOCENE
1271-28-9
- US $7.00 / kg
- 99%
- Career Henan Chemical Co
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